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Continuous dynamic analysis: evolution of elastic properties with strain

Published online by Cambridge University Press:  03 January 2014

S. Basu*
Affiliation:
Agilent Technologies, Chandler, Arizona 85226
J.L. Hay
Affiliation:
Agilent Technologies, Chandler, Arizona 85226
J.E. Swindeman
Affiliation:
Nanomechanics Inc., Oak Ridge, Tennessee 37830
W.C. Oliver
Affiliation:
Nanomechanics Inc., Oak Ridge, Tennessee 37830
*
Address all correspondence to S. Basu atsandipbasu@gmail.com
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Abstract

Mechanical strain triggers changes in inherent molecular structure, especially in polymeric and biological materials. Unlike conventional techniques, we demonstrate a novel dynamic mechanical characterization method to study the effect of this structural evolution with strain on elastic properties. During tensile characterization of small diameter fibers, we quantitatively measured the viscoelastic properties as a continuous function of strain. While this approach is useful to characterize the elastic properties of metal microwires independent of applied strain, it is extremely important for fundamental understanding of molecular changes and their effect on the viscoelastic properties in materials such as polymer fiber and spider silk.

Type
Research Letters
Copyright
Copyright © Materials Research Society 2014 

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References

1.Khatibi, G., Betzwar-Kotas, A., GrÖGer, V., and Weiss, B.: A study of the mechanical and fatigue properties of metallic microwires. Fatigue Fract. Eng. Mater. Struct. 28, 723733 (2005).Google Scholar
2.Danaher, F.D., Williams, J.J., Singh, D.R.P., Jiang, L., and Chawla, N.: Tensile and fatigue behavior of Al-1Si wire used in wire bonding. J. Electron. Mater. 40, 14221427 (2011).Google Scholar
3.Ma, Z., Kotaki, M., Inai, R., and Ramakrishna, S.: Potential of nanofiber matrix as tissue-engineering scaffolds. Tissue Eng. 11, 101109 (2005).Google Scholar
4.Leung, V. and Ko, F.: Biomedical applications of nanofibers. Polym. Adv. Technol. 22, 350365 (2011).Google Scholar
5.Hayashi, C.Y., Shipley, N.H., and Lewis, R.V.: Hypotheses that correlate the sequence, structure, and mechanical properties of spider silk proteins. Int. J. Biol. Macromol. 24, 271275 (1999).Google Scholar
6.Shao, Z. and Vollrath, F.: Materials: surprising strength of silkworm silk. Nature 418, 741–741 (2002).Google Scholar
7.Meyers, M.A., Chen, P.-Y., Lin, A.Y.-M., and Seki, Y.: Biological materials: structure and mechanical properties. Progr. Mater. Sci. 53, 1206 (2008).Google Scholar
8.Termonia, Y.: Molecular modeling of spider silk elasticity. Macromolecules 27, 73787381 (1994).Google Scholar
9.Vollrath, F.: Strength and structure of spiders' silks. Rev. Mol. Biotechnol. 74, 6783 (2000).Google Scholar
10.Tan, E.P.S., Ng, S.Y., and Lim, C.T.: Tensile testing of a single ultrafine polymeric fiber. Biomaterials 26, 14531456 (2005).Google Scholar
11.Chen, Z., Wei, B., Mo, X., Lim, C.T., Ramakrishna, S., and Cui, F.: Mechanical properties of electrospun collagen–chitosan complex single fibers and membrane. Mater. Sci. Eng. C 29, 24282435 (2009).Google Scholar
12.Lechat, C., Bunsell, A.R., Davies, P., and Piant, A.: Mechanical behaviour of polyethylene terephthalate & polyethylene naphthalate fibres under cyclic loading. J. Mater. Sci. 41, 1745 (2006).Google Scholar
13.Schultz, J.M.: Polymer Materials Science. Ch. 11 (Prentice-Hall, New Jersey, 1974).Google Scholar
14.Toki, S., Fujimaki, T., and Okuyama, M.: Strain-induced crystallization of natural rubber as detected real-time by wide-angle X-ray diffraction technique. Polymer 41, 54235429 (2000).Google Scholar
15.Ran, S., Fang, D., Zong, X., Hsiao, B.S., Chu, B., and Cunniff, P.M.: Structural changes during deformation of Kevlar fibers via on-line synchrotron SAXS/WAXD techniques. Polymer 42, 16011612 (2001).Google Scholar
16.Washer, G., Brooks, T., and Saulsberry, R.: Characterization of Kevlar using Raman spectroscopy. J. Mater. Civil Eng. 21, 226234 (2009).CrossRefGoogle Scholar
17.Cranford, S.W., Tarakanova, A., Pugno, N.M., and Buehler, M.J.: Nonlinear material behaviour of spider silk yields robust webs. Nature 482, 7276 (2012).Google Scholar
18.Oliver, W.C. and Pethica, J.B.: method for continuous determination of the elastic stiffness of contact between two bodies. US Patent (1988).Google Scholar
19.Hay, J., Agee, P., and Herbert, E.: Continuous stiffness measurement during instrumented indentation testing. Exp. Tech. 34, 8694 (2010).Google Scholar
20.Blackledge, T.A. and Hayashi, C.Y.: Silken toolkits: biomechanics of silk fibers spun by the orb web spider Argiope argentata (Fabricius 1775). J. Exp. Biol. 209, 24522461 (2006).Google Scholar