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Two-dimensional ordered polymer hollow sphere and convex structure arrays based on monolayer pore films

Published online by Cambridge University Press:  03 March 2011

Yue Li
Affiliation:
Key Lab of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China
Weiping Cai*
Affiliation:
Key Lab of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China
Guotao Duan
Affiliation:
Key Lab of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China
Bingqiang Cao
Affiliation:
Key Lab of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China
Fengqiang Sun
Affiliation:
Key Lab of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, People's Republic of China
*
a) Address all correspondence to this author. e-mail: wpcai@issp.ac.cn
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Abstract

A two-step replication strategy to two-dimensional ordered polymer hollow sphere and convex structure arrays is presented based on polystyrene colloidal monolayer and inverse opal made of FeO(OH). We can control formation of a small hole on top of the hollow spheres by the concentration of polymer precursors, which could be of importance in selective permeability, nutrient and drug deliver, biotechnology, and even study of black-body irradiation in micro or nano space. In addition, the fabrication strategy is suitable for the most soluble polymer materials, which can solidify when they are concentrated.

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Articles
Copyright
Copyright © Materials Research Society 2005

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