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The Surface Modification of Zeolite 4A and Its Effect on the Water-Absorption Capability of Starch-G-Poly (Acrylic Acid) Composite

Published online by Cambridge University Press:  01 January 2024

Zhang Yan ,
Zhao Lin ,
Ma Kai  and
Mao Guozhu
Zhang Yan
Affiliation:
School of Chemical Engineering and Technology, Tianjin University, 92 Weijin Road, 300072, Nankai District, Tianjin, P.R. China School of Chemistry and Chemical Engineering, Yulin university, 4 Chongwen Road, 719000, Yulin City, Shaanxi, P.R. China
Zhao Lin*
Affiliation:
School of Chemical Engineering and Technology, Tianjin University, 92 Weijin Road, 300072, Nankai District, Tianjin, P.R. China School of Environment Science and Engineering, Tianjin University, 92 Weijin Road, 300072, Nankai District, Tianjin, P.R. China
Ma Kai
Affiliation:
School of Environment Science and Engineering, Tianjin University, 92 Weijin Road, 300072, Nankai District, Tianjin, P.R. China
Mao Guozhu
Affiliation:
School of Environment Science and Engineering, Tianjin University, 92 Weijin Road, 300072, Nankai District, Tianjin, P.R. China
*
*E-mail address of corresponding author: zhaolin@tju.edu.cn
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Abstract

The surface modification of Zeolite 4A using cetyl trimethyl ammonium bromide (CTAB) as a modifier via an ultrasonic method was carried out and the surface physicochemical properties measured. Response surface methodology (RSM) was developed with CTAB concentration, handling time, and handling temperature as variables, to help predict the performance of the modified zeolite under particular conditions. The influence of organic-modified surface treatment and of the amount of modified zeolite on the water-absorption capability of starch-g-poly (acrylic acid) hydrogel composites was also assessed. The results showed that the channels and skeleton structure of zeolite 4A were unchanged after organic modification by CTAB and the surface modification was effective. The results suggest that organic-modified zeolite 4A has improved the water-absorption capability.

Keywords

Organic ModificationResponse Surface MethodologySuperabsorbent CompositeWater AbsorptionZeolite 4A
Type
Article
Information
Clays and Clay Minerals , Volume 62 , Issue 3 , June 2014 , pp. 211 - 223
Copyright
Copyright © Clay Minerals Society 2014

