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Reversible fluorescence modulation based on photochromic diarylethene and fluorescent coumarin

Published online by Cambridge University Press:  31 January 2011

Xiaohai Sheng ,
Aidong Peng ,
Hongbing Fu ,
Jiannian Yao ,
Yuanyuan Liu  and
Yaobing Wang
Xiaohai Sheng
Affiliation:
Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China; and Graduate School, Chinese Academy of Sciences, Zhongguancun, Beijing 100080, People’s Republic of China
Aidong Peng
Affiliation:
Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
Hongbing Fu
Affiliation:
Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
Jiannian Yao*
Affiliation:
Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China
Yuanyuan Liu
Affiliation:
Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China; and Graduate School, Chinese Academy of Sciences, Zhongguancun, Beijing 100080, People’s Republic of China
Yaobing Wang
Affiliation:
Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, People’s Republic of China; and Graduate School, Chinese Academy of Sciences, Zhongguancun, Beijing 100080, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: jnyao@iccas.ac.cn
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Abstract

A fluorescence switch by the photoisomerization of a photochromic compound in CH3CN and in a polymer film using a bistable photochromic (1,2-bis(2-methylbenzo[b]thiophen-3-yl) hexafluorocyclopentene) (BTF6) and a fluorescent 3-(2-benzothiazolyl)-7-(diethylamino) coumarin (coumarin6) was demonstrated. Because only the closed form of BTF6 serves as a fluorescence quencher of coumarin6, and the read (406 nm), write (254 nm), and erase (>500 nm) wavelengths are well-separated, a reversible modulation of the fluorescence of coumarin6 with high contrast and high sensitivity is expected to be realized. This system may represent an alternative to the fluorescence switches that are based on covalent systems in the potentially long-term optical data or image storage schemes utilizing luminescence intensity readout.

Keywords

FilmOrganicPhotoemission
Type
Articles
Information
Journal of Materials Research , Volume 22 , Issue 6 , June 2007 , pp. 1558 - 1563
Copyright
Copyright © Materials Research Society2007

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References

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