Hostname: page-component-8448b6f56d-m8qmq Total loading time: 0 Render date: 2024-04-19T23:57:44.823Z Has data issue: false hasContentIssue false

Elastic Constants of Diamond Like Carbon Films by Surface Brillouin Scattering

Published online by Cambridge University Press:  10 February 2011

A. C. Ferrari
Affiliation:
Engineering Department, Cambridge University, Cambridge CB2 1 PZ, UK
J. Robertson
Affiliation:
Engineering Department, Cambridge University, Cambridge CB2 1 PZ, UK
R. Pastorelli
Affiliation:
INFM- Dip. di Ingegneria Nucleare, Politecnico di Milano, 1-20133 Milano, ITALY
M. G. Beghi
Affiliation:
INFM- Dip. di Ingegneria Nucleare, Politecnico di Milano, 1-20133 Milano, ITALY
C. E. Bottani
Affiliation:
INFM- Dip. di Ingegneria Nucleare, Politecnico di Milano, 1-20133 Milano, ITALY
Get access

Abstract

The elastic constants of thin Diamond-Like Carbon (DLC) films supply important information, but their measurement is difficult. Standard nanoindentation does not directly measure the elastic constants and has strong limitations particularly in the case of hard thin films on softer substrates, such as tetrahedral amorphous carbon on Si. Surface acoustic waves provide a better mean to investigate elastic properties. Surface Brillouin scattering (SBS) intrinsically probes acoustic waves of the wavelength which is appropriate to test the properties of films in the tens to hundreds of nanometers thickness range. SBS can be used to derive all the isotropic elastic constants of hard-on-soft and soft-on-hard amorphous carbon films of different kinds, with thickness down to less than 10 nm. The results help to resolve the previous uncertainties in mechanical data. The Young's modulus of tetrahedral amorphous carbon (ta-C) turns out to be lower than that of diamond, while the moduli of hydrogenated ta-C (ta-C:H) are considerably lower than those of ta-C because of the weakening effect of C-H bonding.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] He, H., Thorpe, M F, Phys. Rev. Lett. 54 2107 (1985)Google Scholar
[2] Jiang, X., Reichelt, K. and Stritzker, B., J. Appl. Phys., 68, 1018 (1990)Google Scholar
[3] Pharr, G.M., Callahan, D.L., McAdams, S.D., Tsui, T.Y., Anders, S., Ager, J.W., Brown, I.G., Bhatia, C.S., Silva, S.R.P. and Robertson, J., Appl. Phys. Lett., 68, 779 (1996)Google Scholar
[4] Friedman, T.A., Sullivan, J.P., Knapp, J.A., Tallant, D.R., Follstaedt, D.M., Medlin, D.L. and Mirkarimi, P.B., Appl. Phys. Lett., 71, 3820 (1997)Google Scholar
[5] Weiler, M., Sattel, S., Giessen, T., Jung, K., Ehrhardt, H. and Robertson, J., Phys. Rev. B, 53, 1594 (1996)Google Scholar
[6] Xu, S., Flynn, D., Tay, B.K., Prawer, S., Nugent, K.W., Silva, S.R.P. Lifshitz, Y. and Milne, W.I., Phil. Mag. B, 76, 351 (1997)Google Scholar
[7] Beghi, M.G., Bottani, C.E., Ossi, P.M., Lafford, T. and Tanner, B.K., J. Appl. Phys., 81, 672 (1997), and references thereinGoogle Scholar
[8] Schneider, D., Meyer, C.F., Mai, H., Schoeneich, B., Ziegele, H., Scheibe, H.J. and Lifshitz, Y., Diam. and Rel. Mat., 7, 973 (1998)Google Scholar
[9] Fallon, P. J., Veerasamy, V. S., Davis, C. A., Robertson, J., Amaratunga, G. A. J., Milne, W. I., Phys. Rev. B, 48, 4777 (1993);Google Scholar
Polo, M. C., And, J. L.ujar, Robertson, J. and Milne, W. I., Diamond. Relat. Mater, 9, 663 (2000)Google Scholar
[10] Weiler, M., Lang, K., Li, E., Robertson, J., Appl. Phys. Lett, 72, 1314 (1998);Google Scholar
Morrison, N.A., Rodil, S.E., Ferrari, A.C., Robertson, J. and Milne, W. I., Thin Solid Films, 337, 71 (1999)Google Scholar
[11] Libassi, A., Ferrari, A.C., Stolojan, V., Tanner, B.K., Robertson, J., Brown, L. M., Diamond and Related Materials, 9, 771 (2000)Google Scholar
[12] Ferrari, A.C., Robertson, J., Beghi, M.G., Bottani, C.E., Ferulano, R. and Pastorelli, R., Appl. Phys. Lett. 75, 1893 (1999)Google Scholar
[13] Schultrich, B., Scheibe, H. J., Dresher, D. and Ziegle, H., Surf. Coat. Tech. 98, 1097 (1998)Google Scholar
[14] Morath, C. J., Maris, H. J., Cuomo, J. J., Pappas, D. L., Grill, A., Patel, V. V., Doyle, J. P. and Saenger, K. L., J. Appl. Phys. 76, 2636 (1994)Google Scholar
[15] Knapp, J.A., Follstaedt, D. M., Myers, S. M., Barbour, J. C. and Friedmann, T. A., J. Appl. Phys 85, 1460 (1999)Google Scholar
[16] Kelires, P. C., Phys. Rev. Lett. 73, 2460 (1994)Google Scholar