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References

Ahmad, J. and Hägg, M., 2013 Preparation and characterization of polyvinyl acetate/zeolite 4A mixed matrix membrane for gas separation Journal of Membrane Science 427 73–84.CrossRefGoogle Scholar
Alummoottil, N.J. Janardhanan, S. Subramoney, N.M. and Moothandaserry, S.S., 2010 Response surface methodology for the optimization and characterization of cassava starch-graft-poly (acrylamide) Starch — Stärke 62 18–27.Google Scholar
Bernardi, A.C.D. Oliviera, P.P.A. Monte, M.B.D. and Barros, F.S., 2013 Brazilian sedimentary zeolite use in agriculture Microporous and Mesoporous Materials 167 16–21.CrossRefGoogle Scholar
Bezerra, M.A. Santelli, R.E. Oliveira, E.P. Villar, L.S. and Escaleira, L.A., 2008 Response surface methodology (RSM) as a tool for optimization in analytical chemistry Talanta 76 965–977.CrossRefGoogle ScholarPubMed
Dawood, A.S. and Li, Y., 2013 Modeling and optimization of new flocculant dosage and pH for flocculation: removal of pollutants from wastewater Water 5 342–355.CrossRefGoogle Scholar
Faghihian, H. Moayed, M. Firooz, A. and Iravani, M., 2013 Synthesis, characterization, and evaluation of a ferromagnetically modified natural zeolite composite for removal of Cs+ and Sr2+ Clays and Clay Minerals 61 193–203.CrossRefGoogle Scholar
Ferreira, S.L.C. Bruns, R.E. Ferreira, H.S. Matos, G.D. David, J.M. Branda.o, G.C. da Silva, E.G.P. Portugal, L.A. dos Reis, P.S. Souza, A.S. and Dos Santos, W.N.L., 2007 Box-Behnken design: An alternative for the optimization of analytical methods Analytica Chimica Acta 597 179–186.CrossRefGoogle ScholarPubMed
Guo, L.P. Chen, Y.Z. and Yang, J., 1999 The surface modification of zeolite-4A by CTAB and its properties Journal of Wuhan University of Technology-Material 14 18–23.Google Scholar
Gworek, B., 1992 Inactivation of cadmium in contaminated soils using synthetic zeolites Environmental Pollution 75 269–271.CrossRefGoogle ScholarPubMed
Haggerty, G.M. and Bowman, R.S., 1994 Sorption of chromate and other inorganic anions by organo-zeolite Environmental Science & Technology 28 452–458.CrossRefGoogle ScholarPubMed
Hui, K.S. Chao, C.Y.H. and Kot, S.C., 2005 Removal of mixed heavy metal ions in wastewater by zeolite 4A and residual products from recycled coal fly ash Journal of Hazardous Materials 127 89–91.CrossRefGoogle ScholarPubMed
Irani, M. Ismail, H. and Ahmad, Z., 2013 Preparation and properties of linear low-density polyethylene-g-poly (acrylic acid)/ organo-montmorillonite superabsorbent hydrogel composites Polymer Testing 32 502–512.CrossRefGoogle Scholar
Khoonsap, S. and Amnuaypanich, S., 2011 Mixed matrix membranes prepared from poly(vinyl alcohol) (PVA) incorporated with zeolite 4A-graft-poly(2-hydroxyethyl methacrylate) (zeolite-g-PHEMA) for the pervaporation dehydration of water-acetone mixtures Journal of Membrane Science 367 182–189.CrossRefGoogle Scholar
Lanthong, P. Nuisin, R. and Kiatkamjornwong, S., 2006 Graft copolymerization, characterization, and degradation of cassava starch-g-acrylamide/itaconic acid superabsorbents Carbohydrate Polymers 66 229–245.CrossRefGoogle Scholar
Le Van Mao, R. Sjiariel, B. and Dunnigan, J., 1991 Asbestos-derived zeolites as water-retaining materials in soils Zeolites 11 804–809.CrossRefGoogle Scholar
Lee, W.F. and Yang, L.G., 2004 Superabsorbent polymeric materials. XII. Effect of montmorillonite on water absorbency for poly (sodium acrylate) and montmorillonite nanocomposite superabsorbents Journal of Applied Polymer Science 92 3422–3429.CrossRefGoogle Scholar
Li, A. and Wang, A.Q., 2005 Synthesis and properties of clay-based superabsorbent composite European Polymer Journal 41 1630–1637.CrossRefGoogle Scholar
Lokhande, H.T. and Gotmare, V.D., 1999 Utilization of textile loomwaste as a highly absorbent polymer through graft copolymerization Bioresource Technology 68 283–286.CrossRefGoogle Scholar
Lundstedt, T. Seifert, E. Abramo, L. Thelin, B. Nyström, Pettersen, J. and Bergman, R., 1998 Experimental design and optimization Chemometrics and Intelligent Laboratory Systems 42 3–40.CrossRefGoogle Scholar
