Hostname: page-component-848d4c4894-8bljj Total loading time: 0 Render date: 2024-07-03T03:59:26.604Z Has data issue: false hasContentIssue false

Solid-Gas Interface in Weathering Reactions

Published online by Cambridge University Press:  01 January 2024

Cooper H. Wayman*
Affiliation:
U.S. Geological Survey, Denver Federal Center, Denver, Colorado, USA

Abstract

Most weathering reactions have been interpreted in terms of the solid-liquid interface. In dry climates or at low humidity, weathering might be initiated or controlled by a solid-gas reaction. The stability of gibbsite and some hydrous borates involves the activity of water vapor; and the stability of azurite depends on a ratio of the partial pressures of both water vapor and carbon dioxide. Much additional work is required on the rates of equilibrium dehydration to contribute to our knowledge of the solid-gas interface in weathering.

Type
Symposium on Clay Mineral Transformation
Copyright
Copyright © The Clay Minerals Society 1962

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Published by permission of Director, U.S. Geological Survey, Washington 25, D.C.

References

Alexander, L. T., Hendricks, S. B., and Faust, G. T. (1941) Occurrence of gibbsite in some soil forming minerals: Soil Sci. Soc. Amer. Proc., v. 6, p. 52.CrossRefGoogle Scholar
Allen, V. T. (1948) Formation of bauxite from basaltic rocks of Oregon: Econ. Geol., v. 43, p. 619.CrossRefGoogle Scholar
Bishopp, D. W. (1955) Bauxite resources of British Guiana: British Guiana Geol. Survey Bull. No. 26, p. 1.Google Scholar
Bureau of Standards (1952) Selected values of chemical thermodynamic values: Circular 500, p. 319.Google Scholar
Chirvinskii, P. N. (1940) Gibbsite in platy crystals in bauxite: Mem. Soc. Busse Mineral, v. 69, p. 41.Google Scholar
Christ, C. L., and Garrels, R. H. (1959) Relations among sodium borate hydrates at the Kramer deposit, Boron, California: Amer. J. Sci., v. 257, pp. 516528.Google Scholar
De Ravol, R. (1953) Contributions to the study of bauxite of Plain of Pocas de Caldas: Inst. Tech. Pubi. Sao Paulo, Brazil, No. 17, p. 109.Google Scholar
DeWeisse, J. (1948) Bauxites of Central Europe: Mem. Soc. Sci. Nat., v. 58, p. 162.Google Scholar
DeWeisse, G. (1954) Some laterite types in Portugese Guiana: Congr. Geol. Interm., Compt. rend. Algiers, v. 12, p. 183.Google Scholar
Ekrem, G. (1954) Geology and genesis of bauxite deposits in Turkey: Congr. Geol. Intern., Compt. rend., v. 12, p. 163.Google Scholar
Eyles, V. A. (1952) The composition and origin of the Antrim laterites and bauxites: Gov't. Northern Ireland, Mem. Geol. Survey, No. 18, p. 41.Google Scholar
Funaki, K., and Uchimira, K. (1952) The properties of hydrated alumina and alumina. IV. Characteristics of bayerite and gibbsite: J. Chem. Soc. Japan, Ind. Chem. Sect., v. 55, pp. 5154.Google Scholar
Gedeon, T. G. (1956) Bayerite in Hungarian bauxite: Acta Geol. Acad. Sci. Hung., v. 4, p. 95.Google Scholar
Goldich, S., and Bergquist, H. (1947) Aluminous lateritic of Sierra de Bahamco Area Dominican Republic, B.W.I.: U.S. Geol. Survey Bull. 953C, p. 53.Google Scholar
Hardy, F., and Rodriques, G. (1939) Soil genesis from andesite in Grenada, B.W.I.: Soil Sci., v. 48, p. 361.CrossRefGoogle Scholar
Hill, V. G. (1955) The mineralogy and genesis of bauxite deposits of Jamaica, B.W.I.: Amer. Min., v. 40, p. 677.Google Scholar
Hose, H. R. (1950) The geology and mineral resources of Jamaica: Colonial Geol. and Mineral Resources, v. 1, p. 11.Google Scholar
Kiss, J. (1952) Mineralogy and bauxite of Nezsa: Acta Geol. Acad. Sci. Hung., v. 1, p. 113.Google Scholar
Klute, A. (1960) Water, gas and solute transport theories and their application in drainage research: Paper No. 60-723, Amer. Soc. Agric. Engrs., Winter Meeting, Dec. 4-7, 1960, Memphis, Tenn., p. 4.Google Scholar
Kuznetzov, S. N. (1950) Thermodynamic properties of gibbsite and boehmite: J. Appl. Chem. USSR, v. 23, pp. 12651268.Google Scholar
Miholic, S. (1956) Origin of bauxite on L.S.: Berg. u. huttermann Monatsh. Montau Hochschule Leoben, v. 101, p. 38.Google Scholar
Miralies, J. (1952) Bauxites of N.E. Spain: Congr. Geol. Intern., Compt. rend. Algiers, v. 12, p. 199.Google Scholar
Nemerz, E. (1954) Iron minerals in bauxite: Acta Geol. Acad. Sci. Hung., v. 2, p. 257.Google Scholar
Oda, S. (1955) Investigation of Indian bauxites: J. Chem. Soc. Japan, Pure Chem. Sect., v. 76, p. 209.Google Scholar
Pourbaix, M. (1956) Comportement electrochimique, de l'aluminum. Diagramme d'équilibré tension—pH du system Al-H2O, à 25°C: Centre Belge d'Etude de la Corrosion, Brussels, Tech. Rept. 25, p. 4.Google Scholar
Ragatt, H. (1945) Bauxite deposits of Victoria: Australian Min. Res. Survey Bull. No. 14, p. 26.Google Scholar
Sherman, J. D. (1957) Formation of gibbsite aggregates in latosols developed on volcanic ash: Science, v. 125, p. 1243.CrossRefGoogle ScholarPubMed
Spangenberg, K. S. (1944) The occurrence of bauxites between Siewierz and Tarnouricz, Upper Silesia: Neues Jahrb. Min., Geol. Monatsh, v. 152, p. 68.Google Scholar
Tullet, J. (1951) X-ray analysis of some bauxites of N.E. Spain: Estud, Geol. Inst. "Lucas Mallodas", v. 7, p. 113.Google Scholar
Vachtl, J. (1956) The Greek bauxites, their occurrence, age, and mineral composition: Vestník Ustrednika Ustanes Geol., v. 31, p. 105.Google Scholar
Van Bavel, C. H. M. (1951) A soil aeration theory based on diffusion: Soil Sci., v. 72, pp. 3346.CrossRefGoogle Scholar
Van Kersen, J. F. (1956) Bauxite deposits in Surinam and Demerara (B. G.): Leidsche Geol. Mededeel, v. 21, p. 247.Google Scholar
Wayman, C. H. (1959) Ph.D. dissertation, Michigan State University, Lansing, Michigan, p. 89.Google Scholar
Wayman, C. H. (1961) Hydrate equilibrium in soil profiles: Soil Sci., v. 92, pp. 322330.CrossRefGoogle Scholar
Wayman, C. H. (1963) The Malachite-azurite equilibrium in soil profiles: Soil Sci., v. 94 (in press).Google Scholar
Wysor, D. C. (1916) Aluminous hydroxides in Arkansas bauxite deposits: Econ. Geol., v. 11, p. 42.CrossRefGoogle Scholar
Wysor, D. C. (1923) Diaspore clay of Arkansas-Missouri: J. Amer. Geram. Soc., v. 6, p. 501.Google Scholar