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Crystal-chemical characterisation and spectroscopy of fluorcarletonite and carletonite

Published online by Cambridge University Press:  03 March 2023

Ekaterina Kaneva Open the ORCID record for Ekaterina Kaneva [Opens in a new window] ,
Alexander Bogdanov Open the ORCID record for Alexander Bogdanov [Opens in a new window] ,
Tatiana Radomskaya Open the ORCID record for Tatiana Radomskaya [Opens in a new window] ,
Olga Belozerova  and
Roman Shendrik Open the ORCID record for Roman Shendrik [Opens in a new window]
Ekaterina Kaneva*
Affiliation:
Vinogradov Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences, Favorsky Str. 1A, 664033, Irkutsk, Russia
Alexander Bogdanov
Affiliation:
Vinogradov Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences, Favorsky Str. 1A, 664033, Irkutsk, Russia
Tatiana Radomskaya
Affiliation:
Vinogradov Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences, Favorsky Str. 1A, 664033, Irkutsk, Russia
Olga Belozerova
Affiliation:
Vinogradov Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences, Favorsky Str. 1A, 664033, Irkutsk, Russia
Roman Shendrik
Affiliation:
Vinogradov Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences, Favorsky Str. 1A, 664033, Irkutsk, Russia
*
*Corresponding author: Ekaterina Kaneva; Email: kev604@mail.ru
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Abstract

The minerals of carletonite group, fluorcarletonite, KNa4Ca4[Si8O18](CO3)4(F,OH)·H2O and carletonite, Na4Ca4[Si8O18](CO3)4(OH,F)·H2O, were investigated using a multi-method approach. A detailed comparative chemical study of the minerals was carried out using electron probe microanalysis and Fourier transform infrared spectroscopy. Using X-ray techniques and the results obtained, geometrical and distortion characteristics of the mineral structures are calculated and the successful crystal-structure refinement of these two natural compounds are given. Using spectroscopic and luminescence methods and ab initio calculations, it is shown that hole defects (CO3)•– are responsible for the colouration of the samples studied. Luminescence due to 5d–4f transition in Ce3+ ions is observed in both investigated compounds. Moreover, luminescence attributed to intrinsic luminescence, corresponding to the decay of electronic excitations of (CO3)2– complexes in the carletonite sample, is registered for the first time in phyllosilicates. An analysis of the optical absorption spectra and g-tensor values suggests that (CO3)•– defects in the crystal structure are localised in the C1 positions. Identification of these specific properties for these sheet silicates, with a two-dimensional infinite tetrahedral polymerisation, indicates that carletonites could be prospective materials for novel phosphors and luminophores.

Keywords

phyllosilicatessheet silicatesfluorcarletonitecarletonitecrystal chemistryspectroscopyluminescenceab initio calculation
Type
Article
Information
Mineralogical Magazine , Volume 87 , Issue 3 , June 2023 , pp. 356 - 368
Copyright
Copyright © The Author(s), 2023. Published by Cambridge University Press on behalf of The Mineralogical Society of the United Kingdom and Ireland

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Footnotes

Associate Editor: G. Diego Gatta

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