Mathakiya, I. Vangani, V. and Rakshit, A.K., 1998 Terpolymerization ofacrylamide, acrylic acid, and acrylonitrile: Synthesis and properties Journal of Applied Polymer Science 69 217–228.3.0.CO;2-Q>CrossRefGoogle Scholar
Misaelides, P., 2011 Application of natural zeolites in environmental remediation: A short review Microporous and Mesoporous Materials 144 15–18.CrossRefGoogle Scholar
Mohana Raju, K. and Padmanabha Raju, M., 2001 Synthesis and swelling properties of superabsorbent copolymers Advances in Polymer Technology 20 146–154.CrossRefGoogle Scholar
Razali, M.A. Sanusi, N. Ismail, H. Othman, N. and Ariffin, A., 2012 Application of response surface methodology (RSM) for optimization of cassava starch grafted polyDADMAC synthesis for cationic properties Starch — Stärke 64 935–943.CrossRefGoogle Scholar
Rožić, M. and Miljanić, S., 2011 Sorption of HDTMA cations on Croatian natural mordenite tuff Journal of Hazardous Materials 185 423–429.CrossRefGoogle ScholarPubMed
Saxena, S.K. Kumar, M. and Viswanadham, N., 2013 Studies on textural properties of lanthanum-exchanged Y zeolites as promising materials for value upgradation of Jatropha oil Journal of Materials Science 48 7949–7959.CrossRefGoogle Scholar
Schott, H., 1992 Swelling kinetics of polymers Journal of Macromolecular Science Part B — Physics 31 1–9.CrossRefGoogle Scholar
Spagnol, C. Rodrigues, F.H.A. Pereira, A.G.B. Fajardo, A.R. Rubira, A.F. and Muniz, E.C., 2012 Superabsorbent hydrogel nanocomposite based on starch-g-poly (sodium acrylate) matrix filled with cellulose nanowhiskers Cellulose 19 1225–1237.CrossRefGoogle Scholar
Stojakovic, D. Milenkovic, J. Daneu, N. and Rajic, N., 2011 A study of the removal of copper ions from aqueous solution using clinoptilolite from Serbia Clays and Clay Minerals 59 277–285.CrossRefGoogle Scholar
Wang, A. and Zhang, J.P., 2006 High-Absorption Resin Composed of Organic and Inorganic Materials Beijing Science Press.Google Scholar
Wang, C.Y. Zhou, J.T. He, J.K. Hao, C.S. Pan, Y.Z. and Meng, C.G., 2012 Synthesis of zeolite A and its application as a high-capacity cadmium ion exchanger Chinese Journal of Catalysis 33 1862–1869.Google Scholar
Wang, M.S. Liao, L.B. Zhang, X.L. Li, Z.H. Xia, Z.G. and Cao, W.D., 2011 Adsorption of low-concentration ammonium onto vermiculite from Hebei province, China Clays and Clay Minerals 59 459–465.CrossRefGoogle Scholar
Wang, S.G. Gong, W.X. Liu, X.W. Gao, B.Y. Yue, Q.Y. and Zhang, D.H., 2006 Removal of fulvic acids from aqueous solutions via surfactant modified zeolite Chemical Research in Chinese Universities 22 566–570.CrossRefGoogle Scholar
Weaver, M.O. Bagley, E.B. Fanta, G.F. and Doane, W.M., 1976.Highly absorbent starch-containing polymeric compositions US Patent 3.981.100Google Scholar
Zdanowicz, M. Schmidt, B. and Spychaj, T., 2010 Starch graft copolymers as superabsorbents obtained via reactive extrusion processing Polish Journal of Chemical Technology 12 14–17.CrossRefGoogle Scholar
Zhang, J. Li, A. and Wang, A., 2006 Study on superabsorbent composite. VI. Preparation, characterization and swelling behaviors of starch phosphate-graft-acrylamide/attapulgite superabsorbent composite Carbohydrate Polymers 65 150–158.CrossRefGoogle Scholar
Zhang, X.L. Li, Y.H. Hao, P.P. and Yang, S., 2011 Research on synthesis and performance of water preserver starchgrafted acrylic acid/zeolite/fly ash Journal of Anhui Agricultural Science 39 3–5.Google Scholar
Zhou, B. Liao, R.K. Li, Y.K. Gu, T. Yang, P.L. Feng, J. Xing, W.M. and Zou, Z.C., 2012 Water-absorption characteristics of organic-inorganic composite superabsorbent polymers and its effect on summer maize root growth Journal of Applied Polymer Science 126 423–435.Google Scholar
Zhou, J.P. Qiu, K.Q. and Fu, W.L., 2005 The surface modification of ZnO and its effect on the mechanical properties of filled polypropylene composites Journal of Composite Materials 39 1931–1941.CrossRefGoogle Scholar
Zwingmann, N. Mackinnon, I.D.R. and Gilkes, R.J., 2011 Use of a zeolite synthesized from alkali treated kaolin as a K fertiliser: Glasshouse experiments on leaching and uptake of K by wheat plants in sandy soil Applied Clay Science 53 684–690.CrossRefGoogle Scholar