Hardmetals of tungsten carbides in a cobalt matrix have been attempted to weld in similar joints by Nd/YAG laser in continuous wave mode. The combination of mechanical and thermo-physical properties of these materials poses a significant difficulty in welding these materials, especially for grades with low Co content, as 6 to 12% in volume. However, grades with higher Co content also showed a poor weldability. In fact, when welding hardmetals with a Co content of 25% in volume, a large amount of pores was observed on the fracture surface. Analysis under scanning electron microscopy showed these pores were coated with a thin film.Observations with energy dispersive spectroscopy (SEM-EDS) revealed this film is rich in cobalt and is highly unstable. Figure 1 shows the characteristics of the film around a pore evidencing its corrugated aspect originated during rapid cooling conditions verified during laser welding.