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Weissite from Gambatesa mine, Val Graveglia, Liguria, Italy: occurrence, composition and determination of the crystal structure

Published online by Cambridge University Press:  05 July 2018

L. Bindi ,
C. Carbone ,
D. Belmonte ,
R. Cabella  and
R. Bracco
L. Bindi*
Affiliation:
Dipartimento di Scienze della Terra, Università degli Studi di Firenze, Via G. La Pira 4, I-50121 Florence, Italy CNR – Istituto di Geoscienze e Georisorse, Sezione di Firenze, Via G. La Pira 4, I-50121 Florence, Italy
C. Carbone
Affiliation:
Dipartimento di Scienze della Terra, dell’Ambiente e della Vita, Università degli Studi di Genova, Corso Europa 26, I-16132 Genoa, Italy
D. Belmonte
Affiliation:
Dipartimento di Scienze della Terra, dell’Ambiente e della Vita, Università degli Studi di Genova, Corso Europa 26, I-16132 Genoa, Italy
R. Cabella
Affiliation:
Dipartimento di Scienze della Terra, dell’Ambiente e della Vita, Università degli Studi di Genova, Corso Europa 26, I-16132 Genoa, Italy
R. Bracco
Affiliation:
Via Montenotte 18, I-17100 Savona, Italy
*
* E-mail: luca.bindi@unifi.it
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Abstract

Weissite, Cu2–xTe (x ≈ 0.21), a very rare copper telluride, occurs in a sample from the Gambatesa mine, Val Graveglia, Liguria, Italy, where it occurs as purplish black anhedral grains up to 0.1 mm in length and shows a black streak. No cleavage is observed and the Vickers hardness (VHN100) is 142 kg/mm2. Weissite is dark bluish black, weakly pleochroic, and moderately anisotropic in bluish tints. Reflectance percentages in air for Rmin and Rmax are 37.0, 38.4 (471.1 nm), 33.2, 34.2 (548.3 nm), 31.2, 32.1 (586.6 nm), and 28.6, 31.0 (652.3 nm), respectively.

Weissite is trigonal and belongs to the space group P3m1 with the following unit-cell parameters: a = 8.3124(7) Å, c = 21.546(1) Å, V = 1289.3(2) Å3, and Z = 24. Electron microprobe analyses gave the chemical formula (Cu1.62Ag0.04Au0.04Fe0.04Sb0.04)Σ=1.78(Te0.96S0.02Se0.02). The crystal structure has been solved and refined to R = 1.95%. It consists of Cu and Te polyhedra forming complex crystal-chemical environments as is typical of many intermetallic compounds. The exceedingly short bond distances observed among the metals are discussed in relation to other copper tellurides and pure metals.

Keywords

weissitevulcaniterickarditetelluridesVal GravegliaItaly
Type
Research Article
Information
Mineralogical Magazine , Volume 77 , Issue 4 , June 2013 , pp. 475 - 483
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2013

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Structure factors

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Bond distances

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