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Synthesis and characterization of nitrides of iridium and palladium

Published online by Cambridge University Press:  31 January 2011

Jonathan C. Crowhurst ,
Alexander F. Goncharov ,
B. Sadigh ,
J.M. Zaug ,
D. Aberg ,
Yue Meng  and
Vitali B. Prakapenka
Jonathan C. Crowhurst*
Affiliation:
Lawrence Livermore National Laboratory, University of California, Livermore, California 94551
Alexander F. Goncharov
Affiliation:
Lawrence Livermore National Laboratory, University of California, Livermore, California 94551; and Geophysical Laboratory, Carnegie Institution of Washington, Washington, DC 20015
B. Sadigh
Affiliation:
Lawrence Livermore National Laboratory, University of California, Livermore, California 94551
J.M. Zaug
Affiliation:
Lawrence Livermore National Laboratory, University of California, Livermore, California 94551
D. Aberg
Affiliation:
Lawrence Livermore National Laboratory, University of California, Livermore, California 94551
Yue Meng
Affiliation:
High Pressure Collaborative Access Team (HPCAT), Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439
Vitali B. Prakapenka
Affiliation:
GeoSoilEnviro Consortium for Advanced Radiation Sources (GSECARS), University of Chicago, Chicago, Illinois 60637
*
a)Address all correspondence to this author. e-mail: crowhurst1@llnl.gov
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Abstract

We describe the synthesis of nitrides of iridium and palladium using the laser-heated diamond anvil cell. We have used the in situ techniques of x-ray powder diffraction and Raman scattering to characterize these compounds and have compared our experimental findings where possible to the results of first-principles theoretical calculations. We suggest that palladium nitride is isostructural with pyrite, while iridium nitride has a monoclinic symmetry and is isostructural with baddeleyite.

Keywords

NitrideRaman spectroscopyLaser-induced reaction
Type
Outstanding Symposium Papers
Information
Journal of Materials Research , Volume 23 , Issue 1 , January 2008 , pp. 1 - 5
Copyright
Copyright © Materials Research Society 2008

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References

REFERENCES

1Gregoryanz, E., Sanloup, C., Somayazulu, M., Badro, J., Fiquet, G., Mao, H-K.Hemley, R.J.: Synthesis and characterization of a binary noble metal nitride. Nat. Mater. 3, 294 2004CrossRefGoogle ScholarPubMed
2McMillan, P.F.: New materials from high-pressure experiments. Nat. Mater. 1, 19 2003CrossRefGoogle Scholar
3Oyama, S.T.: Introduction to the chemistry of transition metal carbides and nitrides in The Chemistry of Transition Metal Carbides and Nitrides, edited by S.T. Oyama Blackie Academic & Professional, 1996 Chap. 1CrossRefGoogle Scholar
4Pierson, H.A.: Handbook of Refractory Carbides and Nitrides Noyes Westwood, NJ 1996 Chaps. 9–13Google Scholar
5Jhi, S-H., Ihm, J., Louie, S.G.Cohen, M.L.: Electronic mechanism of hardness enhancement in transition-metal carbonitrides. Nature 399, 132 1999CrossRefGoogle Scholar
6Kroll, P.: Hafnium nitride with thorium phosphide structure: Physical properties and an assessment of the Hf–N, Zr–N, and Ti–N phase diagrams at high pressures and temperatures. Phys. Rev. Lett. 90, 125501 2003CrossRefGoogle Scholar
7Siller, L.S., Hunt, M.R.C., Brown, J.W., Coquel, J-M.Rudolf, P.: Nitrogen ion irradiation of Au (110): Formation of gold nitride. Surf. Sci. 513, 78 2002CrossRefGoogle Scholar
8Soto, G.: Synthesis of PtNx films by reactive laser ablation. Mater. Lett. 58, 2178 2004CrossRefGoogle Scholar
9Crowhurst, J.C., Goncharov, A.F., Sadigh, B., Evans, C.L., Morrall, P.G., Ferreira, J.L.Nelson, A.J.: Synthesis and characterization of the nitrides of platinum and iridium. Science 311, 1277 2006CrossRefGoogle ScholarPubMed
10Goncharov, A.F.Crowhurst, J.C.: Raman spectroscopy under extreme conditions. J. Low Temp. Phys. 139, 727 2005CrossRefGoogle Scholar
11Young, A.F., Sanloup, C., Gregoryanz, E., Scandolo, S., Hemley, R.J., Mao, H-K.: Synthesis of novel transition metal nitrides IrN2 and OsN2. Phys. Rev. Lett. 96, 155501 2006CrossRefGoogle ScholarPubMed
12Zerr, A., Miehe, G.Boehler, R.: Synthesis of cubic silicon nitride. Nature 400, 340 1999CrossRefGoogle Scholar
13Zerr, A., Miehe, G.Boehler, R.: Synthesis of cubic zirconium and hafnium nitrides having Th3P4 structure. Nat. Mater. 2, 185 2003CrossRefGoogle ScholarPubMed
14Goncharov, A.F., Goldman, N., Fried, L.E., Crowhurst, J.C., Kuo, I-F., Mundy, C.J.Zaug, J.M.: Dynamic ionization of water under extreme conditions. Phys. Rev. Lett. 94, 125508 2005CrossRefGoogle ScholarPubMed
15Horvath-Bordon, E., Riedel, R., Zerr, A., McMillan, P.F., Auffermann, G., Prots, Y., Bronger, W., Kniep, R.Kroll, P.: High pressure chemistry of nitride-based materials. Chem. Soc. Rev. 35, 987 2006CrossRefGoogle ScholarPubMed
16Boehler, R.De Hantsetters, K.: New anvil designs in diamond-cells. High Pressure Res. 24, 391 2004CrossRefGoogle Scholar
17Perdew, J.P.Wang, Y.: Accurate and simple analytic representation of the electron-gas correlation energy. Phys. Rev. B 45, 13244 1992CrossRefGoogle ScholarPubMed
18Kresse, G.Furthmuller, J.: Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54, 11169 1996CrossRefGoogle ScholarPubMed
19Kresse, G.Joubert, D.: From ultrasoft pseudopotentials to the projector augmented-wave method. Phys. Rev. B 59, 1758 1999CrossRefGoogle Scholar
20Yu, R., Zhan, Q.De Jonghe, L.C.: Crystal structures of and displacive transitions in OsN2, IrN2, RuN2, and RhN2. Angew. Chem. Int. Ed. Eng. 46, 1136 2007CrossRefGoogle ScholarPubMed
21Young, A.F., Montoya, J.A., Sanloup, C., Lazzeri, M., Gregoryanz, E., Scandolo, S.: Interstitial dinitrogen makes PtN2 an insulating hard solid. Phys. Rev. B 73, 153102 2006CrossRefGoogle Scholar
22Yu, R.: personal communication, 2006Google Scholar
23Siller, L., Peltekis, N., Krishnamurthy, S., Chao, Y., Bull, S.J.Hunt, M.R.S.: Gold film with gold nitride—A conductor but harder than gold. Appl. Phys. Lett. 86, 221912 2005CrossRefGoogle Scholar
24Butenko, Y.V., Alves, L., Brieva, A.C., Yang, J., Krishnamurthy, S.Siller, L.: X-ray induced decomposition of gold nitride. Chem. Phys. Lett. 430, 89 2006CrossRefGoogle Scholar