Skip to main content Accessibility help
×
Home
Hostname: page-component-55b6f6c457-qgndx Total loading time: 0.208 Render date: 2021-09-24T22:49:52.075Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "metricsAbstractViews": false, "figures": true, "newCiteModal": false, "newCitedByModal": true, "newEcommerce": true, "newUsageEvents": true }

Pyrolysis of self-assembled organic monolayers on oxide substrates

Published online by Cambridge University Press:  31 January 2011

Hyunjung Shin
Affiliation:
Department of Materials Science and Engineering, Case Western Reserve University, Cleveland, Ohio 44106
Yuhu Wang
Affiliation:
Department of Materials Science and Engineering, Case Western Reserve University, Cleveland, Ohio 44106
Uma Sampathkumaran
Affiliation:
Department of Materials Science and Engineering, Case Western Reserve University, Cleveland, Ohio 44106
Mark R. De Guire
Affiliation:
Department of Materials Science and Engineering, Case Western Reserve University, Cleveland, Ohio 44106
Arthur H. Heuer
Affiliation:
Department of Materials Science and Engineering, Case Western Reserve University, Cleveland, Ohio 44106
Chaim N. Sukenik
Affiliation:
Department of Chemistry, Bar Ilan University, Ramat Gan, 52100, Israel
Get access

Abstract

The pyrolysis of siloxy-anchored, organic self-assembled monolayers (SAMs) on oxide substrates [titanium dioxide powder; hydrolyzed silicon dioxide on (100) silicon] was studied using x-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), and mass spectroscopy (MS). Pyrolysis in air began on heating at 200 °C and was complete by 400 °C for both octadecyltrichlorosilane (OTS) and C16-thioacetate (TA) SAMs, as observed in TGA of SAM-coated TiO2 powders, and in XPS studies of TA-SAM-coated TiO2 powders and Si wafers after various heat treatments. In low-oxygen environments, pyrolysis of SAMs began at higher temperatures: between 250 and 400 °C for heating in ultrahigh vacuum (10−8 Torr) as observed in XPS studies of TA-SAMs on Si, and between 300 and 400 °C in nitrogen, as observed in TEM analysis of sulfonate SAMs under a TiO2 thin film on Si substrates.

Type
Articles
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. (a)Ulman, A., An Introduction to Ultrathin Organic Films from Langmuir-Blodgett to Self-Assembly (Academic Press, New York, 1991);Google Scholar
(b)Ulman, A., Adv. Mater. 2, 573 (1990).CrossRefGoogle Scholar
2.Bunker, B. C., Rieke, P. C., Tarasevich, B. J., Campbell, A. A., Fryxell, G. E., Graff, G. L., Song, L., Liu, J., Virden, J. W., and McVay, G. L., Science 264, 48 (1994).CrossRefGoogle Scholar
3.Shin, H., Collins, R. J., De Guire, M. R., Heuer, A. H., and Sukenik, C. N., J. Mater. Res. 10, 692 (1995).CrossRefGoogle Scholar
4.Shin, H., Collins, R. J., De Guire, M. R., Heuer, A. H., and Sukenik, C. N., J. Mater. Res. 10, 699 (1995).CrossRefGoogle Scholar
5.Collins, R. J., Shin, H., De Guire, M. R., Heuer, A. H., and Sukenik, C. N., Appl. Phys. Lett. 69 (6), 860 (1996).CrossRefGoogle Scholar
6.Agarwal, M., De Guire, M. R., and Heuer, A. H., Appl. Phys. Lett. 71 (7), 891 (1997).CrossRefGoogle Scholar
7.Agarwal, M., De Guire, M.R., and Heuer, A. H., J. Am. Ceram. Soc. 80 (12), 2967 (1997).CrossRefGoogle Scholar
8.Wang, Y., Supothina, S., De Guire, M. R., Heuer, A. H., Collins, R. J., and Sukenik, C. N., Chem. Mater. 10, 21352144 (1998).CrossRefGoogle Scholar
9. (a)Kumar, A., Biebuyck, H. A., and Whitesides, G. M., Langmuir 10, 1498 (1994);CrossRefGoogle Scholar
(b)Charych, D. H. and Bednarski, M.D., MRS Bull. 17 (11), 61 (1992).CrossRefGoogle Scholar
10.Cohen, S. R., Naaman, R., and Sagiv, J., J. Phys. Chem. 90, 3054– 3056 (1986).CrossRefGoogle Scholar
11.Murphy, M. A., Nordgren, C. E., Fischetti, R. F., Blasie, J. K., Peticolas, L. J., and Bean, J.C., J. Phys. Chem. 99, 14,039 (1995).CrossRefGoogle Scholar
12.Calistri-Yeh, M., Kramer, E. J., Sharma, R., Zhao, W., Rafailovich, M. H., Sokolov, J., and Brock, J. D., Langmuir 12, 2747 (1996).CrossRefGoogle Scholar
13.Brandriss, S. and Margel, S., Langmuir 9, 1232 (1993).CrossRefGoogle Scholar
14.Kluth, G. J., Sung, M. M., and Maboudian, R., Langmuir 13 (14), 3775 (1997).CrossRefGoogle Scholar
15. (a)Balachander, N. and Sukenik, C. N., Langmuir 6, 1621 (1990);CrossRefGoogle Scholar
(b)Collins, R. J. and Sukenik, C. N., Langmuir 11, 2322 (1995).CrossRefGoogle Scholar
16. (a)Gallagher, P. K., Thermochim. Acta 26, 175 (1978);CrossRefGoogle Scholar
(b)Gallagher, P. K., Thermochim. Acta, 82, 325 (1984).CrossRefGoogle Scholar
17.Clarke, D. R., Ultramicroscopy 4, 33 (1979).CrossRefGoogle Scholar
18.Rühle, M. and Sass, N. L., Philos. Mag. A49, 759 (1984).CrossRefGoogle Scholar
19.Ness, J. N., Stobbs, W. M., and Page, T. F., Philos. Mag. A54, 679 (1986).CrossRefGoogle Scholar
20.Cinibulk, M.K., Kleebe, H-J., and Rühle, M., J. Am. Ceram. Soc. 76, 426 (1993).CrossRefGoogle Scholar
21.Chen, S-Y. and Chen, I-W., J. Am. Ceram. Soc. 78, 2929 (1995).CrossRefGoogle Scholar
22.Wright, J. S., Schwartz, J. M., Schmidt, L. D., and Falter Francis, L., J. Am. Ceram. Soc. 78, 2360 (1995).CrossRefGoogle Scholar
23. (a)Solomon, D.H. and Hawthorne, D. G., Chemistry of Pigments and Filler (John Wiley & Sons, Inc., New York, 1983);Google Scholar
(b)Diebold, M. P., Surf. Coatings Int. 1995 (6), 250 (1995).Google Scholar

Send article to Kindle

To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Pyrolysis of self-assembled organic monolayers on oxide substrates
Available formats
×

Send article to Dropbox

To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

Pyrolysis of self-assembled organic monolayers on oxide substrates
Available formats
×

Send article to Google Drive

To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

Pyrolysis of self-assembled organic monolayers on oxide substrates
Available formats
×
×

Reply to: Submit a response

Please enter your response.

Your details

Please enter a valid email address.

Conflicting interests

Do you have any conflicting interests? *