Hostname: page-component-77c89778f8-sh8wx Total loading time: 0 Render date: 2024-07-19T07:45:07.675Z Has data issue: false hasContentIssue false
  • English
  • Français

Colloid Chemical Control of Kaolinite Properties Related to Ceramic Processing

Published online by Cambridge University Press:  28 February 2024

Lyudmyla A. Pavlova  and
Michael J. Wilson
Lyudmyla A. Pavlova
Affiliation:
Institute of Colloid and Water Chemistry, National Academy of Sciences of Ukraine, L. Gavro St. 14, Apt. 104, Kiev-210, 254210, Ukraine
Michael J. Wilson
Affiliation:
Macaulay Land Use Research Institute, Craigiebuckler, Aberdeen, AB15 8QH, Scotland, United Kingdom
Get access Rights & Permissions [Opens in a new window]

Abstract

Experimental data on structure formation in highly concentrated aqueous dispersions of kaolinite were analyzed using rheological models. The physicochemical properties of the clay mineral surface were studied during heating at a range of temperatures, and correlation of acid-base properties with physicomechanical characteristics of the spatial structures formed during heating was obtained. It was shown that interparticle interactions and plastic yield mechanisms under load are dependent upon interfacial phenomena. A method for estimating optimal structural parameters was developed for semidry dispersions, enabling regulation of physicochemical and mechanical properties of ceramic mixtures during processing.

Keywords

Acid-Base Interfacial InteractionsCeramic ProcessingElectroconductivityInterparticle InteractionsKaoliniteOptimal StructuresSilicoorganic LiquidsSurface Modification
Type
Research Article
Information
Clays and Clay Minerals , Volume 47 , Issue 1 , February 1999 , pp. 36 - 43
Copyright
Copyright © 1999, The Clay Minerals Society

