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The Potential Use of Clay-Fly Ash Geopolymer in the Design of Active-Passive Liners: A Review

Published online by Cambridge University Press:  01 January 2024

Elmira Khaksar Najafi ,
Reza Jamshidi Chenari  and
Mahyar Arabani
Elmira Khaksar Najafi
Affiliation:
Department of Civil Engineering, Faculty of Engineering, University of Guilan, P.O. 3756, Rasht, Guilan, Iran
Reza Jamshidi Chenari*
Affiliation:
Department of Civil Engineering, Faculty of Engineering, University of Guilan, P.O. 3756, Rasht, Guilan, Iran
Mahyar Arabani
Affiliation:
Department of Civil Engineering, Faculty of Engineering, University of Guilan, P.O. 3756, Rasht, Guilan, Iran
*
*E-mail address of corresponding author: Jamshidi_reza@guilan.ac.ir
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Abstract

Because long-term leachate migration through a hydraulic barrier is inevitable, compacted clay and cementitious liners are commonly used as ‘active-passive’ liners to attenuate percolated leachate. The scarcity of suitable clay and because of the CO2 emitted during the production of Portland cement as well as drying shrinkage, flow rate due to consolidation, limited attenuation capacity, and chemical instability may mean that these are not the best choices of materials to use for this purpose. An environmentally friendly method to improve the properties of local clay and provision for a long-term physical and chemical containment are essential. Geopolymers can be environmentally friendly substitutes for Portland cement to improve soil properties, not just because of the reduced carbon dioxide emission, but also because of its superior physical and chemical properties, as well as significant early strength, reduced shrinkage, freeze-thaw resistance, long-term durability, and attenuation capacity. According to previous studies, class-F fly ash-based geopolymers activated with NaOH exhibit superior attenuation capacity and long-term durability. The presence of silica, alumina, and iron oxides and the lack of calcium oxide play pivotal roles in the acceptable attenuation capacity and chemical stability of class-F fly ash. Accordingly, a clay-fly ash geopolymer may also work as a sustainable liner with appropriate physical and chemical performance. Clay can also participate in the geopolymerization process as an alumino-silicate precursor. All components of clay-fly ash geopolymers possess acceptable adsorption capacity. The type and percentage of the constituent raw materials control the attenuation capacity and physical properties of final products, however. The porosity and conductivity of typical geopolymers are related to the activator type and concentration, water content, and curing condition. Furthermore, the properties of liner materials can be adjusted with respect to the target contaminants. The present study aimed to present a comprehensive review of the relevant studies to highlight the properties required.

Keywords

Active-passive linerAttenuationFly ashGeopolymersHeavy metals
Type
Article
Information
Clays and Clay Minerals , Volume 68 , Issue 4 , August 2020 , pp. 296 - 308
Copyright
Copyright © Clay Minerals Society 2020

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References

Alastair, M., Andrewa, H., Pascaline, P., Mark, E., & Pete, W. (2018). Alkali activation behavior of un-calcined montmorillonite and illite clay minerals. Applied Clay Science, 166, 250–261.Google Scholar
Al-Zboon, K., Al-Harahsheh, M. S., & Bani Hani, F. (2011). Fly ashbased geopolymer for Pb removal from aqueous solution. Hazardous Materials, 188, 414–421.CrossRefGoogle ScholarPubMed
Andreas, L., Diener, S., & Lagerkvist, A. (2014). Steel slags in a landfill top cover—Experiences from a full-scale experiment. Waste Management, 34, 692–701.CrossRefGoogle Scholar
