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The specific heat of carbon dioxide and the form of the CO2 molecule

Published online by Cambridge University Press:  24 October 2008

W. H. McCrea
W. H. McCrea
Affiliation:
Trinity College
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Summary

Two alternative forms of the CO2 molecule have been suggested by various authors who have discussed the band spectrum data. The specific heat curves based on these models are considered here. It is found that neither is quite satisfactory over the whole range of temperature and we discuss the difficulties for the low temperature and high temperature portions separately. In order to get agreement for low temperatures we find it necessary to introduce a further hypothesis about the molecular model which also seems to explain one or two outstanding difficulties in interpreting the fine structure of the bands. This assumption does not make any difference at higher temperatures where we show the error in one of the curves to be of the order we should expect to be accounted for by a centrifugal stretching of the molecule.

Type
Research Article
Information
Mathematical Proceedings of the Cambridge Philosophical Society , Volume 23 , Issue 8 , October 1927 , pp. 890 - 900
Copyright
Copyright © Cambridge Philosophical Society 1927

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References

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