Hostname: page-component-84b7d79bbc-lrf7s Total loading time: 0 Render date: 2024-07-26T18:10:42.810Z Has data issue: false hasContentIssue false
  • English
  • Français

Effect of competition from other metals on nickel complexation by α-isosaccharinic, gluconic and picolinic acids

Published online by Cambridge University Press:  05 July 2018

N. D. M. Evans ,
S. Antón Gascón ,
S. Vines  and
M. Felipe-Sotelo
N. D. M. Evans*
Affiliation:
Loughborough University, Ashby Road, Loughborough NG9 1DN, UK
S. Antón Gascón
Affiliation:
Loughborough University, Ashby Road, Loughborough NG9 1DN, UK
S. Vines
Affiliation:
Nuclear Decommissioning Authority, Radioactive Waste Management Directorate, NDA Harwell Office, Building 587, Curie Avenue, Harwell, Didcot, Oxfordshire OX11 0RH, UK
M. Felipe-Sotelo
Affiliation:
Loughborough University, Ashby Road, Loughborough NG9 1DN, UK
*
*E-mail: n.d.m.evans@lboro.ac.uk
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

The effect of competition from other metal ions on the complexation of Ni with isosaccharinic acid, gluconic acid and picolinic acid, at high pH, is described. The competing metal ions used were divalent Co, trivalent Eu and tetravalent Th. In the majority of cases, competition from these metal ions followed the predicted pattern, with most anomalies seeming to be caused by sorption of Ni to the many different solid phases formed in presence of the competing ions. The Ni solid phase was shown to change with time during the course of the study. No major unexplained competition effects were found.

Keywords

modellingengineered barriereuropiumisosaccharinic acidgluconic acidpicolinic acidnickelradionuclide transportthorium
Type
Research Article
Information
Mineralogical Magazine , Volume 76 , Issue 8 , December 2012 , pp. 3425 - 3434
Creative Commons
Creative Common License - CCCreative Common License - BY
© [2012] The Mineralogical Society of Great Britain and Ireland. This is an open access article distributed under the terms of the Creative Commons Attribution (CC BY) licence (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2012

References

Arcos, D., Hernán, P., de la Cruz, B., Herbert, H.-J., Savage, D., Smart, N.R., Villar, M.V. and Van Loon, L.R. (2003) NF-PRO RTDC-2 Synthesis Report. Deliverable (D-No: D2.6.4) EU NF-PRO, Project FI6W-CT-2003-02389.Google Scholar
Bath, A.H., Christofi, N., Neal, C., Philip, J.C., Cave, M.R., McKinley, I.G. and Berner, U. (2010) Trace element and microbiological studies of alkaline groundwaters in Oman, Arabian Gulf: a natural analog for cement pore-waters. Geomicrobiology Journal, 27, 225–230.Google Scholar
Bond, K.A., Heath, T.G. and Tweed, C.J. (1997) HATCHES: A Referenced Thermodynamic Database for Chemical Equilibrium Studies. UK Nirex Ltd Report NSS/R379.Google Scholar
Dey, G. R., Naik, D. B., Kishore, K. and Moorthy, P. N. (1992) Efficacy and radiation stability of some decontaminant formulations. Water Chemistry of Nuclear Reactor Systems, 6, 312–313.Google Scholar
Evans, N.D.M. and Heath, T.G. (2004) The Development of a Strategy for the Investigation of Detriments to Radionuclide Sorption in the Geosphere. Nirex Report SA/ENV-0611.Google Scholar
Nirex (2003) Generic Repository Studies: The Phased Disposal Concept. Nirex Report N/074.Google Scholar
Pernin, C.G. and Ibers, J.A. (1997) The new octanuclear europium cluster Eu8(DMF)13(m4-O)(m3-OH)12 (Se3)(Se4)2(Se5)2 comprising oxo, hydroxo, and polyselenidoligands. Inorganic Chemistry, 36, 3802–3803.Google Scholar
Tweed, C. (2012) Sound science in geological disposal in the United Kingdom. Mineralogical Magazine, 76, 2873–287.Google Scholar
Van der Lee, J. (2003) A Users Guide to CHESS, Another Speciation and Surface Complexation Computer Code. E´ cole des Mines de Paris, Fontainebleau, France.Google Scholar
Warwick, P., Evans, N.D.M., Hall, A. and Vines, S. (2003) Complexation of Ni(II) by a-isosaccharinic acid and gluconic acid from pH 7 to pH 13. Radiochimica Acta, 91, 233–240.CrossRefGoogle Scholar
Whistler, R.L. and BeMiller, J.N. (1958) Alkaline degradation of polysaccharides. Pp. 289–329.in: Advances in Carbohydrate Chemistry, Volume 13 (M.L. Wolfrom and R.S. Tipson, editors). Academic Press, New York.Google Scholar