Bagchi, A. (1987). Natural attenuation mechanisms of landfill leachate and effects of various factors on the mechanisms. Waste Management & Research, 453–463.CrossRefGoogle Scholar
Bakharev, T. (2005). Durability of geopolymer materials in sodium and magnesium sulphate solutions. Cement Concrete Research, 35, 1233–1246.CrossRefGoogle Scholar
Bowders, J., Gidley, J., & Usmen, M. (1990). Permeability and leachate characteristics of stabilized class F fly ash. Pp. 70–77 in: Transportation Research Record 1288 TRB, National Research Council, Washington D.C., April 1991.Google Scholar
Broderick, G. P., & Daniel, D. E. (1990). Stabilizing compacted clay against chemical attack. Geotechnical Engineering, 116, 1549– 1567.Google Scholar
Chakradhar, V. & Katoch, S.S. (2016). Study of fly ash in hydraulic barriers in landfills – A review. International Journal of Advanced Science, Engineering & Technology, 5, 32–38.Google Scholar
Chamberlain, E.J., Iskander, I., & Hunsicker, S.E. (1990). Effect of freeze-thaw cycles on the permeability and macrostructure of soils. Pp. 145–155 in: Proceeding of International Symposium on Frozen Soil Impacts on Agricultural, Range, and Forest Lands.Google Scholar
Chertkov, V. Y. (2000). Using surface cracks spacing to predict crack network geometry in swelling soils. Soil Science Society of America, 64, 1918–1921.CrossRefGoogle Scholar
Comire, D.C., Paterson, J.H., & Ritcey, D.J. (1989). Applications of geopolymer technology to waste stabilization. Pp. 161–165 in: Third International Conference On New frontiers for Hazardous Waste Management - Proceedings. US Government Printing Office, Cincinnati, Ohio, USA.Google Scholar
Creek, D. & Shackelford, C. (1992). Permeability and leaching characteristics of fly ash liner materials. Transportation Research Record 1345 TRB, National Research Council, Washington, D.C., 74–83.Google Scholar
Criado, M., Fernández Jiménez, A., Sobrados, I., Palomo, A., & Sanz, J. (2012). Effect of relative humidity on the reaction products of alkali activated fly ash. Journal of European Ceramic Society, 32, 2799–2807.CrossRefGoogle Scholar
Daniel, D. E. (1984). Predicting hydraulic conductivity of clay liners. Geotechnical Engineering, 110, 285–300.CrossRefGoogle Scholar
Daniel, D. E. (1993). Geotechnical Practice for Waste Disposal. Dordrecht, The Netherlands: Springer Science, Business, Media.CrossRefGoogle Scholar
Davidovits, J. (1991). Geopolymers: Inorganic polymeric new materials. Journal of Thermal Analysis, 37, 1633–1656.CrossRefGoogle Scholar
Davidovits, J. (1994). Alkaline cement and concretes, properties of geopolymer cements. in: Proceedings of the First International Conference on Alkaline Cements and Concretes, Kiev, Ukraine, 131–149.Google Scholar
Davidovits, J., & Comrie, D. (1988). Archaeological long-term durability of hazardous waste disposal: preliminary results with geopolymer technologies, Division of Environmental Chemistry. American Chemical Society, Extended Abstracts, 237–240. See also: Long term durability of hazardous toxic and nuclear waste disposals. Geopolymer '88: First European Conference on Soft Mineralurgy, 125–134.Google Scholar
Davidovits, J., Comrie, D., Paterson, J., & Ritcey, D. (1990). Geopolymeric concretes for environmental protection. ACI Concrete International, 12, 30–40.Google Scholar
Dinchak, W.G. (2009). A soil cement/synthetic liner for hazardous waste impoundments. Water International, 79–83.Google Scholar
Dolezal, J., Skvara, F., Svoboda, P., Sulc, R., Kopecky, L., Pavlasova, S., Myskova, L., Lucuk, M. & Dvoracek, K. (2007). Concrete based on fly ash geopolymers. Pp. 185–197 in: Alkali activated materials – research, production and utilization 3rd conference, Prague, Czech Republic.Google Scholar
