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Synthesis and Characterization of Cordierite, Mullite and Cordierite-Mullite Ceramic Materials using Coal Fly Ash as Raw Material

Published online by Cambridge University Press:  09 January 2018

J. López-Cuevas ,
E. Interial-Orejón ,
C.A. Gutiérrez-Chavarría  and
J.C. Rendón-Ángeles
J. López-Cuevas*
Affiliation:
CINVESTAV-IPN, Unidad Saltillo, Calle Industria Metalúrgica No. 1062, Parque Industrial Saltillo - Ramos Arizpe, Ramos Arizpe, Coahuila, México, CP 25900
E. Interial-Orejón
Affiliation:
CINVESTAV-IPN, Unidad Saltillo, Calle Industria Metalúrgica No. 1062, Parque Industrial Saltillo - Ramos Arizpe, Ramos Arizpe, Coahuila, México, CP 25900
C.A. Gutiérrez-Chavarría
Affiliation:
CINVESTAV-IPN, Unidad Saltillo, Calle Industria Metalúrgica No. 1062, Parque Industrial Saltillo - Ramos Arizpe, Ramos Arizpe, Coahuila, México, CP 25900
J.C. Rendón-Ángeles
Affiliation:
CINVESTAV-IPN, Unidad Saltillo, Calle Industria Metalúrgica No. 1062, Parque Industrial Saltillo - Ramos Arizpe, Ramos Arizpe, Coahuila, México, CP 25900
*
*Corresponding author; Tel. +52 844 4389600; E-mail address: jorge.lopez@cinvestav.edu.mx
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Abstract

Cordierite (Mg2Al4Si5O18), Mullite (Al4+2xSi2-2xO10-x) and Cordierite-Mullite ceramic materials were obtained from a stoichiometric mixture of coal fly ash (CFA) as a source of SiO2 and Al2O3, plus high-purity MgO and Al2O3. The starting stoichiometric mixtures were homogenized, and then uniaxially pressed, cold isostatically pressed, and sintered at 1200-1600 °C for 2-5 h. The sintered materials were characterized by X-ray diffraction, scanning electron microscopy, Vickers microhardness, density and four-point flexural strength. In general, the desired phases tended to form in the composites at temperatures of 1350 or 1400 °C, with a considerable amount of glassy phase developing from 3 h onwards at one of those two temperatures, depending on the composite composition. The microstructure of the composites consisted of a matrix of Cordierite and interwoven needles of Mullite. The bulk density decreased, while the flexural strength and the Vickers microhardness increased with increasing nominal content of Mullite in the composites. A synergistic effect taking place between Cordierite and Mullite enhances the mechanical properties of the composites.

Keywords

ceramicchemical synthesiscomposite
Type
Articles
Information
MRS Advances , Volume 2 , Issue 62: International Materials Research Congress XXVI , 2017 , pp. 3865 - 3872
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Copyright © Materials Research Society 2018 

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