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Self-patterning of graphene-encapsulated gold nanoparticles for surface-enhanced Raman spectroscopy

Published online by Cambridge University Press:  29 January 2018

Yuan Li ,
Kelly Burnham ,
John Dykes  and
Nitin Chopra
Yuan Li
Affiliation:
Metallurgical and Materials Engineering Department (MTE), Center for Materials for Information Technology (MINT), The University of Alabama, Tuscaloosa, AL 35487, USA
Kelly Burnham
Affiliation:
NSF-REH Fellow, Northridge High School, Tuscaloosa, AL 35406, USA
John Dykes
Affiliation:
Department of Mathematics, NSF-REU Fellow, The University of Alabama, Tuscaloosa, AL 35407, USA
Nitin Chopra*
Affiliation:
Metallurgical and Materials Engineering Department (MTE), Department of Biological Sciences, Department of Chemistry, Center for Materials for Information Technology (MINT), The University of Alabama, Tuscaloosa, AL 35487, USA
*
Address all correspondence to Dr. Nitin Chopra at nchop2@gmail.com
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Abstract

The main challenges of developing advanced surface-enhanced Raman spectroscopy (SERS) sensors lie in the poor reproducibility, low uniformity, and the lack of molecular selectivity. In this paper, we report a facile and cost-effective approach for the large-scale patterning of graphene-encapsulated Au nanoparticles on Si substrate as efficient SERS sensors with highly-improved uniformity, reproducibility, and unique selectivity. The materials production was accomplished via an industry-applicable galvanic deposition—annealing—chemical vapor deposition approach, followed by a final plasma treatment. Our study provides a facile approach to the fabrication of uniform SERS substrate and further prompts the practical progress of SERS-based chemical sensors.

Type
Research Letters
Information
MRS Communications , Volume 8 , Issue 1 , March 2018 , pp. 79 - 87
Copyright
Copyright © Materials Research Society 2018 

