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Infrared Study of Structural OH in Kaolinite, Dickite, Nacrite, and Poorly Crystalline Kaolinite at 5 to 600 K

Published online by Cambridge University Press:  02 April 2024

R. Prost ,
A. Dameme ,
E. Huard ,
J. Driard  and
J. P. Leydecker
R. Prost
Affiliation:
Station de Science du Sol, Institut National de la Recherche Agronomique, Route de Saint Cyr, 78026 Versailles, France
A. Dameme
Affiliation:
Station de Science du Sol, Institut National de la Recherche Agronomique, Route de Saint Cyr, 78026 Versailles, France
E. Huard
Affiliation:
Station de Science du Sol, Institut National de la Recherche Agronomique, Route de Saint Cyr, 78026 Versailles, France
J. Driard
Affiliation:
Station de Science du Sol, Institut National de la Recherche Agronomique, Route de Saint Cyr, 78026 Versailles, France
J. P. Leydecker
Affiliation:
Station de Science du Sol, Institut National de la Recherche Agronomique, Route de Saint Cyr, 78026 Versailles, France
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Abstract

The resolution of the infrared spectra of structural OH in kaolin-group minerals increases with decreasing temperature. Poorly crystalline kaolinite gives typical infrared spectra, which suggest the existence of kaolinite-, dickite-, and nacrite-like configurations. The relative amount dickite- and nacrite-like configurations compared with kaolinite-like configurations increases with decreasing crystallinity. Low-temperature infrared spectroscopy is a more sensitive means of estimating the degree of order of poorly crystalline kaolinite than is X-ray powder diffraction.

Keywords

CrystallinityDickiteInfrared spectroscopyKaoliniteNacriteX-ray powder diffraction
Type
Research Article
Information
Clays and Clay Minerals , Volume 37 , Issue 5 , October 1989 , pp. 464 - 468
Copyright
Copyright © 1989, The Clay Minerals Society

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References

Brindley, G. W., Chih-Chun, K., Harrison, J. L., Lipsiscas, M. and Raythatha, R., 1986 Relation between structural disorder and other characteristics of kaolinites and dictates Clays & Clay Minerals 34 233 – 249.CrossRefGoogle Scholar
Chauvel, A. (1977) Recherches sur la transformation des sols ferrallitiques dans la zone tropicale à saisons constrastées: Trav. Doc. ORSTOM, Paris 62, 532 pp.Google Scholar
Cruz-Complido, M., Sow, C. and Fripiat, J. J. (1982) Spectre infrarouge des hydroxyles, cristallinité et énergie de cohésion des kaolins: Bull. Minéral. 105, 493 98.CrossRefGoogle Scholar
De Luca, S. and Slaughter, M., 1985 Existence of multiple kaolinite phases and their relationship to disorder in kaolin minerals Amer. Mineral 70 149 – 158.Google Scholar
Farmer, V. C. and Russell, J. D., 1964 The infrared spectra of layer silicates Spectrochim. Acta 20 1149 – 1173.CrossRefGoogle Scholar
Hinckley, D. N., Bradley, W. F. and Bailey, S. W., 1963 Variability in “crystallinity” values among the kaolin deposits of the coastal plain of Georgia and South Carolina Clays and Clay Minerals New York Pergamon Press 220 – 235.Google Scholar
Lombardi, G., Russell, J. D. and Keller, W. D., 1987 Compositional and structural variations in the size fractions of a sedimentary and a hydrothermal kaolin Clays & Clay Minerals 35 321 – 335.CrossRefGoogle Scholar
Lucas, Y., Chauvel, A. and Ambrosi, J. P. (1987) Processes of aluminium and iron accumulation in latosols developed on quartz-rich sediments from central Amaronia (Manaus, Brazil): Proc. 1st Int. Symp. on Geoch. Earth Surface, Granada, Spain, 1986, Rodriguez-Clemente, R. and Tardy, Y., eds., C.S.I.C., Madrid, 289–299.Google Scholar
Miller, J. G. and Oulton, T. D., 1970 Prototopy in kaolinite during percussive grinding Clays & Clay Minerals 18 313 – 323.CrossRefGoogle Scholar
Muller, J. P. and Bocquier, G., 1986 Dissolution of kaolinites and accumulation of iron oxides in lateritic-ferruginous nodules: Mineralogical and microstructural transformations Geoderma 37 113 – 136.CrossRefGoogle Scholar
Muller, J. P. and Bocquier, G. (1987) Textural and mineralogical relationships between ferruginous nodules and surrounding clayey matrices in a latente from Cameroon: in Proc. Int. Clay Conf., Denver, 1985, Schultz, L. G., Olphen, H. Van and Mumpton, F. A., eds., The Clay Minerals Society, Bloomington, Indiana, 186–199.Google Scholar
Prost, R., 1984 Etude par spectroscopic infrarouge à basse température des groupes OH de structure de la kaolinite, de la dickite et de la nacrite Agronomie 4 403 – 406.CrossRefGoogle Scholar
Prost, R., Damême, A., Huard, E. and Driard, J. (1987) Infrared study of structural OH in kaolinite, dickite, and nacrite at 300 to 5 K: in Proc. Int. Clay Conf., Denver, 1985, Schultz, L. G., Olphen, H. Van and Mumpton, F. A., eds., The Clay Minerals Society, Bloomington, Indiana, 17–23.Google Scholar