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Baseline Studies of the Clay Minerals Society Source Clays: Colloid and Surface Phenomena

Published online by Cambridge University Press:  28 February 2024

Wenju Wu
Wenju Wu*
Affiliation:
Department of Chemistry, State University of New York at Buffalo, Buffalo, New York 14260, USA
*
E-mail of corresponding author: wenjuwu@buffalo.edu
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Extract

The interface between the surfaces of clay minerals and other materials (aqueous solution, organic moieties, biomolecules, etc.) is of great importance to many geological, technological and biological processes. The examination of the structure and composition of mineral surfaces is advancing rapidly. However, the crystal structure of a mineral is only part of the information needed to understand the activity of the surface; we still do not fully understand the chemical and physical interactions at the surface or interface. One very powerful methodology for the study of surfaces and interfacial interactions is the determination of the thermodynamic properties of the surface. It became possible in the late 1980s to determine quantitatively the apolar and polar surface-tension components and parameters of liquids and solids (van Oss et al., 1988; van Oss, 1994), and the experimental techniques necessary for obtaining surface free-energy components of minerals, and particularly of colloid-sized minerals, are also a recent development (Costanzo eta!., 1990; van Oss et al., 1990, 1992; Giese et al., 1991).

Type
Research Article
Information
Clays and Clay Minerals , Volume 49 , Issue 5 , October 2001 , pp. 446 - 452
Copyright
Copyright © 2001, The Clay Minerals Society