Engelhardt, G., & Michel, D. (1987). High Resolution Solid State RMN of Silicates and Zeolites. New Delhi: John Wiley & Sons.Google Scholar
Fernandez-Jiménez, A., Cristelo, N., Miranda, T., & Palomo, A. (2017). Sustainable alkali activated materials: precursor and activator derived from industrial wastes. Journal of Cleaner Production, 114, 40–48.Google Scholar
Fernández Pereira, C., Galiano, Y., Querol, X., Antenucci, P., & Vale, J. F. (2009). Waste stabilization/solidification of an electric arc furnace dust using fly ash-based geopolymers. Fuel, 88, 1185–1193.CrossRefGoogle Scholar
Firoozfar, A., & Khosroshiri, N. (2016). Kerman clay improvement by lime and bentonite to be used as materials of landfill liner. Geotechnical & Geology Engineering, 35, 559–571.CrossRefGoogle Scholar
Fu, Y., Cai, L., & Wu, Y. (2011). Freeze-thaw cycle test and damage mechanics models of alkali-activated slag concrete. Construction Building & Materials, 25, 3144–3148.CrossRefGoogle Scholar
Fuller, W.H. (1977). Movement of Selected Metals, Asbestos and Cyanide in Soil, Applications to Waste Disposal Problems. EPA-600/2-77-020, U.S. EPA.Google Scholar
Ganjian, E., Classie, P., Tyrer, M., & Atkinson, A. (2004). Preliminary investigations into the use of secondary waste minerals as a novel cementitious landfill liner. Construction Building & Materials, 18, 689–699.CrossRefGoogle Scholar
Glasser, F. P. (2013). Cement in radioactive waste disposal. Waste Technology Section, Vienna: International Atomic Energy Agency.Google Scholar
Hettiaratchi, J. P. A., Achari, G., Joshi, R. C., & Okoli, R. E. (1999). Feasibility of using fly ash admixtures in landfill bottom liners or vertical barriers at contaminated site. Environmental Science and Health-A, 34, 1897–1917.CrossRefGoogle Scholar
Ishwarya, G. (2013). Development of geopolymer concrete cured at ambient temperature. M. Technical thesis, Roorkee, India: CSIR-Central Building Research Institute (AcSIR).Google Scholar
Javadian, H., Ghorbani, F., Tayebi, H. A., & Hosseini, S. M. (2015). Study of the adsorption of Cd (II). from aqueous solution using zeolite-based geopolymer, synthesized from coal fly ash; kinetic, isotherm and thermodynamic studies. Arabian Journal of Chemistry, 8, 837–849.CrossRefGoogle Scholar
Judith, L. L., Stephen, K., & Michael, W. G. (1992). Zeolite formation in class F fly ash blended cement pastes. Journal of the American Ceramic Society, 75, 1574–1580.Google Scholar
Kleppe, J. H., & Olson, R. E. (1985). Desiccation cracking of soil barriers hydraulic barriers in soil and rock. Hydraulic Barriers Soil Rock, 874, 263–275.CrossRefGoogle Scholar
Koch, D. (2002). Bentonites as a basic material for technical base liners and site encapsulation cut-off walls. Applied Clay Science, 21, 1–11.CrossRefGoogle Scholar
Komljenović, M., Baščarević, Z., & Bradić, V. (2010). Mechanical and microstructural properties of alkali-activated fly ash geopolymers. Journal of Hazardous Materials, 181, 35–42.CrossRefGoogle ScholarPubMed
Komnitsas, K., Bartzas, G., & Paspaliaris, I. (2004). Clean-up of acidic leachates using fly ash barriers: laboratory column studies. Global Nest Journal, 6, 81–89.Google Scholar
Li, L., Wang, S., & Zhu, Z. (2006). Geopolymeric adsorbents from fly ash for dye removal from aqueous solution. Advances in Colloid & Interface Science, 300, 52–59.CrossRefGoogle ScholarPubMed
Ma, Y., Hua, J., & Ye, G. (2013). The pore structure and permeability of alkali activated fly ash. Fuel, 104, 771–780.CrossRefGoogle Scholar
Ma, Y., & Ye, G. (2015). The shrinkage of alkali activated fly ash. Cement Concrete Research, 68, 75–82.CrossRefGoogle Scholar
Majone, M., Papini, M. P., & Rolle, E. (1998). Influence of metal speciation in landfill leachates on kaolinite sorption. Water Research, 32, 882–890.CrossRefGoogle Scholar
