Hostname: page-component-7479d7b7d-m9pkr Total loading time: 0 Render date: 2024-07-11T06:19:20.865Z Has data issue: false hasContentIssue false

Double-diffusive convection caused by coupled molecular diffusion

Published online by Cambridge University Press:  20 April 2006

Trevor J. Mcdougall
Affiliation:
Research School of Earth Sciences, Australian National University, P.O. Box 4, Canberra, A.C.T. 2600

Abstract

Double-diffusive convection is studied for the case where a large coupled diffusion (or cross-diffusion) effect is present. The Soret effect is a familiar example of this cross-diffusion where the flux of the solute depends not only on its own spatial gradient but also on the in situ temperature gradient. The linear stability analysis of double-diffusive convection has been extended to include the two cross-diffusion flux terms and it has been shown that, with a sufficiently large coupled diffusion effect, fingers can form even when the concentrations of both components make the fluid's density gradient statically stable. The conditions under which the diffusive instability can occur are compared with those for the formation of fingers and it is shown that these two types of double-diffusive convection cannot occur together in any particular set of linear property gradients. We then consider finite-amplitude, steady, infinitely long fingers and show that a sufficiently large cross-diffusion effect can again allow fingers to exist when the concentrations of both solutes increase with depth. It is also shown that the diffusion of properties from an initially sharp interface may set up vertical gradients that are favourable for the formation of fingers.

Type
Research Article
Copyright
© 1983 Cambridge University Press

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Antoranz, J. C. & Velarde, M. G. 1979 Thermal diffusion and convective stability: The role of uniform rotation of the container. Phys. Fluids 22, 10381043.Google Scholar
Caldwell, D. R. 1974 Experimental studies on the onset of thermohaline convection J. Fluid Mech. 64, 347367.Google Scholar
Cussler, E. L. 1976 Multicomponent Diffusion. Elsevier.
Cussler, E. L. & Lightfoot, E. N. 1965 Multicomponent diffusion involving high polymers. I. Diffusion of monodisperse polystyrene in mixed solvents J. Phys. Chem. 69, 11351144.Google Scholar
Fujita, H. & Gosting, L. J. 1956 An exact solution of the equations of free diffusion in three-component systems with interacting flows, and its use in evaluation of the diffusion coefficients J. Chem. Soc. Am. 78, 10991107.Google Scholar
Giglio, M. & Vendramini, A. 1977 Buoyancy-driven instability in a dilute solution of macromolecules Phys. Rev. Lett. 39, 10141017.Google Scholar
Huppert, H. E. & Manins, P. C. 1973 Limiting conditions for salt-fingering at an interface Deep-Sea Res. 20, 315323.Google Scholar
Hurle, D. T. J. & Jakeman, E. 1971 Soret-driven thermosolutal convection J. Fluid Mech. 47, 667687.Google Scholar
Leaist, D. G. & Lyons, P. A. 1980 Multicomponent diffusion in dilute solutions of mixed electrolytes Aust. J. Chem. 33, 18691887.Google Scholar
Miller, D. G. 1960 Thermodynamics of irreversible processes Chem. Rev. 60, 1536.Google Scholar
Miller, L. 1966 Instabilities in multicomponent liquid diffusion J. South African Chem. Inst. 19, 125129.Google Scholar
Miller, L., Spurling, T. H. & Mason, E. A. 1967 Instabilities in ternary diffusion Phys. Fluids 10, 18091813.Google Scholar
Piacsek, S. A. & Toomre, J. 1980 Nonlinear evolution and structure of salt fingers. In Marine Turbulence (ed. J. C. J. Nihoul), pp. 193219. Elsevier.
Preston, B. N., Laurent, T. C., Comper, W. D. & Checkley, G. J. 1980 Rapid polymer transport in concentrated solutions through the formation of ordered structures Nature 287, 499503.Google Scholar
Schechter, R. S., Prigogine, I. & Hamm, J. R. 1972 Thermal diffusion and convective stability Phys. Fluids 15, 379386.Google Scholar
Schmitt, R. W. & Georgi, D. T. 1982 Fine structure and microstructure in the North Atlantic current. Submitted for publication.
Stern, M. E. 1975 Ocean Circulation Physics. Academic.
Turner, J. S. 1973 Buoyancy Effects in Fluids. Cambridge University Press.
Velarde, M. G. & Schechter, R. S. 1972 Thermal diffusion and convective stability. II. An analysis of the convected fluxes Phys. Fluids 15, 17071714.Google Scholar
Vitagliano, V., Sartorio, R. & Costantino, L. 1974 Cation exchange diffusion experiments J. Phys. Chem. 22, 22922296.Google Scholar
Vitagliano, V., Zagari, A., Sartorio, R. & Corcione, M. 1972 Dissipative structures and diffusion in ternary systems J. Phys. Chem. 76, 20502055.Google Scholar
Wendt, R. P. & Shamim, M. 1970 Isothermal diffusion in the system water-magnesium chloride-sodium chloride as studied with the rotating diaphram cell J. Phys. Chem. 74, 27702783.Google Scholar
Williams, A. J. 1981 The role of double-diffusion in a Gulf Stream frontal intrusion J. Geophys. Res. 86, 19171928.Google Scholar