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Synthesis, characterization, and base–catalytic performance of ordered mesoporous aluminophosphate oxynitride materials

Published online by Cambridge University Press:  31 January 2011

Jiacheng Wang  and
Qian Liu
Jiacheng Wang
Affiliation:
State key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Shanghai 200050, People’s Republic of China; and Graduate School of the Chinese Academy of Sciences, Beijing 100039, People’s Republic of China
Qian Liu*
Affiliation:
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Shanghai 20050, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: qianliu@sunm.shcnc.ac.cn
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Abstract

The synthesis, physicochemical characterization, and catalytic evaluation of ordered mesoporous aluminophosphate oxynitride (MAPN) materials are presented here. The solid-base materials were prepared through treating aluminophosphate with an ordered mesostructure with ammonia at high temperatures. The MAPNs are well ordered, and possess high surface and pore volume. The amount of nitrogen incorporated increased with prolonged nitridation times. At the same time, the intensity of basicity is consistent with the nitrogen content, which is affirmed by Knoevenagel condensation reaction. The obtained ordered MAPN materials also possess acidity. The easy preparation and control of the nitrogen content of ordered MAPN materials, providing acidity and basicity, make them attractive as alternatives to a solid-base or acid-base catalyst, especially for the interactions of large molecules.

Keywords

CatalyticEnvironmentally benignPowder
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 12 , December 2007 , pp. 3330 - 3337
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1Hattori, H.: Heterogeneous basic catalysis. Chem. Rev. 95, 537 1995CrossRefGoogle Scholar
2Barthomeuf, D.: Basic zeolites: Characterization and uses in adsorption and catalysis. Catal. Rev. 38, 521 1996CrossRefGoogle Scholar
3Weitkamp, J., Hunger, M.Rymsa, U.: Base catalysis on microporous and mesoporous materials: Recent progress and perspectives. Microporous Mesoporous Mater. 48, 255 2001CrossRefGoogle Scholar
4Lednor, P.W.: Synthesis, stability, and catalytic properties of high surface area silicon oxynitride and silicon carbide. Catal. Today 15, 243 1992Google Scholar
5Lednor, P.W.de Ruiter, R.: The use of a high area silicon oxynitride as a solid, basic catalyst. J. Chem. Soc., Chem. Commun. 1625 1991Google Scholar
6Lednor, P.W., de Ruiter, R.Emeis, K.A.: Characterization of high surface area silicon oxynitrides in Better Ceramics Through Chemistry V, edited by M.J. Hampden-Smith, W.G. Klemperer, and C.J. Brinker (Mater. Res. Soc. Symp. Proc. 271, Pittsburgh, PA, 1992), p. 801.CrossRefGoogle Scholar
7Blasco, T., Corma, A., Fernandez, L., Fornes, V.Guil-Lopez, R.: Magic angle spinning NMR investigations on amorphous aluminophosphate oxynitrides. Phys. Chem. Chem. Phys. 1, 4493 1999Google Scholar
8Climent, M.J., Corma, A., Fornes, V., Frau, A., Guil-Lopez, R., Iborra, S.Primo, J.: Aluminophosphates oxynitrides as base catalysts: Nature of the base sites and their catalytic implications. J. Catal. 163, 392 1996CrossRefGoogle Scholar
9Grange, P., Bastians, P., Conanec, R., Marchand, R.Laurent, Y.: Influence of nitrogen content of a new aluminophosphate oxynitride catalyst: AlPON in Knoevenagel condensation. Appl. Catal., A 114, L191 1994Google Scholar
