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Silver nanoparticles supported on electrospun polyacrylonitrile nanofibrous mats for catalytic applications

Published online by Cambridge University Press:  28 December 2015

Yongkun Liu ,
Guohua Jiang ,
Lei Li ,
Hua Chen ,
Qin Huang ,
Tengteng Jiang  and
Xiangxiang Du
Yongkun Liu
Affiliation:
Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China
Guohua Jiang*
Affiliation:
Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China National Engineering Laboratory for Textile Fiber Materials and Processing Technology (Zhejiang), Hangzhou 310018, People's Republic of China Key Laboratory of Advanced Textile Materials and Manufacturing Technology (ATMT), Ministry of Education, Hangzhou 310018, People's Republic of China
Lei Li
Affiliation:
Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China
Hua Chen
Affiliation:
Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China
Qin Huang
Affiliation:
Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China
Tengteng Jiang
Affiliation:
Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China
Xiangxiang Du
Affiliation:
Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China
*
Address all correspondence to Guohua Jiang at ghjiang_cn@zstu.edu.cn
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Abstract

In this work, we developed a convenient way to immobilize silver nanoparticles on the aminated polyacrylonitrile (PAN) nanofibrous mats by combing the electrospinning technology from complex-containing polymer solution, amination of PAN nanofibrous and electroless plating technique. The resultant composite nanaofibrous mats had been characterized by scanning electron microscopy, energy-dispersive spectrometer, transmission electron microscopy, X-ray diffraction, and Fourier transform infrared spectra analysis. The catalytic activity and stability of these resultant composite nanofibrous mats for the catalytic reactions, including reduction of 4-nitrophenol to form 4-aminophenol, and selective oxidation of benzyl alcohol, were investigated. The resultant nanofibrous mats exhibited high-efficiency, convenient separation, recovery, and cyclic utilization properties.

Type
Research Letters
Information
MRS Communications , Volume 6 , Issue 1 , March 2016 , pp. 31 - 40
Copyright
Copyright © Materials Research Society 2015 

