Hostname: page-component-848d4c4894-cjp7w Total loading time: 0 Render date: 2024-06-17T14:26:23.595Z Has data issue: false hasContentIssue false

Two contrasting mineral assemblages in the Meliata blueschists, Western Carpathians, Slovakia

Published online by Cambridge University Press:  05 July 2018

S. W. Faryad
Affiliation:
Institute of Crystallography, Mineralogy and Petrology, University of Graz, Universitätplatz 2, 0811 Graz, Austria
G. Hoinkes
Affiliation:
* Department of Geology and Mineralogy, Technical University Košice, Letná 9, 04200 Košice, Slovakia

Abstract

Low-grade metamorphic rocks from the Meliata unit (Western Carpathians) are characterized by the presence of typical blueschist-facies minerals. In metabasalt, an early low-pressure assemblage (<0.5 GPa at 350°C characterized by muscovite and zoisite, is followed by high-pressure glaucophane, phengite, Na-pyroxene, chlorite, clinozoisite and Al-poor titanite, indicating pressures of >1.2 GPa at 450°C Na-pyroxene shows strong compositional variations between the end-members Jd4–70, Aeg10–49 and Q17–49, respectively. Phengite has high Si content of 3.5 a.p.f.u. The zoisite with Al2Fe (100[Fetot/(−2+Altot+Fetot)]) = 3–5%, is rimmed by clinozoisite, with a maximum of 75% Al2Fe, as well as being enclosed by glaucophane. The occurrence of clinozoisite, rimming zoisite, suggests that the transformation of orthorhombic to monoclinic epidote depends not only on the temperature but also on the pressure. In the studied metabasalt, retrograde phases reflecting greenschist-facies conditions are albite and chlorite. Some neighbouring metabasites may additionally contain actinolite and biotite.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

