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Intercalation of 8-Hydroxyquinoline into Al-Smectites by Solid-Solid Reactions

Published online by Cambridge University Press:  01 January 2024

Nithima Khaorapapong ,
Kazuyuki Kuroda  and
Makoto Ogawa
Nithima Khaorapapong
Affiliation:
Department of Applied Chemistry, Waseda University, Okubo-3, Shinjuku-ku, Tokyo 169-8555, Japan
Kazuyuki Kuroda
Affiliation:
Department of Applied Chemistry, Waseda University, Okubo-3, Shinjuku-ku, Tokyo 169-8555, Japan Kagami Memorial Laboratory for Materials Science and Technology, Waseda University, Nishiwaseda-2, Shinjuku-ku, Tokyo 169-0051, Japan
Makoto Ogawa*
Affiliation:
Department of Earth Sciences, Waseda University, Nishiwaseda-1, Shinjuku-ku, Tokyo 169-8050, Japan PRESTO, Japan Science and Technology Corporation
*
*E-mail address of corresponding author: makoto@waseda.ac.jp
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Abstract

Tris(8-hydroxyquinoline)aluminum (III) complexes (Alq3), one of the molecules studied most widely for organic light-emitting devices, were formed in the interlayer spaces of smectites by solid-solid reactions between Al-smectites (Al-montmorillonite and Al-synthetic saponite (Sumecton)) and 8-hydroxyquinoline (8Hq) at room temperature. The intercalation of 8-hydroxyquinoline molecules into Al-smectites was demonstrated by powder XRD, FTIR, DTA, TG, TG-MS, and chemical analysis. The coordination of the ligand to the interlayer Al cations was proved by FTIR, UV-Vis, and photoluminescence spectroscopies. The luminescence intensity of Alq3-Sumecton was much greater than that of Alq3-montmorillonite, and this was ascribed to the very small amount of quenching impurities in Sumecton.

Keywords

8-HydroxyquinolineMontmorilloniteSolid-State IntercalationSumecton SASynthetic SaponiteTris(8-hydrox yquinoline)aluminum(III) Complex
Type
Research Article
Information
Clays and Clay Minerals , Volume 50 , Issue 4 , August 2002 , pp. 428 - 434
Copyright
Copyright © 2002, The Clay Minerals Society

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