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Mercurian sphalerite from Akoluk deposit (Ordu, NE Turkey): Hg as a cathodoluminescence activator

Published online by Cambridge University Press:  05 July 2018

E. Çiftçi
E. Çiftçi*
Affiliation:
Nigde University, Department of Geological Engineering, 51245 Nigde, Turkey
*
* E-mail: eciftci@nigde.edu.tr
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Abstract

A recent investigation of sphalerite from Akoluk deposit, Ordu, NE Turkey, revealed the possible presence of a new activator element in the sphalerite structure. The sample was studied under a reflected light microscope coupled with a cold-stage cathodoluminescence (CL) system which revealed a unique banding in the sphalerite. The same sample was subsequently examined using the backscattered electron and luminescence modes in an electron microscope, the results of which were later confirmed in terms of chemical composition by electron probe microanalyses (EPMA). Detailed evaluation of the EPMA data indicated the presence of a new CL activator element in the sphalerite structure. The data also indicate that Hg2+ in the sphalerite crystal structure substitutes for Zn in a simple manner and for Cd and Cu in a coupled manner. Spectral analysis indicated a bright yellow and orange-red blend (more like brown) CL colour with λmax centred at 580 nm, probably due to Cd and Mn ions, and relatively broad emission bands ranging from 525 to 690 nm with λmax centred at 580 and 700, due probably to Cu, Cd and Hg. This study reports that Hg in the sphalerite crystal lattice behaves as an activator and/or co-activator element resulting in emissions of CL colours that range from yellow with purple shades to shades of brown, based on their varying contents.

Keywords

sphaleritemercuryactivatorAkolukcathodoluminescenceTurkey.
Type
Research Article
Information
Mineralogical Magazine , Volume 73 , Issue 2 , April 2009 , pp. 257 - 267
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2009

