Hostname: page-component-8448b6f56d-sxzjt Total loading time: 0 Render date: 2024-04-24T12:57:30.292Z Has data issue: false hasContentIssue false
  • English
  • Français

Microstructures induced by femtosecond laser pulses inside glasses

Published online by Cambridge University Press:  31 January 2011

Dong Su ,
Nan Jiang ,
Jianrong Qiu  and
John C.H. Spence
Nan Jiang*
Affiliation:
Department of Physics, Arizona State University, Tempe, Arizona 85287-1504
Jianrong Qiu
Affiliation:
State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, China
John C.H. Spence
Affiliation:
Department of Physics, Arizona State University, Tempe, Arizona 85287-1504
*
a) Address all correspondence to this author. e-mail: nan.jiang@asu.edu
Get access

Abstract

In this article, the chemical and structural changes inside soda-lime glasses induced by femtosecond (fs) laser pulsing have been reported, based on transmission electron microscopy and electron energy loss spectroscopy studies. Under fs-laser interaction, Na-rich phases are formed, and Na nanoparticles are also precipitated around the Na-rich phases. These findings demonstrate how powerful and efficient the fs-laser pulsing and interaction can be in making novel microstructures in soda-lime silicate glass, and they bridge the gap between the macroscale property changes and nanometer-scale structures.

Keywords

Laser decompositionMicrostructureTransmission electron microscopy (TEM)
Type
Articles
Information
Journal of Materials Research , Volume 24 , Issue 6 , June 2009 , pp. 1983 - 1988
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1Shimotsuma, Y., Hirao, K., Kazansky, P.G., and Qiu, J.: Three-dimensional micro and nano-fabrication in transparent materials by femtosecond laser. Jpn. J. Appl. Phys. 44, 4735 (2005)Google Scholar
2Glazer, E.N., Milosavljevic, M., Huang, L., Finlay, R.J., Her, T-H., Callan, J.P., and Mazur, E.: Three-dimensional optical storage inside transparent materials. Opt. Lett. 21, 2023 (1996)Google Scholar
3Glazer, E.N. and Mazur, E.: Ultrafast-laser driven micro-explosions in transparent materials. Appl. Phys. Lett. 71, 882 (1997)CrossRefGoogle Scholar
4Qiu, J., Zhu, C., Nakaya, T., Si, J., Kojima, K., Ogura, F., and Hirao, K.: Space-selective valence state manipulation of transition metal ions inside glasses by a femtosecond laser. Appl. Phys. Lett. 79, 3567 (2001)Google Scholar
5Davis, K.M., Miura, K., Sugimoto, N., and Hirao, K.: Writing waveguides in glass with a femtosecond laser. Opt. Lett. 21, 1729 (1996)Google Scholar
6Miura, K., Qiu, J., Inouye, H., Mitsuyu, T., and Hirao, K.: Ultrafast-laser driven micro-explosions in transparent materials. Appl. Phys. Lett. 71, 3329 (1997)Google Scholar
7Watanabe, W. and Itoh, K.: Fabrication of photonic devices with femtosecond laser pulses. SPIE Proc. 5340, 119 (2004)Google Scholar
8Kawamura, K., Hirano, M., Kamiya, T., and Hosono, H.: Holo-graphic writing of volume-type microgratings in silica glass by a single chirped laser pulse. Appl. Phys. Lett. 81, 1137 (2002)Google Scholar
9Bricchi, E., Mills, J.D., Kazansky, P.G., Klappauf, B.G., and Baumberg, J.J.: Holographic data storage on nonphotosensitive glass with a single femtosecond laser pulse. Opt. Lett. 27, 2200 (2002)Google Scholar
10Sun, H., Mizeikis, V., Xu, Y., Juodkazis, S., Ye, J., Matsuo, S., and Misawa, H.: Microcavities in polymeric photonic crystals. Appl. Phys. Lett. 79, 1 (2001)Google Scholar
11Qiu, J., Jiang, X., Zhu, C., Shirai, M., Si, J., Jiang, N., and Hirao, K.: Manipulation of gold nanoparticles inside transparent materials. Angew. Chem. Int. Ed. 43, 2230 (2004)Google Scholar
12Kazansky, P.G., Qiu, J., Shimotsuma, Y., Bricchi, E., and Hirao, K.: Femtosecond laser nano-structuring of transparent materials. Proc. SPIE Int. Soc. Opt. Eng. 5399, 88 (2004)Google Scholar
13Zoubir, A., Rivero, C., Grodsky, R., Richardson, K., Richardson, M., Cardinal, T., and Couzi, M.: Laser-induced defects in fused silica by femtosecond IR irradiation. Phys. Rev. B: Condens. Matter 73, 224117 (2006)Google Scholar
14Streltsov, A.M. and Borrelli, N.F.: Study of femtosecond-laser-written waveguides in glasses. J. Opt. Soc. Am. B 19, 2496 (2002)Google Scholar
15Schaffer, C.B., Garcia, J.F., and Mazur, E.: Bulk heating of transparent materials using a high-repetition-rate femtosecond laser. Appl. Phys. A 76, 351 (2003)Google Scholar
16Jiang, N. and Silcox, J.: Electron irradiation induced phase decomposition in alkaline earth multi-component oxide glass. J. Appl. Phys. 92, 2310 (2002)Google Scholar
17Jiang, N., Qiu, J., Ellison, A., and Silcox, J.: Fundamentals of high-energy electron-irradiation-induced modifications of silicate glasses. Phys. Rev. B: Condens. Matter 68, 64207 (2003)Google Scholar
18Jiang, N., Su, D., and Spence, J.C.H.: Sodium reconstruction on surface of silicate glasses in transmission electron microscope. Appl. Phys. Lett. 91, 231906 (2007)Google Scholar
19Paul, A.: Chemistry of Glasses (Chapman and Hall, London, 1990), p. 101.Google Scholar
20Dickinson, J.T., Orlando, S., Avanesyan, S.M., and Langford, S.C.: Color center formation in soda lime glass and NaCl single crystals with femtosecond laser pulses. Appl. Phys. A 79, 859 (2004)Google Scholar