Minnesota, P. C. A. (1978). Disposal of Residuals by Landfilling. Minneapolis, Mnnesota, U.S.A.: Minnesota PCA.Google Scholar
Mishra, A., & Ravindra, V. (2015). On the utilization of fly ash and cement mixture as a landfill liner material. International Journal of Geosynthetics and Ground Engineering, 1, 16–22.CrossRefGoogle Scholar
Mitchell, J. K. (1976). Fundamentals of Soil Behavior. New York: John Wiley & Sons.Google Scholar
Mohan, S., & Gandhimathi, R. (2009). Removal of heavy metal ions from municipal solid waste leachate using coal fly ash as an adsorbent. Hazardous Materials, 169, 351–359.CrossRefGoogle ScholarPubMed
Mollah, M. Y. A., Hess, T. R., & Cocke, D. L. (1994). Surface and bulk studies of leached and un-leached fly ash using XPS, EDS, SEM and FT-IR techniques. Cement and Concrete Research, 24, 109–118.CrossRefGoogle Scholar
Mužek, M. N., Svilović, S., & Zelić, J. (2014). Fly ash-based geopolymeric adsorbent for copper ion removal from wastewater. Desalination & Water Treatment, 52, 2519–2526.CrossRefGoogle Scholar
Nhan, C. T., Graydon, J. W., & Kirk, D. W. (1996). Utilizing coal fly ash as a landfill barrier material. Waste Management, 16, 587–595.CrossRefGoogle Scholar
Oruh, S., & Nuri Ergun, O. (2010). Use of fly ash, phosphogypsum and red mud as a liner material for the disposal of hazardous zinc leach residue waste. Hazardous Materials, 173, 468–473.Google Scholar
Pacheco-Torgal, F., Castro-Gomes, J., & Jalali, S. (2008). Alkaliactivated binders: A review: Part 1. Historical background, terminology, reaction mechanisms and hydration products. Construction and Building Materials, 22, 1305–1314.CrossRefGoogle Scholar
Pacheco-Torgal, F., Labrincha, J., Leonelli, C., Palomo, A., & Chindaprasirt, P. (2015). Handbook of Alkali activated Cements, Mortars and Concretes, Woodhead Publishing in Civil and Structural Engineering, Elsevier, AmsterdamCrossRefGoogle Scholar
Palmer, B. G., Edil, T. B., & Benson, C. H. (2000). Liners for waste containment constructed with class F and C fly ashes. Hazardous Materials, 76, 193–216.CrossRefGoogle Scholar
Palomo, A., Grutzeck, M. W., & Blanco, M. T. (1999). Alkaliactivated fly ashes - a cement for the future. Cement Concrete Research, 29, 1323–1329.CrossRefGoogle Scholar
Palomo, A., Alonso, S., & Fernandez-Jiménez, A. (2004). Alkaline activation of fly ashes: NMR study of the reaction products. American Ceramic Society, 87, 1141–1145.CrossRefGoogle Scholar
Phair, J. W., Van Deventer, J. S. J., & Smith, J. D. (2004). Effect of Al source and alkali activation on Pb and Cu immobilisation in fly-ash based “geopolymers”. Applied Geochemistry, 19, 423–434.CrossRefGoogle Scholar
Pignatello, J. J. (1998). Soil organic matter as a nonporous sorbent of organic pollutants. Advances in Colloid Interface Science, 76, 445–467.CrossRefGoogle Scholar
Pignatello, J. J., & Xing, B. (1996). Mechanisms of slow sorption of organic chemicals to natural particles. Environmental Science & Technology, 30, 1–11.CrossRefGoogle Scholar
Prashanth, J. P., Sivapullaiah, P. V., & Sridharan, A. (2001). Pozzolanic fly ash as a hydraulic barrier in land fill. Engineering Geology, 60, 245–252.CrossRefGoogle Scholar
Provis, J. L., Lukey, G. C., & Van Deventer, J. S. J. (2005). Do geopolymers actually contain nanocrystalline zeolites? A reexamination of existing results. Materials Chemistry, 17, 3075–3085.CrossRefGoogle Scholar
Rao, R. K. A., Hess, T. R., Cocke, D. L., & Lauer, H. V. (1994). Fraction and characterisation of Texas lignite class F fly ash by XRD, TGA, FTIR and SFM. Cement and Concrete Research, 24, 1153–1164.Google Scholar
Rios, S., Cristelo, C., Viana Da Fonseca, A., & Ferreira, C. (2016). Structural performance of alkali activated soil-ash versus soil-cement. Material in Civil Engineering, 28(2).Google Scholar
