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The lattice parameters of α-alumina and chromic oxide

Published online by Cambridge University Press:  14 March 2018

A. H. Jay
Affiliation:
Central Research Department, The United Steel Companies Limited, Stocksbridge, near Sheffield
W. T. Wilde
Affiliation:
Refractories Department, Sheffield University

Extract

During the course of a study of the interaction of certain pure refractory oxides at high temperatures it became necessary to obtain accurate values for the lattice parameters of α-alumina and chromic oxide. Values obtained by previous workers, listed in table I, did not attain a greater accuracy than one part in 2000, whereas the use of large-diameter powder cameras calibrated with quartz now yield lattice parameters accurate to at least one part in 30,000.

Samples of the calcined oxides were examined in a 19 cm. diameter powder camera, alumina with cobalt Kα radiation and chromic oxide with chromium Kα radiation. Results are given in tables II and III.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1944

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