New calculations have been carried out in intermediate coupling of the wavelengths and intensities of the Fe XXIV transitions ls2nℓ-ls2pnℓ with n ≥ 3.

It is shown that some of these lines are situated on the short wave-length side of the helium-like Fe XXV resonance transition. For the intensities new calculations of the rates of autoionization and radiative decay have been made for the levels involved. Only dielectronic capture has been considered because the contribution of direct inner-shell excitation of the doubly excited states with n ≥ 3 is expected to be small in low density astrophysical plasmas.

For this reason both wavelengths and intensities are compared with the only available solar flare Iron spectra of Grineva et al. (1973). Some features not yet identified in these spectra can be explained with the results of the present calculations. These lead to an important new diagnostic capability for solar flare soft X-ray spectra.