Rogers, E.H. (1968). Soil-cement linings for water-containing structures. Pp. 95–105 in: Proceedings of Second Seepage Symposium, Phoenix, Arizona, USA, 95–105.Google Scholar
Ruen-ngam, D., Rungsuk, D., Apiratikul, R., & Pavasant, P. (2009). Zeolite formation from coal fly ash and its adsorption potential. Air & Waste Management Association, 59, 1140–1147.Google ScholarPubMed
Sahoo, P. K., Tripathy, S., Panigrahi, M. K. P., & Equeenuddin, S. K. M. D. (2013). Evaluation of the use of an alkali modified fly ash as a potential adsorbent for the removal of metals from acid mine drainage. Applied Water Science, 3, 567–576.CrossRefGoogle Scholar
Schevon, G. R., & Damas, G. (1986). Using double liners in landfill design and operation. Waste Management & Research, 4, 161–176.CrossRefGoogle Scholar
Shackelford, C. D., & Glade, M. J. (1994). Constant flow and constant gradient permeability tests on sand-bentonite fly ash mixtures. Hydraulic Conduct Waste Contaminant Transport Soil ASTM STP, 1142, 521–545.CrossRefGoogle Scholar
Sivapullaiah, P. V., & Lakshmikantha, H. (2004). Properties of fly ash as hydraulic barrier. Soil and Sediment Contamination, 13, 391–406.CrossRefGoogle Scholar
Sivapullaiah, P., & Moghal, A. (2011). Role of gypsum in the strength development of fly ashes with lime. Materials in Civil Engineering 23, 197–206.CrossRefGoogle Scholar
Skvara, F., Šmilauer, V., Hlaváček, P., Kopecký, L., & Ćilová, Z. (2012). A weak alkali bond in (N, K)-A-S-H gels: evidence from leaching and modeling. Ceramic Silikaty, 56, 374–382.Google Scholar
Suzuki, K., & Ono, Y. (2008). Leaching characteristics of stabilized/ solidified fly ash generated from ash melting plant. Chemosphere, 71, 922–932.CrossRefGoogle ScholarPubMed
Temuujin, J., Van Riessen, A., & Williams, R. (2009). Influence of calcium compounds on the mechanical properties of fly ash geopolymer pastes. Hazardous Material, 167, 82–88.CrossRefGoogle ScholarPubMed
Thornton, S. F., & Lerner, D. N. (2001). Attenuation of landfill leachate by clay liner materials in laboratory columns: 2. Behavior of inorganic contaminants. Waste Management & Research, 19, 70–88.CrossRefGoogle ScholarPubMed
UK Nirex (1993). Report No. 525, Scientific Update. (Harwell, Didcot, OXON UK): United Kingdom Nirex Ltd, p. 25.Google Scholar
Van Jaarsveld, J. G. S., Van Deventer, J. S. J., & Lorenzen, L. (1998). Factors affecting the immobilisation of metals in geopolymerised fly ash. Metallurgy and Materials Transaction-B, 29, 283–291.CrossRefGoogle Scholar
Van Jaarsveld, J. G. S., Van Deventer, J. S. J., & Schwartzman, A. (1999). The potential use of geopolymeric materials to immobilise toxic metals: Part II. Material and leaching characteristics. Minerals Engineering, 12, 75–91.CrossRefGoogle Scholar
Vesperman, K. D., Edil, T. B., & Berthouex, P. M. (1985). Conductivity of fly ash and fly ash sand mixtures. Hydraulic Barriers Soil Rock, 874, 289–298.CrossRefGoogle Scholar
Waijarean, N., Asavapisit, S., & Sombatsompop, K. (2014). Strength and microstructure of water treatment residue-based geopolymers containing heavy metals. Construction and Building Materials, 50, 486–491.CrossRefGoogle Scholar
Wang, S. H., Li, L., & Zhua, Z. H. (2007). Solid-state conversion of fly ash to effective adsorbents for Cu removal from wastewater. Hazardous Materials, 139, 254–259.CrossRefGoogle ScholarPubMed
Yeheyis, M. B., Shang, J. Q., & Yanful, K. Y. (2009). Feasibility of using coal fly ash for mine waste containment. Environmental Engineering, 136, 682–690.CrossRefGoogle Scholar
Zhang, Z., Wang, H., & Provis, J. L. (2012). Quantitative study of the reactivity of fly ash in geopolymerization by FTIR. Sustainable Cement-Based Materials, 1, 154–166.CrossRefGoogle Scholar