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Advances in actinide solid-state and coordination chemistry

Published online by Cambridge University Press:  31 January 2011

Peter C. Burns ,
Yasuhisa Ikeda  and
Ken Czerwinski
Peter C. Burns
Affiliation:
Department of Civil Engineering and Geological Sciences, University of Notre Dame, IN 46556, USA; pburns@nd.edu
Yasuhisa Ikeda
Affiliation:
Laboratory for Nuclear Reactors at Tokyo Institute of Technology, Japan; yikeda@nr.titech.ac.jp
Ken Czerwinski
Affiliation:
University of Nevada, Las Vegas, NV 89154, USA; ken.czerwinski@unlv.edu
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Abstract

Actinide solid-state and coordination chemistry has advanced through unexpected results that have further revealed the complex nature of the 5f elements. Nanoscale control of actinide materials is emerging, as shown by the creation of a considerable range of cluster and tubular topologies. Departures from established structural trends for actinyl ions are provided by cation-cation interactions in which an O atom of one actinyl ion is an equatorial ligand of a bipyramid of another actinyl ion. The solid-state structural complexity of actinide materials has been further demonstrated by open framework materials with interesting properties. The U(VI) tetraoxide core has been added to this cation's repertoire of coordination possibilities. The emergence of pentavalent uranium solid-state and coordination chemistry has resulted from the prudent selection of ligands. Finally, analogues of the uranyl ion have challenged our understanding of this normally unreactive functional group.

Type
Research Article
Information
MRS Bulletin , Volume 35 , Issue 11: Emerging areas of actinide science , November 2010 , pp. 868 - 876
Copyright
Copyright © Materials Research Society 2010

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