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bibik, E.E. Vvedenskaya, N.V. and Nechiporenko, A.G., 1986 Acid-basic properties of zirconium oxide surface Zhurnal Prik-ladnoj Khimii 59 2531–2537.Google Scholar
Bondarenko, S.V. Nazarenko, A.V. and Tarasevich, Y.I., 1986 Liquid-phase modification of support for gas chromatography Ukrainskiy Khimicheskij Zhurnal 52 3 254–258.Google Scholar
Derjaguiin, B.V. and Churaev, N.V., 1977 Disjoining pressure of thin layers of binary solutions J Colloid Interface Sci 62 3 374–385 10.1016/0021-9797(77)90088-1.CrossRefGoogle Scholar
Derjaguin, B.V. and Churaev, N.V., 1982 Disjoining pressure of thin films of liquids Moskva Nauka.Google Scholar
Derjaguin, B.V. Churaev, N.V. and Muller, V.M., 1987 Surface forces New York Consultants Bureau 10.1007/978-1-4757-6639-4.CrossRefGoogle Scholar
Fripiat, J.J. and Toussaint, F., 1963 Dehydroxylation of kaolinite. II. Conductometric measurements and infrared spectroscopy J Phys Chem 67 1 30–36 10.1021/j100795a008.CrossRefGoogle Scholar
Hamilton, W.C., 1968 Hydrogen bonding in solids New York W. A. Benjamin Inc.Google Scholar
Hang, P.T. and Brindley, G.W., 1970 Methylene blue adsorption by clay minerals. Determination of surface areas and cation exchange capacities (clay-organic studies XVIII) Clays Clay Miner 18 203–212 10.1346/CCMN.1970.0180404.CrossRefGoogle Scholar
Israelachvili, J.N., 1978 Measurement of forces between two mica surfaces in aqueous solutions J Chem Soc, Faraday Trans I 74 10 979–991.CrossRefGoogle Scholar
Israelachvili, J.N., 1985 Intermolecular and surface forces London Academic Pr.Google Scholar
Israelachvili, J.N. and Wennerstrom, M.H., 1992 Entropic forces between amphiphilic surfaces in liquids J. Phys Chem 96 520–531 10.1021/j100181a007.CrossRefGoogle Scholar
Kruglitskij, N.N., 1968 Physicochemical basis for manipulation of properties of clay mineral dispersions Kiev Naukova Dumka.Google Scholar
Kruglitskij, N.N. Minchenko, V.V. and Pavlova, L.A., 1989 The effect of external load and water content onto the coagulation structures formation in silicate dispersions Kolloidnyj Zhurnal 51 581–585.Google Scholar
Low, P.F., 1980 The swelling of clay: II. Montmorillonites Soil Sci Soc Am J 44 667–676 10.2136/sssaj1980.03615995004400040001x.CrossRefGoogle Scholar
Low, P.F., 1987 Structural component of the swelling pressure of clays Langmuir 3 18–25 10.1021/la00073a004.CrossRefGoogle Scholar
Oliphant, J.L. and Low, P.F., 1983 The isothermal compressibility of water mixed with Na-saturated montmorillonite J Colloid Interface Sci 95 45–50 10.1016/0021-9797(83)90070-X.CrossRefGoogle Scholar
Pashley, R.M., 1980 Hydration forces between mica surfaces in aqueous electrolyte solutions J Colloid Interface Sci 80 153–162 10.1016/0021-9797(81)90171-5.CrossRefGoogle Scholar
Paukshtis, E.A. and Yurchenko, E.N., 1983 The use of IR-spectros-copy for the investigation of acid-base properties for heterogeneous catalyst Uspekhi Khimii 52 3 426–454.CrossRefGoogle Scholar
Pavlova, L.A., 1988 ontrol of properties of silicate dispersions in abrasive tools and decorative glasses [Ph.D. dissertation] Kiev, Ukraine Naukova Dumka.Google Scholar
Pavlova, L.A., 1997 Effect of the kaolinite-water interfacial modifications on interparticle interactions Geologica Car-pathica-Series Clays 6 1 61–68.Google Scholar
Pavlova, L.A. and Taranukhina, L.D., 1995 Effect of chemical composition on interparticle interactions in aluminosilicate systems EUROCLAY’ 95 Abstr 245.Google Scholar
Pavlova, L.A. Taranukhina, L.D. and Goncharuk, V.V., 1991 Interparticle acid-base interactions in dispersions of layered silicates Doklady Akademii Nauk Ukr SSR 11 118–122.Google Scholar
Rebinder, P.A. Shchukin, E.D. and Margolis, L.Y., 1964 On mechanical strength of disperse systems Doklady Akademii Nauk SSSR 154 695–698.Google Scholar
Regel, B.I. Slutsker, E.V. and Tomashevskij, N.A., 1974 Fluctuation theory of solids Moskva Nauka.Google Scholar
Schramm, L. and Kwak, J.C.T. 1982. Influence of exchangeable cation composition on the size and shape of montmorillonite particles in dilute suspension. Clays Clay Miner 30:40–48.CrossRefGoogle Scholar
Skipper, N.T. Refson, K. and McConnell, J.D.C., 1991 Computer simulation of interlayer in 2:1 clays J Chem Phys 94 7434–7445 10.1063/1.460175.CrossRefGoogle Scholar
Skipper, N.T. Refson, K. and McConnell, J.D.C., 1991 Monte Carlo simulations of Mg- and Na-smectites Mineral Mag 34 645–667.Google Scholar
Skorokhod, V.V., 1981 Rheological theory of sintering powder-like solids Kiev Naukova Dumka.Google Scholar
Sun, Y. Lin, H. and Low, P.F., 1986 The non-specific interaction of water with the surfaces of clay minerals J Colloid Interface Sci 112 556–564 10.1016/0021-9797(86)90126-8.CrossRefGoogle Scholar
Taranukhina, L.D. Pavlova, L.A. and Goncharuk, V.V., 1996 Interfacial interactions in dispersions of natural and modified aluminosilicates Colloids Surf A: Physicochem Eng Aspects 108 33–38 10.1016/0927-7757(95)03269-X.CrossRefGoogle Scholar
Tarasevich, Y.I., 1988 The structure and surface chemistry of laminated silicates Kiev Naukova Dumka.Google Scholar
Tarasevich, Y.I. and Gribina, I.A., 1985 The state of structural hy-droxyl groups in minerals of kaolinite group according to IR-spectroscopy data Teoreticheskaja I Experimentalnaja Khimia 21 1 73–81.Google Scholar
Tarasevich, Y.I. Poliakova, I.G. and Poliakov, V.E., 1983 Heat of water adsorption on kaolinite with cations of alkali metals in exchangeable sites Kolloidnyj Zhurnal 45 2 368–373.Google Scholar
Uriev, N.B. Finashin, V.N. Kotliarskij, E.D. and Chernomaz, A.C., 1987 Structure formation of high filled disperse systems based on organic binders Kolloidnyj Zhurnal 49 72–80.Google Scholar
van Oss, C.J., 1993 Acid-base interfacial interactions in aqueous media. Colloids Surf A Physicochem Eng Asp 78 1–49 10.1016/0927-7757(93)80308-2.CrossRefGoogle Scholar
Viani, B.E. Low, P.F. and Roth, C.B., 1983 Direct measurement of the relation between interlayer force and interlayer distance in the swelling of montmorillonite J Colloid Interface Sci 96 229–244 10.1016/0021-9797(83)90025-5.CrossRefGoogle Scholar
Viani, B.E. Low, P.F. and Roth, C.B., 1985 Direct measurement of the relation between swelling pressure and interlayer distance in Li-vermiculite Clays Clay Miner 33 244–250 10.1346/CCMN.1985.0330311.CrossRefGoogle Scholar
Yaminskij, V.V. Pchelin, V.A. Amelina, E.A. and Shchukin, E.D., 1982 Coagulation contacts in disperse systems Moskva Khimia.Google Scholar
Zubkov, S.A. Kustov, L.M. Kazanskij, V.B. Fetter, G. Tichit, D. and Figueras, F., 1994 Study of the nature of acid site of montmorillonites pillared with aluminium and oligosesquioxane complex cations. 1. Bronsted acidity Clays Clay Miner 42 421–427 10.1346/CCMN.1994.0420407.CrossRefGoogle Scholar