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Shape-controlled synthesis of FeNi3 nanoparticles by ambient chemical reduction and their magnetic properties

Published online by Cambridge University Press:  08 March 2012

Guo Hongxia ,
Cheng Hua ,
Li Fan ,
Qin Zhenping ,
Cui Suping  and
Nie Zuoren
Guo Hongxia*
Affiliation:
College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
Cheng Hua
Affiliation:
College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
Li Fan
Affiliation:
College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
Qin Zhenping
Affiliation:
College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
Cui Suping
Affiliation:
College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
Nie Zuoren*
Affiliation:
College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
*
a)Address all correspondence to these authors. e-mail: hxguo@bjut.edu.cn
b)e-mail: zrnie@bjut.edu.cn
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Abstract

A facile method to control the morphology of FeNi3 nanoparticles by solution reduction reaction is presented. The spherical to platelet FeNi3 particles were obtained by changing pH from 11.5 to12.5 with 0.16 mol/L of hydrazine under ultrasound irradiation, with the ratio of Fe2+ to Ni2+ as 1:3. The amount of hydrazine had little influence on the morphology of the particles. The saturation magnetization (Ms) and coercive force (Hc) of the platelet particles were 59 emu/g and 120 Oe, respectively. The real part μ′ of the permeability of the platelet particles was about 2.43–2.71 and was frequency-independent in the range of 0.1–1.0 GHz. The imaginary part (μ′′) of the particles showed increase from 0.04 to 2.14 within the same frequency range.

Keywords

MagneticAlloyCrystal
Type
Articles
Information
Journal of Materials Research , Volume 27 , Issue 11 , 14 June 2012 , pp. 1522 - 1530
Copyright
Copyright © Materials Research Society 2012

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