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Infrared reflectance of single-crystal jarandolite, CaB3O4(OH)3

Published online by Cambridge University Press:  05 July 2018

P. M. Nikolić ,
S. Đurić ,
K. M. Paraskevopoulos ,
T. T. Zorba ,
D. Luković ,
S. Savić ,
V. Blagojević  and
M. V. Nikolić
P. M. Nikolić*
Affiliation:
Institute of Technical Science of SASA, Knez Mihailova 35/IV, P.Box 315, 11000 Belgrade, Serbia
S. Đurić
Affiliation:
Institute of Technical Science of SASA, Knez Mihailova 35/IV, P.Box 315, 11000 Belgrade, Serbia
K. M. Paraskevopoulos
Affiliation:
Physics Department, Solid State Section, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece
T. T. Zorba
Affiliation:
Physics Department, Solid State Section, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece
D. Luković
Affiliation:
Institute of Technical Science of SASA, Knez Mihailova 35/IV, P.Box 315, 11000 Belgrade, Serbia
S. Savić
Affiliation:
Institute of Technical Science of SASA, Knez Mihailova 35/IV, P.Box 315, 11000 Belgrade, Serbia
V. Blagojević
Affiliation:
Faculty of Electronic Engineering, University of Belgrade, Bulevar Kralja Aleksandra 73, 11000 Belgrade, Serbia
M. V. Nikolić
Affiliation:
Centre for Multidisciplinary Studies of the University of Belgrade, Kneza Viseslava 1, 11000 Belgrade, Serbia
*
*E-mail: nikolic@sanu.ac.yu
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Abstract

Polarized far- and mid-infrared reflectance spectra were measured at room temperature for the new mineral species jarandolite, CaB3O4(OH)3, for the two principal directions. Thirty three vibration modes for and 32 for were observed and analysed numerically. Symmetry analysis predicts 41 and 40 vibration modes that include lattice and O–H modes. Mode assignment was made based on the structure of jarandolite. The values of the mode frequencies (ωTO), the damping factors (γ) and the oscillator strength (S) of each oscillator were obtained by fitting to a Lorentz model.

Keywords

jarandoliteIR reflectance spectraLorentz model
Type
Research Article
Information
Mineralogical Magazine , Volume 71 , Issue 3 , June 2007 , pp. 273 - 283
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2007

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