10Delsarte, S., Centeno, M.A.Grange, P.: Nitrided galloaluminophosphates “AlGaPON”: Influence of the nitridation time on the nature and the stability of surface nitrogenous species. J. Non-Cryst. Solids 297, 189 2002CrossRefGoogle Scholar
11Fripiat, N., Parvulescu, V., Parvulescu, V.I.Grange, P.: Role of nitrogen on the acid-base properties of zirconophosphate (ZrPON) oxynitride catalysts. Appl. Catal., A 181, 331 1999Google Scholar
12Fripiat, N., Centeno, M.A.Grange, P.: Identification and stability of the nitrogenous species in zirconium phosphate oxynitride catalysts. Chem. Mater. 11, 1434 1999CrossRefGoogle Scholar
13Fripiat, N.Grange, P.: Synthesis and characterization of a novel zirconophosphate oxynitride catalyst. J. Chem. Soc., Chem. Commun. 1409 1996Google Scholar
14Delsarte, S., Peltier, V., Laurent, Y.Grange, P.: X-ray photoelectron study of new mixed oxynitrides “AlGaPON”. J. Eur. Ceram. Soc. 18, 1287 1998Google Scholar
15Peltier, V., Conanec, R., Marchand, R., Laurent, Y., Delsarte, S., Guéguen, E.Grange, P.: A novel family of mixed gallium aluminium phosphorus oxynitrides: Their synthesis, characterization and utilization in heterogeneous catalysis. Mater. Sci. Eng., B 47, 177 1997Google Scholar
16Zhao, D.Y., Feng, J.L., Huo, Q.S., Melosh, N., Fredrickson, G.H., Chmelka, B.F.Stucky, G.D.: Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores. Science 279, 548 1998CrossRefGoogle ScholarPubMed
17Chen, H., Shi, J., Li, Y., Yan, J., Hua, Z., Chen, H.Yan, D.: A new method for the synthesis of highly dispersive and catalytically active platinum nanoparticles confined in mesoporous zirconia. Adv. Mater. 15, 1078 2003Google Scholar
18Antonelli, D.M.: Synthesis of highly ordered macro-mesoporous niobium oxide molecular sieves. Microporous Mesoporous Mater. 30, 315 1999CrossRefGoogle Scholar
19Ciesla, U., Schacht, S., Stucky, G.D., Unger, K.K.Schüth, F.: Formation of a porouszirconium oxo phosphate with a high surface area by a surfactant-assisted synthesis. Angew. Chem., Int. Ed. Engl. 35, 541 1996Google Scholar
20Yang, H., Kupeman, A., Coombs, N., Mamiche-Afra, S.Ozin, G.A.: Synthesis of oriented films of mesoporous silica on mica. Nature 379, 703 1996Google Scholar
21Niesz, K., Yang, P.Somorjai, G.A.: Sol-gel synthesis of ordered mesoporous alumina. Chem. Commun. 1986 2005CrossRefGoogle ScholarPubMed
22Schüth, F.: Non-siliceous mesostructured and mesoporous materials. Chem. Mater. 13, 3184 2001Google Scholar
23Haskouri, J.E., Cabrera, S., Sapiña, F.F., Latorre, J., Guillen, C., Beltrán-Porter, A., Marcos, M.D.Amorós, P.: Ordered mesoporous silicon oxynitrides. Adv. Mater. 13, 192 2001Google Scholar
24Xia, Y.Mokaya, R.: Highly ordered mesoporous silicon oxynitride materials as base catalysts. Angew. Chem., Int. Ed. Engl. 42, 2639 2003Google Scholar
25Xia, Y.Mokaya, R.: Ordered mesoporous MCM-41 silicon oxynitride solid base materials with high nitrogen content: Synthesis, characterisation and catalytic evaluation. J. Mater. Chem. 14, 2507 2004Google Scholar
26Wan, K., Liu, Q.Zhang, C.: Synthesis of highly ordered mesoporous silicon oxynitride with high nitrogen content. Chem. Lett. (Jpn.). 32, 362 2003Google Scholar
27Wang, J.Liu, Q.: Mesoporous silicon oxynitride thin films. Chem. Commun. 8, 900 2006Google Scholar
28Zhang, C., Liu, Q.Xu, Z.: Synthesis and characterization of non-crystalline mesoporous silicon oxynitride MCM-41 with high nitrogen content. J. Non-Cryst. Solids 351, 1377 2005CrossRefGoogle Scholar
