Hostname: page-component-5c6d5d7d68-thh2z Total loading time: 0 Render date: 2024-08-08T00:42:42.814Z Has data issue: false hasContentIssue false
  • English
  • Français

Chemical Synthesis of Single and Mixed Phase Oxide Ceramics

Published online by Cambridge University Press:  15 February 2011

K. S. Mazdiyasni
K. S. Mazdiyasni*
Affiliation:
Air Force Wright Aeronautical Laboratories, Wright-Patterson Air Force Base, Ohio 45433, USA
Get access

Abstract

Thermal and hydrolytic decomposition of metal alkoxides, M(OR)n, is employed to obtain ultra-high-purity submicron-size < 50 nm refractory, ferroelectric, and electro-optic oxide powders. The high surface activity associated with these powders makes possible relatively low temperature processing of the powder compacts to near theoretical density with uniform fine-grain-size bodies. Transmission electron microscopy, high-temperature X-ray, and infrared and Raman spectroscopy are used to observe nucleation, growth, crystallite morphology of the synthesized powder, and microstructural features.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 32: Symposium B – Better Ceramics Through Chemistry I , 1984 , 175
Copyright
Copyright © Materials Research Society 1984

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Nielsen, M. L., Hamilton, P. M., and Walsh, R. J. in: Ultrafine Particles, Kuhn, W. E., Lamprey, H., and Sheer, C., eds. (Wiley, New York 1963) pp. 181–195.Google Scholar
2. Rau, R. C., J. Amer. Ceram. Soc. 47, 179 (1964).CrossRefGoogle Scholar
3. White, L. J. and Duffy, G. J., Inc. Eng. Chem. 51, 232–238 (1959).CrossRefGoogle Scholar
4. Hedger, H. J. and Hall, A. R., Powder Met. 8, 65–72 (1961).CrossRefGoogle Scholar
5. Sheer, C. and Korman, S. in: Arcs in Inert Atmospheres and Vacuum, Kuhn, W. E., ed. (Wiley, New York 1956) p. 169–183.Google Scholar
6. Mazdiyasni, K. S., Ceram. Int. 8, 42–56 (1982).CrossRefGoogle Scholar
7. Bradley, D. C., Mehratra, R. C., and Gaur, D. P., Metal Alkaxides (Academic Press, New York 1978) p. 411.Google Scholar
8. Mazdiyasni, K. S., Lynch, C. T., and Smith, J. S., J. Amer. Ceram. Soc. 50 532 (1967).CrossRefGoogle Scholar
9. Bradley, D. C., Mehratra, R. C., and Wardlaw, J., Chem. Soc. (London) 1963 (1953).Google Scholar
10. Herman, D. F., U.S. Patents 2,654,770 (1953), 2,655,523 (1953).Google Scholar
11. Anand, S. K., Singh, J. J., Multani, R. K., and Jain, B. D., Israel J. Chem. 7, 171 (1969).CrossRefGoogle Scholar
12. Mehratra, R. C., J. Amer. Chem. Soc. 76, 2266 (1954).CrossRefGoogle Scholar
13. Mazdiyasni, K. S., Lynch, C. T., and Smith, J. S., Inorg. Chem. 5, 342 (1966).CrossRefGoogle Scholar
14. Brown, L. M. and Mazdiyasni, K. S., Inorg Chem. 9, 2783 (1970).CrossRefGoogle Scholar
15. Adkins, H. and Cox, J., J. Amer. Chem. Soc. 60, 1151 (1938).CrossRefGoogle Scholar
16. Mazdiyasni, K. S., Lynch, C. T., and Smith, J. S., J. Amer. Ceram. Soc. 48 372 (1965).CrossRefGoogle Scholar
17. Mazdiyasni, K. S. in: Proceeding of the VI International Symposium on Reactivity of Solids, Mitchell, R. W., Devries, R. C., Roberts, R. W., and Cannon, P. J., eds. (Wiley, New York 1968) pp. 115–125.Google Scholar
18. McDevitt, N. T. and Baun, W. K., J. Amer. Ceram. Soc. 54, 254 (1971).Google Scholar
19. Phillipi, C. M. and Mazdiyasni, K. S., J. Amer. Ceram. 54, 254 (1971).CrossRefGoogle Scholar
20. Barker, A. S., Phys. Rev. 132, 1471 (1963).CrossRefGoogle Scholar
21. Mazdiyasni, K. S., Lynch, C. T., and Smith, J. S., J. Amer. Ceram. Soc. 49, 286 (1966).CrossRefGoogle Scholar
22. Burke, J. E. and Turnbull, D., Prog. Met. Phys. 3, 220 (1952).CrossRefGoogle Scholar
23. Coble, R., J. Appl. Phys. 32, 787 (1961).CrossRefGoogle Scholar
24. Anderson, P. J. and Morgan, P. L., Trans Farad. Soc. 60, 930 (1964).CrossRefGoogle Scholar
25. Mazdiyasni, K. S. in: Proceeding of the Second International Conference on Fine Particles, Kuhn, W. E., ed. (Electrochemical Society, Princeton, NJ 1974) pp. 3–27.Google Scholar
26. Rhodes, W. H. and Haag, R. M., AFML-TR-70-209 (Air Force Materials Laboratory, Wright-Patterson Air Force Base, OH September 1970).Google Scholar
27. Hoch, M. and Nair, K. M., Ceramurgia Int. 2, 88 (1976).CrossRefGoogle Scholar