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Study on the structure of PbS nanoparticles coated with dialkyldithiophosphate

Published online by Cambridge University Press:  31 January 2011

Shuang Chen ,
Weimin Liu  and
Laigui Yu
Shuang Chen
Affiliation:
Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000, People's Republic of China
Weimin Liu*
Affiliation:
Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000, People's Republic of China
Laigui Yu
Affiliation:
Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000, People's Republic of China
*
a)Address all correspondence to this author.
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Abstract

PbS nanoparticles modified with di-n-hexadecyldithiophosphate (DDP) were prepared by the chemical surface modification method. The structure of the PbS nanoparticles coated with DDP was investigated by means of infrared spectroscopy (ir), x-ray photoelectron spectroscopy (XPS), x-ray diffraction (XRD), transmission electron microscopy (TEM), and 31P nuclear magnetic resonance spectroscopy (31P NMR). The thermal stability of DDP coating on the PbS nanoparticles was compared with that of pyridinium di-n-hexadecyldithiophosphate (PyDDP) using a thermogravimetric analyzer (TGA). It was found that coated PbS nanoparticles had an average diameter of about 5 nm. Surface modification with DDP prevented water adsorption and effectively improved the dispersive capacity and antioxidative stability of PbS nanoparticles. The thermal stability of DDP coating on the surface of nano-PbS particles was higher than that of modifier PyDDP because of the chemical interaction between PyDDP and PbS during the coating process.

Type
Articles
Information
Journal of Materials Research , Volume 14 , Issue 5 , May 1999 , pp. 2147 - 2151
Copyright
Copyright © Materials Research Society 1999

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