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References

Adamson, A.W., 1990 Physical Chemistry of Surfaces 5th New York Wiley-Interscience 203–414.Google Scholar
Chaudhury, M.K., 1984 Short range and long range forces in Colloidal and Macroscopic Systems Buffalo, New York State University of New York at Buffalo 189 pp.Google Scholar
Claesson, P.M., 1986 Forces between Surfaces immersed in Aqueous Solutions Stockholm, Sweden Royal Institute of Technology 110 pp.Google Scholar
Costanzo, P.M. Giese, R.F. and van Oss, C.J., 1990 Determination of the acid-base characteristics of clay mineral surfaces by contact angle measurements—implications for the adsorption of organic solutes from aqueous media Journal of Adhesion Science Technology 4 267–275 10.1163/156856190X00298.CrossRefGoogle Scholar
Debye, P., 1920 Van der Waals cohesion forces Physikalische Zeitschrift 21 178–187.Google Scholar
Debye, P., 1921 Molecular forces and their electrical interpretation Physikalische Zeitschrift 22 302–308.Google Scholar
Dupré, A., 1869 Theorie Mecanique de la Chaleur Pairs Gauthier-Villars 1–50.Google Scholar
Everett, D.H., 1988 Basic Principles of Colloid Science London Royal Society of Chemistry 10.1039/9781847550200-00026 250 pp.CrossRefGoogle Scholar
Fowkes, F.W., 1963 Additivity of intermolecular forces at interfaces. I. Determination of the contribution to surface and interfacial tensions of dispersion forces in various liquids Journal of Physical Chemistry 67 2538–2541 10.1021/j100806a008.CrossRefGoogle Scholar
Giese, R.F. Costanzo, P.M. and Van Oss, C.J., 1991 The surface free energies of talc and pyrophyllite Physics and Chemistry of Minerals 17 611–616 10.1007/BF00203840.CrossRefGoogle Scholar
Good, R.J. and Girifalco, L.A., 1960 A theory for estimation of surface and interfacial energies. III. Estimation of surface energies of solids from contact angle data Journal of Physical Chemistry 64 561–565 10.1021/j100834a012.CrossRefGoogle Scholar
Good, R.J. and van Oss, C.J., 1991 Surface enthalpy and entropy and the physico-chemical nature of hydrophobic and hydrophilic interactions Journal of Dispersion, Science and Technology 12 273–287 10.1080/01932699108913130.Google Scholar
Hiemenz, P.C., 1986 Principles of Colloid and Surface Chemistry 2nd New York Marcel Dekker, Inc. 611–786.Google Scholar
Keesom, W.M., 1915 The second virial coefficient for rigid spherical molecules whose mutual attraction is equivalent to that of a quadruplet placed at its center Proceedings Royal Academy Science, Amsterdam 18 636–646.Google Scholar
Keesom, W.M., 1920 Quadrupole moments of the oxygen and nitrogen and nitrogen molecules Proceedings Royal Academy Science, Amsterdam 23 939–942.Google Scholar
Keesom, W.M., 1921 Van der Waals attractive force Physikalische Zeitschrift 22 129–141.Google Scholar
Keesom, W.M., 1921 Van der Waals attractive force Physikalische Zeitschrift 22 643–644.Google Scholar
Klein, C. and Hurlbut, C.S., 1993 Manual of Mineralogy New York John Wiley & Sons 123–125.Google Scholar
Lifshitz, E.M., 1955 The theory of molecular attraction forces between solid bodies Zhurnal Eksperimentalnoi Teoreticheskoi Fiziki 29 94–110.Google Scholar
London, F., 1930 Theory and systematic of molecular forces Physikalische Zeitschrift 63 245–279.Google Scholar
Overbeek, J.T.h.G. and Kruyt, H.R., 1952 Electrokinetics Colloid Science Amsterdam, The Netherlands Elsevier 194–244.Google Scholar
Van Oss, C.J., 1994 Interfacial Forces in Aqueous Media New York Marcel Dekker 1–401.Google Scholar
Van Oss, C.J. and Giese, R.F., 1995 The hydrophilicity and hydrophobicity of clay minerals Clays and Clay Minerals 43 474–477 10.1346/CCMN.1995.0430411.CrossRefGoogle Scholar
Van Oss, C.J. and Good, R.J., 1988 On the mechanism of “hydrophobic” interactions Journal of Dispersion Science and Technology 9 355–362 10.1080/01932698808943994.CrossRefGoogle Scholar
Van Oss, C.J. Fike, R.M. Good, R.J. and Reinig, J.M., 1974 Cell microelectrophoresis simplified by the reduction and uniformization of the electroosmotic backflow Analytical Biochemistry 60 242–251 10.1016/0003-2697(74)90150-X.CrossRefGoogle ScholarPubMed
Van Oss, C.J. Chaudhury, M.K. and Good, R.J., 1988 Interfacial Lifshitz-van der Waals and polar interactions in macroscopic systems Chemical Reviews 88 927 10.1021/cr00088a006.CrossRefGoogle Scholar
Van Oss, C.J. Giese, R.F. and Costanzo, P.M., 1990 DLVO and NON-DLVO interactions in hectorite Clays and Clay Minerals 38 151–159 10.1346/CCMN.1990.0380206.CrossRefGoogle Scholar
Van Oss, C.J. Giese, R.F. Li, Z. Murphy, K. Norris, J. Chaudhury, M.K. and Good, R.J., 1992 Determination of contact angles and pore sizes of porous media by column and thin layer wicking Journal of Adhesion Science and Technology 6 413 10.1163/156856192X00755.CrossRefGoogle Scholar
Van Oss, C.J. Giese, R.F. and Wu, W., 1997 On the predominant electron-donicity of the polar solid surfaces Journal of Adhesion 63 71–88 10.1080/00218469708015214.CrossRefGoogle Scholar
Washburn, E.W., 1921 The dynamics of capillary flow Physical Review 17 273–283 10.1103/PhysRev.17.273.CrossRefGoogle Scholar
Wu, W. Giese, R.F. and Van Oss, C.J., 1994 Linkage between ζ-potential and electron donicity of charged polar surfaces. I. Implications for the mechanism of flocculation of particle suspensions with plurivalent counterions Colloids and Surface A 89 241–252 10.1016/0927-7757(94)80122-3.CrossRefGoogle Scholar