29Wang, J.Liu, Q.: Synthesis and characterization of ordered mesoporous SiOxNy thin films with different nitrogen contents. Nanotechnology 17, 2828 2006CrossRefGoogle Scholar
30Wang, J.Liu, Q.: Structural change and characterization in nitrogen-incorporated SBA15 oxynitride mesoporous materials via different thermal history. Microporous Mesoporous Mater. 83, 225 2005Google Scholar
31Wang, J.Liu, Q.: Nitrogen loss and structural change of nitrogen-incorporated SBA-15 mesoporous materials under different treatment conditions. J. Mater. Res. 20, 2296 2005Google Scholar
32Wan, K., Liu, Q., Zhang, C.Wang, J.: The basicity and catalytic activity of ordered mesoporous silicon nitride oxide. Bull. Chem. Soc. Jpn. 77, 1409 2004Google Scholar
33Tian, B., Liu, X., Tu, B., Yu, C., Fan, J., Wang, L., Xie, S., Stucky, G.D.Zhao, D.: Self-adjusted synthesis of ordered stable mesoporous minerals by acid-base pairs. Nat. Mater. 2, 259 2003Google Scholar
34Wang, L., Tian, B., Fan, J., Liu, X., Yang, H., Yu, C., Tu, B.Zhao, D.: Block copolymer templating syntheses of ordered large-pore stable mesoporous aluminophosphates and Fe-aluminophosphate based on an “acid–base pair” route. Microporous Mesoporous Mater. 67, 123 2004Google Scholar
35Sing, K.S.W., Everett, D.H., Haul, R.A.W., Moscou, L., Pierotti, R.A., Rouquerol, J.Siemieniewska, T.: Reporting physisorption data for gas / solid systems with special reference to the determination of surface area and porosity. Pure Appl. Chem. 57, 603 1985Google Scholar
36Benítez, J., Díaz, A., Laurent, Y.Odriozola, J.: Study of aluminophosphate oxynitride (AlPON) materials by x-ray photoelectron (XPS) and diffuse reflectance Fourier transform IR spectroscopy (DRIFTS). J. Mater. Chem. 8, 687 1998Google Scholar
37Benítez, J., Díaz, A., Laurent, Y.Odriozola, J.A.: Characterisation, surface hydrolysis and nitrogen stability in aluminophosphate oxynitride (AlPON) catalysts. Appl. Catal., A 176, 177 1999Google Scholar
38Marquez, F., Guil-López, R., Fornés, V.Corma, A.: First evidences on the stability of nitride species in ALPON catalysts. Catal. Commun. 1, 21 2000Google Scholar
39Centeno, M.A., Debois, M.Grange, P.: DRIFTS study of platinum aluminophosphate oxynitride catalysts. J. Phys. Chem. B 102, 6835 1998Google Scholar
40Benítez, J., Díaz, A., Laurent, Y.Odriozola, J.: CO2 adsorption and surface basicity evaluation of aluminophosphate oxynitride (AlPON). Catal. Lett. 54, 159 1998Google Scholar
41Marchand, R., Agliz, D., Boukbir, L.Quemerais, A.: Characterization of nitrogen containing phosphate glasses by x-ray photoelectron spectroscopy. J. Non-Cryst. Solids 103, 35 1988Google Scholar
42Brow, R.K., Reidmeyer, M.R.Day, D.E.: Oxygen bonding in nitrided sodium- and lithium-metaphosphate glasses. J. Non-Cryst. Solids 99, 178 1988Google Scholar
43Climent, M.J., Corma, A., Guil-Lopez, R.Iborra, S.: Aluminophosphates oxynitrides as base catalysts for the production of dicyanomethylene derivative dyes. Catal. Lett. 74, 161 2001Google Scholar
44Bradley, J.S., Vollmer, O., Rovai, R., Specht, U.Lefebvre, F.: High surface area silicon imidonitrides: A new class of microporous solid base. Adv. Mater. 10, 938 19983.0.CO;2-8>CrossRefGoogle Scholar
45Wiame, H.M., Cellier, C.M.Grange, P.: Aluminovanadate oxynitride catalyst: Proposition for the basic site. J. Phys. Chem. B 104, 591 2000Google Scholar
46Zahedi-Niaki, M. Hassan, Zaidi, S.M. JavaidKaliaguine, S.: Acid properties of titanium aluminophosphate molecular sieves. Microporous Mesoporous Mater. 32, 251 1999Google Scholar