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Some Things Never Change - The Microcrystallite Story After 25 Years

Published online by Cambridge University Press:  02 July 2020

J.M. Gibson
Affiliation:
Argonne National Laboratories, Materials Science Division, 9700 S. Cass Avenue, Argonne, IL60439-4838 University of Illinois, Department of Physics, 1110 W. Green St., Urbana, IL61801
M.M.J. Treacy
Affiliation:
NEC Research Institute, 4 Independence Way, Princeton, NJ08540
P.M. Voyles
Affiliation:
University of Illinois, Department of Physics, 1110 W. Green St., Urbana, IL61801
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Extract

When I (JMG) began my Ph.D. studies under the supervision of Archie Howie in 1975, he was still licking his wounds over one of the very few apparently incorrect publications[l] of his career. I am proud that our recent work has shown that, far from being wrong, Archie and Lee Rudee were actually 25 years before their time. It was in the early 1970’s that electron microscopy instrumentation reached the performance level that was adequate to resolve the interplanar spacings in elemental materials, such as the semiconductors silicon and germanium. It immediately became of interest to examine the structure of amorphous silicon and germanium, in the expectation that direct imaging could resolve the old controversy between micro-crystallite and random network structural models. Porai-Koschits was the first to suggest that amorphous materials comprised extremely small crystalline domains (microcrystals), in contrast Zachariasen[2] proposed that a continuous random network was a better description of glassy materials.

Type
A. Howie Symposium: Celebration of Pioneering Electron Microscopy
Copyright
Copyright © Microscopy Society of America

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References

1. Rudee, M.L. and Howie, A., Phil. Mag., 1972. 25: p. 1001CrossRefGoogle Scholar

2. W.H., Zachariasen, J. Am. Chem. Soc, 1932. 54: p. 3841.Google Scholar

3. Treacy, M.M.J, and J.M., Gibson, 1996. A 52: p. 212220.CrossRefGoogle Scholar

4. Gibson, J.M. and Treacy, M.M.J., Phys. Rev. Lett., 1997. 78 : p. 10741077.CrossRefGoogle Scholar

5. Treacy, M.M.J, and Gibson, J.M., J. Non-Cryst. Solids, 1998.Google Scholar