Recently, Inoue et al. succeeded in fabricating ultrahigh-strength Al-based alloys consisting of a nanoscale mixture of α-Al and amorphous phases or a mixture of a-Al, amorphous and icosahedral phases in Al-TM-Ce, Al-TM-Ln (TM: transition metals) and Al-Cr-Co-Ce systems by rapid solidification [1-3]. In order to understand the mechanism of the nanoscale microstructural evolution during the rapid solidification processes in these nanocomposite alloys, we have characterized the microstructures of rapidly solidified Al94.5Cr3Co1.5Ce1 and Al96V4Fe2 alloys by atom probe field ion microscopy (APFIM) and high resolution transmission electron microscopy (HREM).

TEM investigations have revealed that the as-quenched Al94.5Cr3Co1.5Ce1 alloy is composed of a nanoscale mixture of amorphous and α-Al. A typical TEM bright field micrograph is shown in Fig. 1. The microdiffraction patterns taken at various locations in the darkly contrasted region have shown that the region consists of a few interconnected α-Al grains and many localized amorphous regions which are trapped within the Al grains.