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Diamond deposition on Ni/Ni-diamond coated stainless steel substrate

Published online by Cambridge University Press:  31 January 2011

A. K. Sikder
Affiliation:
Department of Physics, Indian Institute of Technology, Bombay-400 076, India
T. Sharda
Affiliation:
Department of Physics, Indian Institute of Technology, Bombay-400 076, India
D. S. Misra
Affiliation:
Department of Physics, Indian Institute of Technology, Bombay-400 076, India
D. Chandrasekaram
Affiliation:
Department of Earth Sciences, Indian Institute of Technology, Bombay-400 076, India
P. Veluchamy
Affiliation:
Department of Applied Chemistry, Gifu University, Gifu 501, Japan
H. Minoura
Affiliation:
Department of Applied Chemistry, Gifu University, Gifu 501, Japan
P. Selvam
Affiliation:
Department of Chemistry, Indian Institute of Technology, Bombay-400 076, India
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Abstract

Electrodeposited Ni and Ni-diamond composite layers were used as diffusion barriers for Fe to facilitate the diamond growth on stainless steel substrates. Raman spectroscopy and scanning electron microscopy show the formation of good quality diamond crystallites by chemical vapor deposition. X-ray diffraction results indicate that the expansion of Ni unit cell has taken place due to the formation of the Ni–C solid solution. This observation is also well supported by x-ray photoelectron spectroscopy studies. The lattice constant of the expanded Ni unit cell matches closely with the diamond, and this may be helpful in explaining the epitaxial growth of diamond on single-crystal Ni observed by others.

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Copyright
Copyright © Materials Research Society 1999

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References

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