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Phases of Thin Colloidal Layers

Published online by Cambridge University Press:  29 November 2013

Cherry Murray
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Extract

Colloids have long been used in applications such as paints, coatings, foods, and many manufacturing processes. Recently, synthetic crystalline arrays of colloidal particles have been used as novel optical materials such as diffractive filters, mimicking the optical properties of opals—natural colloidal crystals made from silica spheres. Colloidal assembly has been proposed to manufacture photonic bandgap materials that can be tailored and that could have many uses in optical devices. The advantages of using colloids to do the self-assembly of novel materials are the relative ease with which monodisperse spheres comparable in size to the wavelength of light can be manufactured and also the demonstrated ease by which some suspensions of monodisperse colloidal spheres crystallize when placed under favorable conditions. Before we can use colloidal crystallization as a controlled self-assembly technique for making novel optical materials, we need (1) to create a means of manufacturing large quantities of monodisperse particles of the desired dielectric behavior, (2) to understand the phase diagram and nucleation phenomena of colloidal suspensions, and (3) to find an easy means to fix the particles in place once they selforganize. In this article, I focus on the second point just mentioned, I give an overview of the phases and some of the complex phenomena encountered in three-dimensional (3D) suspensions and in thin layers of monodisperse colloidal spheres between smooth walls, and I then briefly mention the greater complexity encountered in bidisperse systems. The first and third points will be dealt with elsewhere in this issue.

Type
From Dynamics to Devices: Directed Self-Assembly of Colloidal Materials
Information
MRS Bulletin , Volume 23 , Issue 10 , October 1998 , pp. 33 - 38
Copyright
Copyright © Materials Research Society 1998

