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Cluster spin-glasslike behavior in nanoparticles of diluted magnetic semiconductors ZnS:Mn

Published online by Cambridge University Press:  31 January 2011

Zhen-Hua Wang*
Shenyang National Laboratory for Materials Science, Institute of Metal Research, and International Centre for Materials Physics, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
Dian-Yu Geng
Shenyang National Laboratory for Materials Science, Institute of Metal Research, and International Centre for Materials Physics, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
Da Li
Shenyang National Laboratory for Materials Science, Institute of Metal Research, and International Centre for Materials Physics, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
Zhi-Dong Zhang
Shenyang National Laboratory for Materials Science, Institute of Metal Research, and International Centre for Materials Physics, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China
a)Address all correspondence to this author. e-mail:
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Zn1−xMnxS nanoparticles with x = 0.08, 0.16, and 0.32 were synthesized by a coprecipitation reaction between nitrate and sodium sulfide at room temperature in air. The magnetic properties of the Zn1−xMnxS nanoparticles were investigated by alternating-current (ac) susceptibility and direct-current (dc) magnetization measurements. The Mn3O4 phase was observed to exist in the Zn1−xMnxS nanoparticles as x ⩾ 0.16. The actual concentrations (x) of Mn-doped ZnS nanoparticles were determined by energy-dispersive x-ray analysis (EDAX) to be 0.06, 0.11, and 0.20, respectively, corresponding to the initial concentrations x = 0.08, 0.16, and 0.32. All the nanoparticles had the cubic structure and the lattice constant of Zn1−xMnxS phase increased with increasing Mn dopant concentration. For the Zn0.68Mn0.32S nanoparticles, there was evidence for appearance of cluster spin-glasslike behavior, as indicated by two maxima around 15 and 25 K in temperature dependence of ac susceptibility. The frequency independence of the peak at higher temperature is related to the intracluster ferromagnetic (FM) interactions, and the frequency dependence of the peak at lower temperature is associated with the spin glass. All the results revealed that the concentration of Mn2+ in Mn–ZnS and the amount of Mn3O4 were crucial for the cluster spin-glass behavior, which was not found when the real concentration (x) was unequal to 0.20 in Zn1−xMnxS.

Copyright © Materials Research Society 2007

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