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References

1. Caron, S., Dugger, R., Ruggeri, S., Ragan, J., and Ripin, D.: Large-scale oxidations in the pharmaceutical industry. Chem. Rev. 106, 2943 (2006).CrossRefGoogle ScholarPubMed
2. Punniyamurthy, T., Velusamy, S., and Iqbal, J.: Recent advances in transition metal catalyzed oxidation of organic substrates with molecular oxygen. Chem. Rev. 105, 2329 (2005).CrossRefGoogle ScholarPubMed
3. Zhan, G., Hong, Y., Mbah, V., Huang, J., Ibrahim, A., Du, M., and Li, Q.: Bimetallic Au–Pd/MgO as efficient catalysts for aerobic oxidation of benzyl alcohol: a green bio-reducing preparation method. Appl. Catal. A 439, 179 (2012).Google Scholar
4. Liu, C., Tan, R., Yin, D., Yu, N., and Zhou, Y.: Selective oxidation of benzal alcohol catalyzed by Pd/PMO-SMA-15 catalyst. Chin. J. Catal. 31, 1369 (2010).Google Scholar
5. Ma, L., Guo, X., and Xiang, L.: Catalytic activity of Ag/SBA-15 for low-temperature gas-phase selective oxidation of benzyl alcohol to benzaldehyde. Chin. J. Catal. 35, 108 (2014).Google Scholar
6. Lin, F. and Doong, R.: Highly efficient reduction of 4-nitrophenol by heterostructured gold-magnetite nanocatalysts. Appl. Catal. A 486, 32 (2014).Google Scholar
7. Wang, X., Fu, J., Wang, M., Wang, Y., Chen, J., and Xu, Q.: Facile synthesis of Au nanoparticles supported on polyphosphazene functionalized carbon nanotubes for catalytic reduction of 4-nitrophenol. J. Mater. Sci. 49, 5056 (2014).Google Scholar
8. Sau, T., Rogach, A., Jackel, F., Klar, T., and Feldmann, J.: Properties and applications of colloidal nonspherical noble metal nanoparticles. Adv. Mater. 22, 1805 (2010).Google Scholar
9. Zeng, J., Zhang, Q., Chen, J., and Xia, Y.: A comparison study of the catalytic properties of Au-based nanocages, nanoboxes, and nanoparticles. Nano Lett. 10, 30 (2009).CrossRefGoogle Scholar
10. Gong, J. and Mullins, C.: Surface science investigations of oxidative chemistry on gold. Acc. Chem. Res. 42, 1063 (2009).Google Scholar
11. Hutchings, G.: Reactions of alkynes using heterogeneous and homogeneous cationic gold catalysts. Top. Catal. 48, 55 (2008).Google Scholar
12. Mondal, S., Rana, U., and Malik, S.: Facile decoration of polyaniline fiber with Ag nanoparticles for recyclable SERS substrate. ACS Appl. Mater. Interfaces 7, 10457 (2015).Google Scholar
13. Jiang, G., Jiang, T., Wang, Y., Du, X., Wei, Z., and Zhou, H.: Facile preparation of novel Au-polydopamine nanoparticles modified by 4-mercaptophenyl boronic acid for glucose sensor. RSC Adv. 4, 33658 (2014).Google Scholar
14. Jiang, G., Wang, L., Chen, T., Yu, H., and Chen, C.: Preparation of gold nanoparticles in the presence of poly(benzyl ether) alcohol dendrons. Mater. Chem. Phys. 98, 76 (2006).CrossRefGoogle Scholar
15. Jiang, G., Wang, L., and Chen, W.: Studies on the preparation and characterization of gold nanoparticles protected by dendrons. Mater. Lett. 61, 278 (2007).Google Scholar
16. Jiang, G., Wang, Y., and Sun, X.: Influence on fluorescence properties of hyperbranched poly(amidoamine)s by nano golds. J. Polym. Sci. B: Polym. Phys. 48, 2386 (2010).Google Scholar
17. Zhang, H., Jin, M., and Xia, Y.: Enhancing the catalytic and electrocatalytic properties of Pt-based catalysts by forming bimetallic nanocrystals with Pd. Chem. Soc. Rev. 41, 8035 (2012).Google Scholar
18. Zhou, Y., Cheng, X., Du, D., Yang, J., Zhao, N., Ma, S., Zhong, T., and Lin, Y.: Graphene-silver nanohybrids for ultrasensitive surface enhanced Raman spectroscopy: size dependence of silver nanoparticles. J. Mater. Chem. C 2, 6850 (2014).CrossRefGoogle Scholar
19. Li, X., Wu, K., Yea, Y., and Wei, X.: Gas-assisted growth of boron-doped nickel nanotube arrays: rapid synthesis, growth mechanisms, tunable magnetic properties, and super-efficient reduction of 4-nitrophenol. Nanoscale 5, 3648 (2013).CrossRefGoogle ScholarPubMed
20. Sawada, K., Sakai, S., and Taya, M.: Polyacrylonitrile-based electrospun nanofibers carrying gold nanoparticles in situ formed by photochemical assembly. J. Mater. Sci. 49, 4595 (2014).Google Scholar