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References

1.Evans, D.F. and Wennerstrom, H.A., The Colloidal Domain, Where Physics, Chemistry, Biology and Technology Meet (VCH Publishers, New York, 1994).Google Scholar
2. For example, see Holtz, J.H. and Asher, S., Nature 389 (1997) p. 829; G. Pan, R. Kesavamoorthy, and S. Asher, Phys. Rev. Lett. 78 (1997) p. 3860.CrossRefGoogle Scholar
3.Joannopoulos, J.D., Meade, R.D., and Winn, J.N., Photonic Crystals (Princeton University Press, Princeton, 1995).Google Scholar
4.Murray, C. and Grier, D.G., Ann. Rev. Phys. Chem. 47 (1996) p. 421.CrossRefGoogle Scholar
5.Russel, W.B., Saville, D.A., and Schowalter, W.R., Colloidal Dispersions, Cambridge Monographs on Mechanics and Applied Mathematics (Cambridge University Press, Cambridge, 1991).Google Scholar
6. For example, see Crocker, J.C. and Grier, D.G., Phys. Rev. Lett. 73 (2) (1994) p. 352; For example, see J.C. Crocker and D.G. Grier, Phys. Rev. Lett. 77 (9) (1996) p. 1897.CrossRefGoogle Scholar
7.Angell, C., Clarke, J., and Woodcock, L., Adv. Chem. Phys. 48 (1981) p. 397.CrossRefGoogle Scholar
8.Baus, M. and Hansen, J., Phys. Rep. 59 (1980) p. 1.CrossRefGoogle Scholar
9.Robbins, M.O., Kremer, K., and Grest, G.S., J. Chem. Phys. 88 (5) (1988) p. 3286.CrossRefGoogle Scholar
10.Pusey, P. and van Megan, W., in Physics of Complex and Supramolecular Fluids, edited by Safran, S. and Clark, N. (John Wiley & Sons, New York, 1987) p. 673.Google Scholar
11.Monovoukas, Y. and Gast, A.P., J. Colloid I. Sci. 128 (2) (1989) p. 533; E.B. Sirota, H. Ou-Yang, S. Sinha, P. Chaikin, J. Axe, and Y. Fujii, Phys. Rev. Lett. 62 (13) (1989) p. 1524.CrossRefGoogle Scholar
12.Dickenson, E. and Parker, R., J. Phys. Lett. 46 (1985) p. L229.CrossRefGoogle Scholar
13.Van Winkle, D. and Murray, C., J. Chem. Phys. 89 (1988) p. 3885.CrossRefGoogle Scholar
14.Aastuen, D., Clark, N., Cottier, L., and Ackerson, B., Phys. Rev. Lett. 57 (1986) p. 1733.CrossRefGoogle Scholar
15.Ackerson, B. and Clark, N., Phys. Rev. Lett. 46 (1981) p. 123.CrossRefGoogle Scholar
16.Grier, D.G. and Murray, C., J. Chem. Phys. 100 (12) (1994) p. 9088.CrossRefGoogle Scholar
17.Hansen, J.P. and Verlet, L., Phys. Rev. 184 (1969) p. 151.CrossRefGoogle Scholar
18.Lindemann, F., Phys. Z. 11 (1910) p. 609.Google Scholar
19.Van Winkle, D. and Murray, C., Phys. Rev. A 34 (1986) p. 562.CrossRefGoogle Scholar
20.Pansu, B., Pieranski, P., and Strzelecki, L., J. Phys. France 44 (1984) p. 531; P. Pieranski, L. Strzelecki, and B. Pansu, Phys. Rev. Lett. 50 (1983) p. 900.CrossRefGoogle Scholar
21.Schmidt, M. and Lowen, H., J. Phys. France 76 (1996) p. 4552; S. Neser, C. Bechinger, P. Leiderer, and T. Palberg, J. Phys. France 79 (1997) p. 2348.Google Scholar
22.Dubin, D., J. Phys. France 71 (1993) p. 2753.Google Scholar
23.Neser, S., Palberg, T., Bechinger, C., and Leiderer, P., Prog. Colloid Polym. Sci. 104 (1997) p. 194; C. Murray, J. Cerise, and W. Sprenger (unpublished).CrossRefGoogle Scholar
24.Murray, C., Sprenger, W., Seshadri, R., and Cerise, J., in Dynamics in Small Confining Systems II, edited by Drake, J.M., Klafter, J., Kopelman, R., and Troian, S.M. (Mater. Res. Soc. Symp. Proc. 366, Pittsburgh, 1995) p. 163.Google Scholar
25.Strandburg, K., Bond Order in Condensed Matter Systems (Springer-Verlag, New York, 1991).Google Scholar
26.Chou, T. and Nelson, D.R., Phys. Rev. E 48 (1993) p. 4611.Google Scholar
27. This was first pointed out by Rice, S. (private communication).Google Scholar
28.Chou, T. and Nelson, D.R., Phys. Rev. E 53 (1996) p. 2560; P. Bladon and D. Frenkel, Phys. Rev. Lett. 74 (1995) p. 2519.Google Scholar
29.Murray, M. and Sanders, J., Philos. Mag. A42 (1980) p. 721.CrossRefGoogle Scholar
30. For example, see Yoshimura, S. and Hachisu, S., Prog. Colloid Polym. Sci. 68 (1983) p. 59; A. Dinsmore, A.G. Yodh, and D. Pine, Phys. Rev. E 52 (1995) p. 4045.CrossRefGoogle Scholar
31.Dinsmore, A., Yodh, A.G., and Pine, D., Nature 383 (1996) p. 239.CrossRefGoogle Scholar
32.van Blaaderen, A., Ruel, R., and Wiltzius, P., Nature 385 (1997) p. 321.CrossRefGoogle Scholar
33.Dufresne, E.R. and Grier, D.G., Rev. Sci. Instr. 69 (1998) p. 1974.CrossRefGoogle Scholar
34. For example, see Adams, M., Dogic, Z., Keller, S.L., and Fraden, S., “Phases Created in a Bidisperse Suspension of Spheres and Rods,” Nature 393 (1998) p. 349.CrossRefGoogle Scholar