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References

Benedetto, F.D., Bernardini, G.P., Costagliola, P., Plant, D. and Vaughan, D.J. (2005) Compositional zoning in sphalerite crystals. American Mineralogist, 90, 1384-1392.CrossRefGoogle Scholar
Çifçfi, E. (2000) Mineralogy, paragenetic sequence, geochemistry and genesis of the gold and silver bearing Upper Cretaceous mineral deposits, northeastern Turkey. PhD Dissertation (unpublished), University of Missouri-Rolla, Missouri, USA. 251 pp.Google Scholar
Dini, A., Benvenuti, M., Costagliola, P. and Lattanzi, P. (2001) Mercury deposits in metamorphic settings: the example of Levigliani and Ripa mines, Apuane Alps (Tuscany, Italy). Ore Geology Reviews, 18, 149-167.CrossRefGoogle Scholar
Goni, J. and R^mond, G. (1969) Localization and distribution of impurities in blende by cathodolumi- nescence. Mineralogical Magazine, 37, 153-155.CrossRefGoogle Scholar
Götze, J. (2002) Potential of cathodoluminescence (CL) microscopy and spectroscopy for the analysis of minerals and materials. Analytical and Bioanalytical Chemistry, 374, 703-708.Google ScholarPubMed
Grammatikopoulos, T.A., Valeyev, O. and Roth, T. (2006) Compositional variation in Hg-bearing sphalerite from the polymetallic Eskay Creek deposit, British Columbia, Canada. Chemie der Erde, 66, 307-314.CrossRefGoogle Scholar
Gumlich, H.E. and Reihl, N. (1971) Phosphore der ZnS- Gruppe (II-IV-Verbindungen). Pp. 35-109 in: Einführung in die Lumineszenz (N. Reihl, editor). Karl Thiemig, Miinchen, Germany.Google Scholar
Haberlandt, H. and Schroll, E. (1950) Lumineszierende Anwachszonen in der Zinkblende von Bleiberg- Kreuth (Karnten, Österreich). Experientia, V1, 91-92.CrossRefGoogle Scholar
Johan, Z. (1988) Indium and germanium in the structure of sphalerite: an example of coupled substitution with copper. Mineralogy and Petrology, 39, 211-229.CrossRefGoogle Scholar
Karakus, M. (2006) Cathodoluminescence microscopy and spectroscopy characterization of refractory and advanced structural ceramics. Pp. 330-334 in: UNITECR ‘05 - Proceedings of the Unified International Technical Conference on Refractories: 9th Biennial Worldwide Congress on Refractories, 8-11 November 2005. Orlando, Florida USA (J.D. Smith, editor). J. Wiley & Sons.Google Scholar
Karakus, M., Hagni, R.D., Koenig, A. and Çifçfi, E. (2008) Cathodoluminescence, laser ablation inductively coupled plasma mass spectrometry, electron probe microanalysis and electron paramagnetic resonance analyses of natural sphalerite. Pp. 112-124 in: ICAM 2008 Proceedings, Brisbane, Australia. The Australasian Institute of Mining and Metallurgy, Victoria, Australia.Google Scholar
Kazanskii, S.A., Ryskin, A.I. and Khil’ko, G.I. (1969) Effect of bonding character on the spectra of Co2+ and Ni2+ ions in ZnS crystals containing stacking faults. Soviet Physics - Solid State, 10, 1899-1902.Google Scholar
Kuhlemann, J. and Zeeh, S. (1995) Sphalerite stratigraphy and trace element composition of East Alpine Pb-Zn deposits (Drau Range, Austria-Slovenia). Economic Geology, 90, 2073-2080.CrossRefGoogle Scholar
Kuhlemann, J., Vennemann, T., Herlec, U., Zeeh, S., and Bechstadt, T. (2001) Variations of sulfur isotopes, trace element compositions, and cathodo- luminescence of Mississippi Valley-type Pb-Zn ores from the Drau Range, eastern Alps (Slovenia- Austria): implications for ore deposition on a regional versus microscale. Economic Geology, 96, 1931-1941.Google Scholar
Kyle, J.R. and Price, P.E. (1985) Mineralogical investigation of sulfide concentrations in the Hockley salt dome cap rock, Texas. Pp. 1065-1082 in: Applied Mineralogy (W.C. Park et al., editors). Metallurgical Society of the AIME.Google Scholar
Laubach, S.E., Reed, R.M., Olson, J.E., Lander, R.H. and Bonnell, L.M. (2004) Co-evolution of crack-seal texture and fracture porosity in sedimentary rocks: cathodoluminescence observations of regional fractures. Journal of Structural Geology, 26, 967-982.CrossRefGoogle Scholar
Leverenz, H.W. (1968) An Introduction to Luminescence of Solids. Dover Publications, New York.Google Scholar
Marfunin, A.S. (1979) Spectroscopy Luminescence and Radiation Centers in Minerals. Springer-Verlag, Berlin, 352 pp.CrossRefGoogle Scholar
Marshall, J.D. (1988) Cathodoluminescence of Geological Materials. Unwin Hyman, London, 146 pp.Google Scholar
McKeag, A.H. and Steward, E.G. (1957) Effect of crystal disorder on the electroluminescence of zinc sulfide phosphors. Journal of the Electrochemical Society, 104, 41-45.CrossRefGoogle Scholar
Onasch, C.M. and Davis, T.L. (1988) Strain determination using cathodoluminescence of calcite overgrowths. Journal of Structural Geology, 10, 301-303.CrossRefGoogle Scholar
Pattrick, R.A., Dorling, M. and Poyla, D.A. (1993) TEM study of indium and copper-bearing growth- banded sphalerite. The Canadian Mineralogist, 31, 105-117.Google Scholar
Picot, P. and Johan, Z. (1982) Atlas of Ore Minerals. Elsevier, Amsterdam, 458 pp.Google Scholar
Platanov, A.N. and Tarashchan, A.N. (1967) Red photoluminescence in natural sphalerites. Doklady Akademii Nauk, 177, 415-417.Google Scholar
Rager, H., Amthauer, G., Bernroider, M. and Schurmann, K. (1996) Colour, crystal chemistry, and mineral association of a green sphalerite from Steinperf, Dill Syncline, FRG. European Journal of Mineralogy, 8, 1191-1198.CrossRefGoogle Scholar
Ramseyer, K., Aldahan, A.A., Collini, B. and Landstrom, O. (1992) Petrological modifications in granitic rocks from the Siljan impact structure: evidence from cathodoluminescence. Tectonophysics, 216, 195-204.CrossRefGoogle Scholar
Ryall, W.R. (1979) Mercury in Broken Hill (NSW, Australia) lead-zinc-silver lodes. Journal of Geochemical Exploration, 11,175-194.CrossRefGoogle Scholar
Rytuba, J.J. (2003) Mercury from mineral deposits and potential environmental impact. Environmental Geology, 43, 326-338.CrossRefGoogle Scholar
Spalek, J., Lewicki, A., Tarnawski, Z., Furdyna, J.K., Galazka, R.R. and Obuszko, Z. (1986) Magnetic susceptibility of semimagnetic semiconductors: the high-temperature regime and the role of superexchange. Physical Reviews (B), 33, 3407-3418.CrossRefGoogle ScholarPubMed
Stirling, D., Duncan, A.M., Guest, J.E. and Finch, A.A. (1999) Petrogenesis of plagioclase phenocrysts of Mount Etna, Sicily, with particular reference to the 1983 eruption: Contribution from cathodolumines- cence petrography. Mineralogical Magazine, 63, 189-198.CrossRefGoogle Scholar
Tarashchan, A.N. and Platonov, A.N. (1968) Luminescence spectra of sphalerites. Geokhimiya, 2, 173-179.Google Scholar
Thomas, C.A., Hagni, R.D. and Berendsen, P. (1991) Ore microscopy of the Paoli silver-copper deposit, Oklahoma. Ore Geology Reviews, 6, 229-244.CrossRefGoogle Scholar
Wallace, M.W., Both, R.A., Ruano, S.M., Hach-Ali, P.F. and Lees, T. (1994) Zebra textures from carbonate- hosted sulfide deposits: sheet cavity networks produced by fracture and solution enlargement. Economic Geology, 89, 1183-1191.CrossRefGoogle Scholar
Zeeh, S. and Kuhlemann, J. (1996) Luminescence and geochemical composition of sphalerite: an example from the Alpine lead-zinc deposits (Austria/ Slovenia). Pp. 171-172 in: International Conference on Cathodoluminescence and Related Techniques in Geosciences and Geomaterials: Nancy, France, Abstracts. Google Scholar