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References

1. Camden, J.P., Dieringer, J.A., Zhao, J., and Van Duyne, R.P.: Controlled plasmonic nanostructures for surface-enhanced spectroscopy and sensing. Acc. Chem. Res. 41, 1653 (2008).Google Scholar
2. He, Y., Su, S., Xu, T., Zhong, Y., Zapien, J.A., Li, J., and Lee, S.T.: Silicon nanowires-based highly-efficient SERS-active platform for ultrasensitive DNA detection. Nano Today 6, 122 (2011).Google Scholar
3. Galopin, E., Barbillat, J., Coffinier, Y., Szunerits, S., Patriarche, G., and Boukherroub, R.: Silicon nanowires coated with silver nanostructures as ultrasensitive interfaces for surface-enhanced Raman spectroscopy. ACS Appl. Mater. Interfaces 1, 1396 (2009).Google Scholar
4. Tian, Z.Q., Ren, B., Li, J.F., and Yang, Z.L.: Expanding generality of surface-enhanced Raman spectroscopy with borrowing SERS activity strategy. Chem. Commun. 34, 3514 (2007).Google Scholar
5. Gong, X., Bao, Y., Qiu, C., and Jiang, C.: Individual nanostructured materials: fabrication and surface-enhanced Raman scattering. Chem. Commun. 48, 7003 (2012).CrossRefGoogle ScholarPubMed
6. Ko, H., Singamaneni, S., and Tsukruk, V.V.: Nanostructured surfaces and assemblies as SERS media. Small 4, 1576 (2008).Google Scholar
7. Luo, P., Li, C., and Shi, G.: Synthesis of gold@ carbon dots composite nanoparticles for surface enhanced Raman scattering. Phys. Chem. Chem. Phys. 14, 7360 (2012).Google Scholar
8. Gunawidjaja, R., Kharlampieva, E., Choi, I., and Tsukruk, V.V.: Bimetallic nanostructures as active Raman markers: gold-nanoparticle assembly on 1D and 2D silver nanostructure surfaces. Small 5, 2460 (2009).Google Scholar
9. Halas, N.J., Lal, S., Link, S., Chang, W.S., Natelson, D., Hafner, J.H., and Nordlander, P.: A plethora of plasmonics from the laboratory for nanophotonics at Rice University. Adv. Mater. 24, 4842 (2012).Google Scholar
10. Li, Y., DiStefano, J.G., Murthy, A.A., Cain, J.D., Hanson, E.D., Li, Q., Castro, F.C., Chen, X., and Dravid, V.P.: Superior plasmonic photodetectors based on Au@ MoS2 core-shell Heterostructures. ACS Nano 11, 10321 (2017).Google Scholar
11. Li, Y., Cain, J.D., Hanson, E.D., Murthy, A.A., Hao, S., Shi, F., Li, Q., Wolverton, C., Chen, X., and Dravid, V.P.: Au@ MoS2 core-shell heterostructures with strong light-matter interactions. Nano Lett 16, 7696 (2016).Google Scholar
12. Zheng, Y., Wang, W., Fu, Q., Wu, M., Kamran, S.Y., Wong, K.M., and Lei, Y.: Surface-Enhanced Raman Scattering (SERS) Substrate based on large-area well-defined gold nanoparticle arrays with high SERS uniformity and stability. Chem Plus Chem 79, 1622 (2014).Google Scholar
13. Baik, S.Y., Cho, Y.J., Lim, Y.R., Im, H.S., Jang, D.M., Myung, Y., and Kang, H.S.: Charge-selective surface-enhanced Raman scattering using silver and gold nanoparticles deposited on silicon–carbon core-shell nanowires. ACS Nano 6, 2459 (2012).CrossRefGoogle ScholarPubMed
14. Wang, H., Jiang, X., Lee, S.T., and He, Y.: Silicon nanohybrid- based surface-enhanced Raman scattering sensors. Small 10, 4455 (2014).Google Scholar
15. Xu, W., Mao, N., and Zhang, J.: Graphene: a platform for surface-enhanced Raman spectroscopy. Small 9, 1206 (2013).Google Scholar
16. Li, X., Li, J., Zhou, X., Ma, Y., Zheng, Z., Duan, X., and Qu, Y.: Silver nanoparticles protected by monolayer graphene as a stabilized substrate for surface enhanced Raman spectroscopy. Carbon 66, 713 (2014).CrossRefGoogle Scholar
17. Xu, W., Ling, X., Xiao, J., Dresselhaus, M.S., Kong, J., Xu, H., and Zhang, J.: Surface enhanced Raman spectroscopy on a flat graphene surface. Proc. Natl. Acad. Sci. 109, 9281 (2012).Google Scholar
18. Li, Y., Shi, W., Gupta, A., and Chopra, N.: Morphological evolution of gold nanoparticles on silicon nanowires and their plasmonics. RSC Adv. 5, 49708 (2015).Google Scholar
19. Li, Y., Dykes, J., Gilliam, T., and Chopra, N.: A new heterostructured SERS substrate: free-standing silicon nanowires decorated with graphene-encapsulated gold nanoparticles. Nanoscale 9, 5263 (2017).Google Scholar
20. Li, Y. and Chopra, N.: Gold nanoparticle integrated with nanostructured carbon and quantum dots: synthesis and optical properties. Gold Bull. 48, 73 (2015).Google Scholar
21. Chopra, N., Wu, J.C., and Summerville, L.: Controlled assembly of graphene shells encapsulated gold nanoparticles and their integration with carbon nanotubes. Carbon 62, 76 (2013).CrossRefGoogle Scholar
22. Chopra, N., Bachas, L.G., and Knecht, M.R.: Fabrication and biofunctionalization of carbon-encapsulated Au nanoparticles. Chem. Mater. 21, 1176 (2009).Google Scholar
23. Wu, J., Shi, W., and Chopra, N.: Plasma oxidation kinetics of gold nanoparticles and their encapsulation in graphene shells by chemical vapor deposition growth. J. Phys. Chem. C 116, 12861 (2012).Google Scholar
24. Li, Y. and Chopra, N.: Fabrication of nanoscale hetero-structures comprised of graphene-encapsulated gold nanoparticles and semi-conducting quantum dots for photocatalysis. Phys. Chem. Chem. Phys. 17, 12881 (2015).CrossRefGoogle Scholar
25. Li, Y. and Chopra, N.: Graphene encapsulated gold nanoparticle-quantum dot heterostructures and their electrochemical characterization. Appl. Surf. Sci. 344, 27 (2015).Google Scholar
26. Li, Y., Shi, W., and Chopra, N.: Functionalization of multilayer carbon shell-encapsulated gold nanoparticles for surface-enhanced Raman scattering sensing and DNA immobilization. Carbon 100, 165 (2016).Google Scholar
27. Jain, P.K., Lee, K.S., El-Sayed, I.H., and El-Sayed, M.A.: Calculated absorption and scattering properties of gold nanoparticles of different size, shape, and composition: applications in biological imaging and biomedicine. J. Phys. Chem. B 110, 7238 (2006).Google Scholar
28. Lee, K.S. and El-Sayed, M.A.: Gold and silver nanoparticles in sensing and imaging: sensitivity of plasmon response to size, shape, and metal composition. J. Phys. Chem. B 110, 19220 (2006).Google Scholar
29. Xu, P., Jeon, S.H., Mack, N.H., Doorn, S.K., Williams, D.J., Han, X., and Wang, H.L.: Field-assisted synthesis of SERS-active silver nanoparticles using conducting polymers. Nanoscale 2, 1436 (2010).Google Scholar
30. Malard, L.M., Pimenta, M.A., Dresselhaus, G., and Dresselhaus, M.S.: Raman spectroscopy in graphene. Phys. Rep. 473, 51 (2009).Google Scholar
31. Lu, G., Li, H., Liusman, C., Yin, Z., Wu, S., and Zhang, H.: Surface enhanced Raman scattering of Ag or Au nanoparticle-decorated reduced graphene oxide for detection of aromatic molecules. Chem. Sci. 2, 1817 (2011).Google Scholar
32. Björk, J., Hanke, F., Palma, C.A., Samori, P., Cecchini, M., and Persson:, M. Adsorption of aromatic and anti-aromatic systems on graphene through π-π stacking. J. Phys. Chem. Lett. 1, 3407 (2010).Google Scholar
33. Yang, S.T., Chen, S., Chang, Y., Cao, A., Liu, Y., and Wang, H.: Removal of methylene blue from aqueous solution by graphene oxide. J. Colloid Interface Sci. 359, 24 (2011).Google Scholar
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