21. Destaye, A., Lin, C., and Lee, C.: Glutaraldehyde vapor cross-linked nanofibrous PVA mat with in situ formed silver nanoparticles. ACS Appl. Mater. Interfaces 5, 4745 (2013).CrossRefGoogle ScholarPubMed
22. Supaphol, P. and Chuangchote, S.: On the electrospinning of poly (vinyl alcohol) nanofiber mats: a revisit. J. Appl. Polym. Sci. 108, 969 (2008).Google Scholar
23. Wong, K., Hutter, J., Zinke-Allmang, M., and Wan, W.: Physical properties of ion beam treated electrospun poly (vinyl alcohol) nanofibers. Eur. Polym. J. 45, 1349 (2009).Google Scholar
24. Han, D., Filocamo, S., Kirby, R., and Steckl, A.: Deactivating chemical agents using enzyme-coated nanofibers formed by electrospinning. ACS Appl. Mater. Interfaces 3, 4633 (2011).CrossRefGoogle ScholarPubMed
25. Miao, Y., Wang, R., Chen, D., Liu, Z., and Liu, T.: Electrospun self-standing membrane of hierarchical SiO2@ γ-AlOOH (Boehmite) core/sheath fibers for water remediation. ACS Appl. Mater. Interfaces 4, 5353 (2012).Google Scholar
26. Li, X., Wang, M., Wang, C., Cheng, C., and Wang, X.: Facile immobilization of Ag nanocluster on nanofibrous membrane for oil/water separation. ACS Appl. Mater. Interfaces 6, 15272 (2014).Google Scholar
27. Hooper, A., Werho, D., Hopson, T., and Palmer, O.: Evaluation of amine-and amide-terminated self-assembled monolayers as “Molecular glues” for Au and SiO2 substrates. Surf. Interface Anal. 31, 809 (2001).Google Scholar
28. Watzky, M. and Finke, R.: Transition metal nanocluster formation kinetic and mechanistic studies. A new mechanism when hydrogen is the reductant: slow, continuous nucleation and fast autocatalytic surface growth. J. Am. Chem. Soc. 119, 10382 (1997).Google Scholar
29. Stoeva, S., Zaikovski, V., Prasad, B., Stoimenov, P., Sorensen, C., and Klabunde, K.: Reversible transformations of gold nanoparticle morphology. Langmuir 21, 10280 (2005).CrossRefGoogle ScholarPubMed
30. Vattikuti, S., Byon, C., Shim, J., and Reddy, C.: Effect of temperature on structural, morphological and magnetic properties of Cd0.7Co0.3Fe2O4 nanoparticles. J. Magn. Magn. Mater. 393, 132 (2015).Google Scholar
31. Modak, S., Ammar, M., Mazaleyrat, F., Dasc, S., and Chakrabartia, P.: XRD, HRTEM and magnetic properties of mixed spinel nanocrystalline Ni–Zn–Cu-ferrite. J. Alloy. Compd. 473, 15 (2009).CrossRefGoogle Scholar
32. Yu, H., Chen, M., Rice, P., Wang, S., White, R., and Sun, S.: Dumbbell-like bifunctional Au-Fe3O4 nanoparticles. Nano Lett. 5, 379 (2005).Google Scholar
33. Nie, R., Liang, D., Shen, L., Gao, J., Chen, P., and Hou, Z.Y.: Selective oxidation of glycerol with oxygen in base-free solution over MWCNTs supported PtSb alloy nanoparticles. Appl. Catal. B 127, 212 (2012).Google Scholar
34. Zahed, B. and Hosseini-Monfared, H.: A comparative study of silver-graphene oxide nanocomposites as a recyclable catalyst for the aerobic oxidation of benzyl alcohol: support effect. Appl. Surf. Sci. 328, 536 (2015).Google Scholar
35. Wakayama, H., Setoyama, N., and Fukushima, Y.: Size-controlled synthesis and catalytic performance of Pt nanoparticles in micro- and mesoporous silica prepared using supercritical solvents. Adv. Mater. 15, 742 (2003).CrossRefGoogle Scholar
36. Bulushev, D., Reshetnikov, S., and Kiwi-Minsker, L.: Deactivation kinetics of V/Ti-oxide in toluene partial oxidation. Appl. Catal. A 220, 31 (2001).CrossRefGoogle Scholar
37. Pajonk, G.: Contribution of spillover effects to heterogeneous catalysis. Appl. Catal. A 202, 157 (2000).Google Scholar
38. Zhao, G., Hu, H., Deng, M., and Lu, Y.: Microstructured Au/Ni-fiber catalyst for low-temperature gas-phase selective oxidation of alcohols. Chem. Commun. 47, 9642 (2011).CrossRefGoogle ScholarPubMed
39. Jia, L., Zhang, S., Gu, F., Ping, Y., Guo, X., Zhong, Z., and Su, F.: Highly selective gas-phase oxidation of benzyl alcohol to benzaldehyde over silver-containing hexagonal mesoporous silica. Microporous Mesoporous Mater. 149, 158 (2012).Google Scholar
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