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Phase transition, dielectric and electrostrictive behaviors in (1 – x)PYN–xPMN

Published online by Cambridge University Press:  31 January 2011

Dong Heon Kang
Affiliation:
Department of Electronic Materials Engineering, The University of Suwon, Suwon 440–600, Korea
Yong Hwa Lee
Affiliation:
Department of Electronic Materials Engineering, The University of Suwon, Suwon 440–600, Korea
Ki Hyun Yoon
Affiliation:
Department of Ceramic Engineering, Yonsei University, Seoul 120–749, Korea
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Abstract

A system of (1 − x)Pb(Yb1/2Nb1/2)O3 (PYN)–xPb(Mg1/3Nb2/3)O3 (PMN) (0 ≤ x ≤ 1) has been investigated with regard to its phase transition, densification, and dielectric and electrostrictive properties. According to the XRD study, a crystal structure transformed from orthorhombic to pseudocubic at approximately x = 0.22. The superlattice peaks were gradually weakened with increasing x, and disappeared above x = 0.22. Increasing x led to an increase in the maximum dielectric constant and a decrease in transition temperature over the entire composition range. As a result of P-E hysteresis loops, successive phase transitions of ferroelectric-antiferroelectric-paraelectric were observed to occur in the range of 0.18 ≤ x ≤ 0.25 with increasing temperature, while the direct transition into the paraelectric region was found to take place for x ≥ 0.3. From the field-induced strain measurement, high electrostrictive coefficients, 7.3–8.2 × 10−2 (m4/C2), were determined in the PYN-rich range (x ≤ 0.1). Based on the results, a phase diagram of the system was constructed with variations in x and temperature.

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Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

1.Shrout, T. R. and Halliyal, A., Am. Ceram. Soc. Bull. 66, 704 (1987).Google Scholar
2.Halliyal, A., Kumar, V., Newnham, R. E., and Cross, L. E., Am. Ceram. Soc. Bull. 66, 571 (1987).Google Scholar
3.Shrout, T. R., Swartz, S. L., and Haun, M. J., Ceram. Bull. 63, 808 (1984).Google Scholar
4.Nomura, S., Jang, S. J., Cross, L. E., and Newnham, R. E., J. Am. Ceram. Soc. 62, 485 (1979).CrossRefGoogle Scholar
5.Yoon, K. H., Kim, S. Y., and Kang, D. H., J. Mater. Res. 10, 4 (1995).Google Scholar
6.Yamamoto, T. and Ohashi, S., Jpn. J. Appl. Phys. 34 (9B), 5349 (1995).CrossRefGoogle Scholar
7.Yonezawa, M., Ferroelectrics 68, 181 (1986).CrossRefGoogle Scholar
8.Furuya, M., Mori, T., and Ochi, A., J. Appl. Phys. 75, 4144 (1994).CrossRefGoogle Scholar
9.Nomura, S., Kuwata, J., Uchino, K., Jang, S. J., Cross, L. E., and Newnham, R. E., Phys. Status Solidi 57, 317 (1980).CrossRefGoogle Scholar
10.Smolenskii, G. A., Agranovskaya, A. I., Povov, S. N., and Isupov, V. A., Sov. Phys. Tech. Phys. 3, 1981 (1958).Google Scholar
11.Poplavko, Y. M. and Tsykalov, V. G., Sov. Phys. Solid State 9, 2600 (1965).Google Scholar
12.Kwon, J. R. and Choo, W. K., J. Phys.: Condens. Matter 3, 2147 (1991).Google Scholar
13.Swartz, S. L. and Shrout, T. R., Mater. Res. Bull. 17, 1245 (1982).CrossRefGoogle Scholar
14.Kwon, J. R., Choo, C. K. K., and Choo, W. K., Jpn. J. Appl. Phys. 30, 1028 (1991).CrossRefGoogle Scholar
15.Tomashpoll'skii, Y. Y. and Nenevtsev, Y. N., Sov. Phys. Solid State 6, 2388 (1965).Google Scholar
16.Yoon, K. H., Kwak, C. K., and Kang, D. H., Ferroelectrics 116, 231 (1991).CrossRefGoogle Scholar
17.Cross, L. E., Ferroelectrics 76, 241 (1987).CrossRefGoogle Scholar
18.Shirane, G. and Hoshino, S., Acta Crystallogr. 7, 203 (1954).CrossRefGoogle Scholar
19.Yoon, K. H., Hwang, S. C., and Kang, D. H., J. Mater. Sci. 32, 17 (1997).CrossRefGoogle Scholar
20.Uchino, K., Tatsumi, M., Hayashi, I., and Hayashi, T., Jpn. J. Appl. Phys. 24, Suppl. 733 (1985).Google Scholar
21.Masuda, Y., Jpn. J. Appl. Phys. 33, 5549 (1994).CrossRefGoogle Scholar
22.Uchino, K., Nomura, S., Cross, L. E., Newnham, R. E., and Jang, S. J., J. Mater. Sci. 16, 569 (1981).CrossRefGoogle Scholar

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