Hostname: page-component-cd4964975-96cn4 Total loading time: 0 Render date: 2023-04-02T00:55:12.883Z Has data issue: true Feature Flags: { "useRatesEcommerce": false } hasContentIssue true
  • English

Experimental studies of the dissociative recombination processes for the C6D6+ and C6D7+ ions

Published online by Cambridge University Press:  30 March 2011

C. Joblin ,
A.G.G.M. Tielens ,
M. Hamberg ,
E. Vigren ,
R.D. Thomas ,
V. Zhaunerchyk ,
M. Zhang ,
S. Trippel ,
M. Kaminska  and
I. Kashperka
...Show all authors
M. Hamberg
Affiliation:
Department of Physics, Stockholm University, SE-106 91 Stockholm, Sweden. e-mail: mathias.hamberg@physto.se ;
E. Vigren
Affiliation:
Department of Physics, Stockholm University, SE-106 91 Stockholm, Sweden. e-mail: mathias.hamberg@physto.se ;
R.D. Thomas
Affiliation:
Department of Physics, Stockholm University, SE-106 91 Stockholm, Sweden. e-mail: mathias.hamberg@physto.se ;
V. Zhaunerchyk
Affiliation:
Radboud University Nijmegen, Institute for Molecules and Materials, PO Box 9010, 6500 GL Nijmegen, The Netherlands
M. Zhang
Affiliation:
Institute of Modern Physics, Chinese Academy of Sciences, 509 Nanchang Rd., Lanzhou 730000, China
S. Trippel
Affiliation:
Department of Physics, Albert-Ludwigs Universität Freiburg, Hermann-Herder-Str. 3, 79104 Freiburg, Germany
M. Kaminska
Affiliation:
Jan Kochanowski University, Świȩtokrzyska 15, 25406 Kielce, Poland
I. Kashperka
Affiliation:
Department of Physics, Stockholm University, SE-106 91 Stockholm, Sweden. e-mail: mathias.hamberg@physto.se ;
M. af Ugglas
Affiliation:
Department of Physics, Stockholm University, SE-106 91 Stockholm, Sweden. e-mail: mathias.hamberg@physto.se ;
A. Källberg
Affiliation:
Manne Siegbahn Laboratory, Frescativägen 26, 114 18 Stockholm, Sweden
A. Simonsson
Affiliation:
Manne Siegbahn Laboratory, Frescativägen 26, 114 18 Stockholm, Sweden
A. Paál
Affiliation:
Manne Siegbahn Laboratory, Frescativägen 26, 114 18 Stockholm, Sweden
J. Semaniak
Affiliation:
Jan Kochanowski University, Świȩtokrzyska 15, 25406 Kielce, Poland
M. Larsson
Affiliation:
Department of Physics, Stockholm University, SE-106 91 Stockholm, Sweden. e-mail: mathias.hamberg@physto.se ;
W.D. Geppert
Affiliation:
Department of Physics, Stockholm University, SE-106 91 Stockholm, Sweden. e-mail: mathias.hamberg@physto.se ;

Abstract

HTML view is not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

We have investigated the dissociative recombination (DR) of the C6D6+ and C6D7+ ions using the CRYRING heavy-ion storage ring at Stockholm University, Sweden. The dissociative recombination branching ratios were determined at minimal collision energy, showing that the DR of both ions was dominated by pathways keeping the carbon atoms together in one product. The absolute reaction cross sections for the titular ions are best fitted by σ(Ecm [eV]) = 1.3 ± 0.4 × 10-15 (Ecm [eV])−1.19 ± 0.02 cm2 (C6D6+) and σ(Ecm [eV]) = 1.1 ± 0.3 ×  10-15(Ecm [eV])−1.33 ± 0.02 cm2 (C6D7+) in the intervals 3-300 meV and 3-200 meV respectively. The thermal rate constants of the titular reactions are best described by: k(T) = 1.3 ± 0.4 × 10-6(T/300)−0.69 ± 0.02 cm3s-1 for C6D6+ and k(T) = 2.0 ± 0.6 × 10-6 (T/300)−0.83 ± 0.02 cm3s-1 for C6D7+. These expressions correlates well with earlier flowing afterglow studies on the same process.

Type
Research Article
Information
European Astronomical Society Publications Series , Volume 46: PAHs and the Universe: A Symposium to Celebrate the 25th Anniversary of the PAH Hypothesis , 2011 , pp. 241 - 249
Copyright
© EAS, EDP Sciences 2011

References

Abouelaziz, H., Gomet, J.C., Pasquerault, D., Rowe, B.R., & Mitchell, J.B.A., 1993, J. Chem. Phys., 99, 237 CrossRef
Boulanger, F., 1999, in Solid State Matter: The ISO Revolution, Lecture 2, ed. L. dH´endecour, C. Joblin, & A. Jones (New York Springer), 19
Cernicharo, J., Heras, A.M., Tielens, A.G.G.M., et al., 2001, Astrophys. J. Lett., 546, 123 CrossRef
Geppert, W.D., Thomas, R.D., Ehlerding, A., et al., 2005, J. Phys. Conf. Ser., 4, 26 CrossRef
Hamberg, M., 2010, A&A, 514, A83
Kuck, D., 1990, Mass Spectrometry Reviews, 9, 187 CrossRef
Le Page, V., Snow, T.P., & Bierbaum, V.M., 2009, ApJ, 704, 274 CrossRef
Lias, S.G., & Ausloos, P., 1985, J. Chem. Phys., 82, 3613 CrossRef
Lias, S.G., Bartmess, J.E., Liebman, J.F., et al., 1988, J. Phys. Chem. Ref. Data., 17 Suppl. 1
McLain, J.L., Poterya, V., Molek, C.D., Babcock, L.M., & Adams, N.G., 2004, J. Phys. Chem., 108, 6704 CrossRef
Milligan, D.B., Wilson, P.F., Freeman, C.G., Meot-Ner, M., & McEwan, M.J., 2002, J. Phys. Chem. A, 106, 9745 CrossRef
Mowat, J.R., Danared, H., Sundtroem, G., et al., 1995, Phys. Rev. Lett., 74, 50 CrossRef
Neau, A., Al-Khalili, A., Rosén, S., et al., 2000, J. Chem. Phys., 113, 1762 CrossRef
Paal, A., Simonsson, A., Dietrich, J., & Mohos, I., 2006, Proceedings of EPAC2006, 1196
Solca, N., & Dopfer, O., 2002, Angew. Chem. Int. Ed., 41, 3628 3.0.CO;2-1>CrossRef
Spanel, P., & Smith, D., 1998, Int. J. Mass Spectrom., 181, 1 CrossRef
Spanel, P., Smith, D., & Henchman, M., 1995, Int. J. Mass Spectrom. Ion Proc., 141, 117 CrossRef
Thomas, R.D., 2008, Mass Spectrom. Rev., 27, 485 CrossRef
Vinatier, S., Bézard, B., Fouchet, T., et al., 2007, Icarus, 188, 120 CrossRef
Vuitton, V., Yelle, R., & Cui, J., 2008, J. Geophys. Res., 113, E05007 CrossRef
Woods, P.M., Millar, T.J., Zijlstra, A.A., & Herbst, E., 2002, Astrophys J. Lett., 574, 167 CrossRef