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Dielectric, ferroelectric, and ferromagnetic properties of 0.7Bi1−xLax(Fe0.9Cr0.1)O3–0.1BaTiO3–0.2PbTiO3 solid solutions

Published online by Cambridge University Press:  31 January 2011

Xiao-hui Liu ,
Zhuo Xu ,
Xiao-yong Wei  and
Xi Yao
Xi Yao
Affiliation:
Electronic Materials Research Laboratory, Key Laboratory of Ministry of Education, Xi'an Jiaotong University, Xi'an 710049, China
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Abstract

Solid solutions 0.7Bi1−xLax (Fe0.9Cr0.1) O3–0.1BaTiO3–0.2PbTiO3 (BLxFOC-BT-PT, with x = 0, 0.03, 0.05, 0.07) solid solutions were prepared by the traditional ceramic process. X-ray diffraction results reveal that all samples show pure pseudocubic perovskites structure. The lattice parameter of the solid solutions increases linearly with the La content, indicating that La ions have entered crystal lattices to form a solid solution. The Curie temperature of the solid solutions decreases with the La content. Room-temperature polarization–electric field (P–E) curves indicate that the samples with x = 0.03 and 0.05 exhibit saturated P–E loops. Piezoelectric constant d33 of the solid solutions increases firstly and then decreases. Magnetizations of the solid solutions decrease with the La content. The evidence of weak ferromagnetism and saturated ferroelectric hysteresis loops in BLxFOC–BT–PT system at room temperature makes it a good candidate for multiferroic applications.

Keywords

CeramicFerromagneticFerroelecricity
Type
Articles
Information
Journal of Materials Research , Volume 25 , Issue 9 , September 2010 , pp. 1812 - 1816
Copyright
Copyright © Materials Research Society 2010

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References

REFERENCES

1.Smolenskii, G.A., Chupis, I.Ferroelectromagnets. Sov. Phys. Usp. 25, 475 (1982)Google Scholar
2.Fiebig, M., Lottermoser, T., Frohlich, D., Goltsev, A.V., Pisarev, R.V.Observation of coupled magnetic and electric domains. Nature 419, 818 (2002)CrossRefGoogle ScholarPubMed
3.Fiebig, M.Revival of the magnetoelectric effect. J. Phys. D 38, R123 (2005)CrossRefGoogle Scholar
4.Cheng, J.R., Li, N., Cross, L.E.Structural and dielectric properties of Ga-modified BiFeO3–PbTiO3 crystalline solutions. J. Appl. Phys. 94, 5153 (2003)Google Scholar
5.Sosnowska, I., Peterlin-Neumaier, T., Steichele, E.Spiral magnetic ordering in bismuth ferrite. J. Phys. C: Solid State Phys. 15, 4835 (1982)CrossRefGoogle Scholar
6.Kim, J.S., Cheon, C.I., Choi, Y.N., Jang, P.W.Ferroelectric and ferromagnetic properties of BiFeO3–PrFeO3–PbTiO3 solid solutions. J. Appl. Phys. 93, 9263 (2003)CrossRefGoogle Scholar
7.Kumar, M.M., Srinath, S., Kumar, G.S., Suryanarayana, S.V.Spontaneous magnetic moment in BiFeO3–BaTiO3 solid solutions at low temperatures. J. Magn. Magn. Mater. 188, 203 (1998)CrossRefGoogle Scholar
8.Palkar, V.R., Kundaliya, D.C., Malik, S.K., Bhattacharya, S.Magnetoelectricity at room temperature in the Bi0.9−xTbxLa0.1FeO3 system. Phys. Rev. B 69, 212102 (2004)CrossRefGoogle Scholar
9.Mathe, V.L., Patankar, K.K., Patil, R.N., Lokhande, C.D.Synthesis and dielectric properties of Bi1−xNdxFeO3 perovskite. J. Magn. Magn. Mater. 270, 380 (2004)CrossRefGoogle Scholar
10.Yang, C.H., Koo, T.Y., Jeong, Y.H.How to obtain magnetocapacitance effects at room temperature: The case of Mn-doped BiFeO3. Solid State Commun. 134, (4)299 (2005)CrossRefGoogle Scholar
11.Liu, X.H., Xu, Z., Wei, X.Y., Yao, X., Yang, X.Dielectric and magnetic properties of 0.7BiFe1−xCrxO3–0.1BaTiO3–0.2PbTiO3 solid solutions. J. Alloys Compd. 480, L41 (2009)CrossRefGoogle Scholar
12.Jiang, Q-H., Nanw, C-W., Shen, Z-J.Synthesis and properties of multiferroic La-modified BiFeO3 ceramics. J. Am. Ceram. Soc. 89, (7)2123 (2006)CrossRefGoogle Scholar
13.Chen, J., Qi, Y., Shi, G., Yan, X., Yu, S., Cheng, J.Diffused phase transition and multiferroic properties of 0.57(Bi1−xLax)FeO3–0.43PbTiO3 crystalline solutions. J. Appl. Phys. 104, 064124 (2008)CrossRefGoogle Scholar
14.Cheng, Z.Y., Katiyar, R.S., Yao, X., Guo, A.Dielectric behavior of lead magnesium niobate relaxors. Phys. Rev. B 55, 8165 (1997)Google Scholar
15.Rai, R., Sharma, S.Structural and dielectric properties of (La, Bi) modified PZT ceramics. Solid State Commun. 129, 305 (2004)CrossRefGoogle Scholar