*

Address for correspondence

References

Black, P.M. (1977) Regional high-pressure metamorphism in New Caledonia: phase equilibria in the Ouégoa District. Tectonophys., 43, 89107.CrossRefGoogle Scholar
Berman, R.G. (1988) Internally-consistent thermodynamic data for minerals in the system Na2O-K2O- CaO-MgO-FeO-Fe2O3-Al2O3-SiO2-TiO2-H2O-CO2 . J. Petrol., 29, 445–522.CrossRefGoogle Scholar
Dallmeyer, R.D., Neubauer, F., Fritz, H. and Putis, M. (1994) Variscan vs. Alpine tectonothermal evolution within the Eastern Alps and Western Carpathians, Austria-Slovakia. J. Czech Geol Soc., 39, 120–1.Google Scholar
Enami, M. and Banno, S. (1980) Zoisite-clinozoisite relations in low- to medium-grade high-pressure metamorphic rocks and their implications. Mineral. Mag., 3, 1005–13.CrossRefGoogle Scholar
Ernst., G. (1971) Do mineral parageneses reflect unusually high-pressure conditions of the Franciscan metamorphism. Amer. J. Sci., 270, 81108.CrossRefGoogle Scholar
Evans, B.W. (1990) Phase relations of epidote-blueschists. Lithos, 25, 323.CrossRefGoogle Scholar
Faryad, S.W. (1995 a) Phase petrology and P-T conditions of mafic blueschists from the Meliata unit, Western Carpathians, Slovakia. J. Metam. Geol., 13, 701–14.CrossRefGoogle Scholar
Faryad, S.W. (1995 b) Petrology and phase relations of low-grade high-pressure metasediments from the Meliata unit, Western Carpathians, Slovakia. Eur. J. Mineral, 7, 7187.CrossRefGoogle Scholar
Faryad, S.W. and Henjes-Kunst, F. (1997) K-Ar and Ar-Ar age constraints of the Meliata blueschist facies rocks, the Western Carpathians (Slovakia). Tectonophys., 280, 141–56.CrossRefGoogle Scholar
Franz, G. and Selverstone, J. (1992) An empirical phase diagram for the clinozoisite-zoisite transformation in the system Ca2Al3Si3O12(OH)-Ca2Al2Fe3+-Si3O12(OH ). Amer. Mineral., 77, 631–42.Google Scholar
Ghent, E.D and Stout, M.Z. (1994) Geobarometry of low-temperature eclogites: applications of isothermal pressure-activity calculations. Contrib. Mineral. Petrol., 116, 500–7.CrossRefGoogle Scholar
Heinrich, W. and Althaus, E. (1988) Experimental determination of the reactions 4 Lws + Ab = Prg + 2 Zo + 2 Qtz + 6 W and 4 Lws + Jd = Prg + 2 Zo + Qtz + 6 W. Neues Jahrb. Mineral Abh., 11, 516–28.Google Scholar
Holland, T.J.Band Powell, R. (1990) An enlarged and updated internally consistent thermodynamic dataset with certainties and correlations: the system K2O-Na2O-CaO-MgO-MnO-FeO-Fe2O3-Al2O3-TiO2-SiO2-C-H2-O2 . J. Metam. Geol., 8, 89–124.CrossRefGoogle Scholar
Holland, T. and PowelI, R. (1996) Thermodynamics of order-disorder in minerals: II. Symmetric lbrmalism applied to solid solution. Amer. Mineral., 81, 1425–37.CrossRefGoogle Scholar
Hovorka, D., Ivan, P., Jaroš, J., Kratochviíl, M., Reichwalder, P., Rojkovič, I. Spigiak, J. and Turanová, L. (1985) Ultramafic Rocks of the Western Carpathians, Czechoslovakia. Geol. Inst. Dionýz štúr, Bratislava, 258 p.Google Scholar
Kozur, H. and Mock, R. (1996) New paleogeographic and tectonic interpretations in the Slovakian Carpathians and their implications for correlations with the Eastern Alps. Part I: Central Western Carpathians. Mineralia Slovaca, 28, 151–74.Google Scholar
Liu, J. and Bohlen, S.R. (1995) Mixing properties and stability of jadeite-acmite pyroxene in the presence of albite and quartz. Contrib. Mineral. Petrol., 119, 433 -40.CrossRefGoogle Scholar
Maluski, H, Rajlich, P. and Matte, Ph. (1993) 40Ar/39 Ar dating of the Inner Carpathian Variscan Basement and Alpine mylonitic overprinting. Tectonophys., 223, 313–37.CrossRefGoogle Scholar
Maryuama, S. and Liou, J. (1988) Petrology of Franciscan metabasites along the jadeite-glaucophane type facies series, Cazdero, California. J. Petrol., 29, 137.CrossRefGoogle Scholar
Massonne, H.J. and Schreyer, W. (1987) Phengite geobarometry based on the limiting assemblage with K-feldspar, phlogopite, and quartz. Contrib. Mineral. Petrology, 96, 212–24.CrossRefGoogle Scholar
Miller, Ch. (1990) Petrology of type locality eclogites from the Korealpe and Saualpe (Eastena Alps), Austria. Schweiz. Mineral. Petrogr. Mitt., 70, 287300.Google Scholar
Morimoto, N. (1988) Nomenclature of pyroxenes. Schweiz. Mineral. Petrogr. Mitt., 68, 95111.Google Scholar
Prunier, A.R and Hewitt, D.A. (1985) Experimental observations on coexisting zoisite-clinozoisite. Amer. Mineral., 70, 375–8.Google Scholar
Reichwalder, P. (1973) Geologische Verhäiltnisse des jüngeren Paläiozoikums im Süd Teil des Zips-Gemerer Erzgebirges. Západné Karpaty, 18, 99139, Geol. Inst. D. štúr, Bratislava.Google Scholar
Selverstone, J., Spear, F.S., Franz, G. and Morteani, G. (1984) High-pressure metamorphism in the SW Tauern Window, Austria: P-T paths from hornblende-kyanite-staurolite schists. J. Petrol 25, 501–31.CrossRefGoogle Scholar