Hostname: page-component-848d4c4894-v5vhk Total loading time: 0 Render date: 2024-07-02T13:39:12.050Z Has data issue: false hasContentIssue false

Influence of chemical composition and inorganic admixtures on the electrical conductivity of hydrating cement pastes

Published online by Cambridge University Press:  31 January 2011

M. Perez-Pena
Affiliation:
Materials Research Laboratory, The Pennsylvania State University. University Park, Pennsylvania 16802
D. M. Roy
Affiliation:
Materials Research Laboratory, The Pennsylvania State University. University Park, Pennsylvania 16802
F. D. Tamás
Affiliation:
University of Veszprem, Institute of Silicate Chemistry and Technology, H-8201 Veszprem, P.O. B. 158, Hungary
Get access

Abstract

Electrical conductivity of cementitious materials with a wide range of chemical compositions has been studied during the first 24 h of hydration. Relationships between heat of hydration and electrical conductivity curves are discussed. Results are tentatively explained in terms of some physical and chemical parameters. Further evidence that the electrical conductivity of hydrating cement pastes is related to the hydration mechanisms operating in these systems was obtained. The order in which the cations of inorganic admixtures (chlorides and hydroxides) were found to increase the peak and rate of development of the electrical conductivity is the same order that they have been found to increase the heat liberated upon hydration of systems containing these admixtures.

Type
Articles
Copyright
Copyright © Materials Research Society 1989

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1Hammond, E. and Robson, T. D., in “Comparison of Electrical Properties of Various Cements and Concrete,” The Engineer (London, Jan. 1955), Vol. 199, No. 5165, pp. 7880.Google Scholar
2Boast, W. B., “A Conductometric Analysis of Portland Cement Pastes and Mortars and Some of Its Applications,” ACI Journal 33, 131146 (Nov. 1936).Google Scholar
3Calleja, J., “New Techniques in the Study of Setting and Hardening of Hydraulic Materials,” ACI Journal 48, 525536 (Mar. 1952).Google Scholar
4Calleja, J., “Determination of Setting and Hardening Time of High-Alumina Cements by Electrical Resistance Techniques,” ACI Journal 50, 249256 (Nov. 1953).Google Scholar
5Monfore, B. E., “The Electrical Resistivity of Concrete,” Journal of the PCA Research and Development Laboratories 10 (2), 3548 (May 1968); PCA Research Department Bulletin 224.Google Scholar
6Vernet, C., Demoulian, P., and Hawthorn, F., “Mecanismes Reactionnels de L'Hydration,” 7th International Congress on the Chemistry of Cement, Paris, Vol. II, 1980, pp. 267278.Google Scholar
7Tamas, F. D., “Electrical Conductivity of Cement Pastes,” Cement and Concrete Research 12 (1), 115120 (Jan. 1982).Google Scholar
8Tamas, F. D., Farkas, E., and Roy, D. M., “Electrical Conductivity of Pastes Made of Clinker + Gypsum,” Proc. Brit. Ceram. Soc. 35, 237248 (1984).Google Scholar
9McCarter, W. J. and Curan, P. N., “The Electrical Response Characteristics of Setting Cement Paste,” Magazine of Concrete Research 36 (126), 4249 (Mar. 1984).Google Scholar
10Malik, W. V., Gupta, D. R., Gupta, H. O., Gupta, R. S., and Masood, I., “Changes in Electrical Properties During Hydration and Setting of Cements,” Trans. Indian Ceram. Soc. 43, 130144 (1984).Google Scholar
11Perez-Pena, M., “Electrical Conductivity and Dielectric Studies of Hydraulic Cements,” Ph.D. Thesis, The Pennsylvania State University, University Park, PA, May 1986.Google Scholar
12Afshar, A. B. and McCarter, W. J., “Monitoring the Influence of Admixtures and Composition on the Early Hydration Characteristics of Cement Using AC Electrical Response Techniques,” 8th International Symposium on the Chemistry of Cements (FINEP Editions, Brazil, 1986), Vol. Ill, p. 193.Google Scholar
13Tamas, F. D., Farkas, E., Voros, M., and Roy, D. M., “Low-frequency Electrical Conductivity of Cement, Clinker and Clinker Mineral Pastes,” 8th International Symposium on the Chemistry of Cements. (FINEP Editions, Brazil, 1986), Vol. VI. pp. 374-380; also in Cement and Concrete Research 17, 340-348 (1987).Google Scholar
14Majling, J., Moses, P., Perez-Pena, M., and Roy, D. M., “A Novel Experimental Setup to Measure the Changes in Electrical Conductivity of Hydrating Cementitious Materials”, in Bonding in Cementitious Composites, edited by Mindess, S. and Shah, S. P. (MRS 114, Boston, MA, 1987), p. 114.Google Scholar
15Taylor, M. A. and Arulanandan, K., “Relationships Between Electrical and Physical Properties of Cement Pastes,” Cement and Concrete Research 4 (6), 881897 (1974).Google Scholar
16Whittington, H. W., “The Conduction of Electricity Through Concrete,” Magazine of Concrete Research 33, (114), 4860 (Mar. 1951).Google Scholar
17Hansson, L. H. and Hansson, C. M., “Ion-Conduction in Cement-Based Materials,” Cement and Concrete Research 15 (2), 201212 (Mar. 1985).CrossRefGoogle Scholar
18Skalny, J. P. and Young, J. F., “Mechanisms of Portland Cement Hydration,” Proceedings, 7th International Congress on the Chemistry of Cements (Editions Septima, Paris, 1980), Vol. I, pp. II-1/3-II-1/45.Google Scholar
19Rousan, A., “A Methodology for Thermal Characterization of Cementitious Materials,” Ph.D. Thesis, The Pennsylvania State University, University Park, PA, May 1982.Google Scholar
20Young, J.F., “Hydration of Portland Cement,” Instructional Modules in Cement Science, Journal of Materials Education, edited by Roy, D.M. (The Pennsylvania State University, University Park, PA, 1985), pp. 524.Google Scholar
21Silsbee, M., Malek, R.I. A., and Roy, D.M., “Composition of Pore Fluids Extruded From Slag-Cement Pastes,” 8th International Symposium on the Chemistry of Cements (FINEP Editions, Brazil, 1986).Google Scholar
22Diamond, S., “Alkali Reactions in Concrete-Pore Solution Effects,” Alkalis in Concrete Research and Practice, Proceedings of the 6th International Conference, edited by Worn, G.M. and Rostam, Steen (Danish Concrete Association, June 1983), pp. 155166.Google Scholar
23Wilding, C. R., Walter, A., and Double, D. P., “A Classification of Inorganic and Organic Admixtures by Conducting Calorimetry,” Cement and Concrete Research 14 (2), 185193 (Mar. 1984).CrossRefGoogle Scholar