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Perspectives in Applied Organo-Clay Chemistry

Published online by Cambridge University Press:  01 January 2024

Paul G. Nahin
Paul G. Nahin*
Affiliation:
Union Oil Company of California, Research Center, Brea, California
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Abstract

Some aspects of organo-clay chemistry that have interested a growing number of scientists are reviewed and discussed. Particular attention is directed to published evidence for the “reality” of clay compounds, the possible effects of high energy radiation on clay properties, industrial applications of modified clays and the increasing number of patents being granted in this field of applied chemistry. A number of areas of inadequate information where further basic research could lead to useful applications is pointed out.

Type
Symposium on Industrial Applications
Information
Clays and Clay Minerals (National Conference on Clays and Clay Minerals) , Volume 10 , February 1961 , pp. 257 - 271
Copyright
Copyright © Clay Minerals Society 1961

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Footnotes

1

Published by permission of the Union Oil Company of California.

References

Agnello, L A, Morris, H H, Gunn, F A. Kaolin. Ind. Eng. Chem. 1960 52 370–376 10.1021/ie50605a019CrossRefGoogle Scholar
Allen, A O, Cafirey, J M. Irradiation method of converting organic compounds 1960Google Scholar
Barrer, R M, Kelsey, K E. Thermodynamics of interlamellar complexes. Trans. Faraday Soc. 1961 57 452–462 10.1039/TF9615700452CrossRefGoogle Scholar
Barrer, R M, Reay, J S S. The sorption of benzene and water by a “phenyl” montmorillonite. Clay Minerals Bull. 1958 3 214–220 10.1180/claymin.1958.003.19.03CrossRefGoogle Scholar
Bisque, R E. Clay polymerization in carbonate rooks: A silicification reaction defined. Clays and Clay Minerals 1962 9 365–373 10.1346/CCMN.1960.0090123CrossRefGoogle Scholar
Blackmon, P D. Neutralization curves and the formulation of monovalent cation exchange properties of clay minerals. Amer. J. Sci. 1958 256 733–743 10.2475/ajs.256.10.733CrossRefGoogle Scholar
Bradley, W F, Rowland, R A, Weiss, E J, Weaver, C E. Temperature stabilities of montmorillonite- and vermiculite-glycol complexes. Clays and Clay Minerals 1958 348–355CrossRefGoogle Scholar
Brindley, G W, Hoffmann, R W. Orientation and packing of aliphatic chain molecules on montmorillonite. Clays and Clay Minerals 1962 9 546–556 10.1346/CCMN.1960.0090140CrossRefGoogle Scholar
British Thomson-Houston Company, Limited London. Improvements in and relating to bentonite products 1941Google Scholar
Brown, W E. Treatment of clays 1956Google Scholar
Brown, W E, Giacobine, C R. Treatment of clays 1956Google Scholar
Caffrey, J M, Allen, A O. Radiolysis of pentane adsorbed on mineral solids. J. Phys. Chem. 1958 62 33–37 10.1021/j150559a009CrossRefGoogle Scholar
Caldwell, J R. Acrylonitrile polymer compositions containing modified bentonite and fibers formed therefrom 1960Google Scholar
Cochran, W. “Effective” ionic charge in crystals. Nature 1961 191 60–61 10.1038/191060c0CrossRefGoogle Scholar
Cohn, M I. Rubber composition reinforced with a clay which contains olefinically unsaturated cations 1954Google Scholar
Cordier, D E. Production of moldable compositions comprising an unsaturated alkyd and kaolin coated with a heterocyclic amine—formaldehyde resin 1953Google Scholar
Cordier, D E. Polymerizable diallyl phthalate compositions containing as a filler, kaolin coated with a thermosetting amine formaldehyde resin 1957Google Scholar
Cowan, C T, Hartwell, J M. An organo-clay complex for the separation of isomeric dichlorobenzenes using gas chromatography. Nature 1961 190 712 10.1038/190712a0CrossRefGoogle Scholar
Cowan, C T, White, D. The mechanism of exchange reactions occurring between sodium montmorillonite and various n-primary aliphatic amine salts. Trans. Faraday Soc. 1958 54 691–697 10.1039/tf9585400691CrossRefGoogle Scholar
de Mello, V F B, Hauser, E A, Lambe, T W. Stabilization of soils 1953Google Scholar
Deuel, H. Organic derivatives of clay minerals. Agrochemien 1957 1 248–267Google Scholar
Dodd, C G, Ray, S. Semiquinone cation adsorption on montmorillonite as a function of surface acidity. Clays and Clay Minerals 1960 8th New York: Pergamon Press 237–251 10.1016/B978-0-08-009351-2.50026-XCrossRefGoogle Scholar
Emerson, W W. Complexes of calcium-montmorillonite with polymers. Nature 1960 186 573–574 10.1038/186573a0CrossRefGoogle Scholar
Freeman, P K, Peterson, W H. Hydrophobic oleophilic organo-clay thickened lubricating oil 1961Google Scholar
Garrels, R M, Christ, C L. Application of cation-exchange reactions to the beidellite of the Putnam silt loam soil. Amer. J. Sci. 1956 254 372–379 10.2475/ajs.254.6.372CrossRefGoogle Scholar
Georgia Kaolin Company. Teaching clay new tricks. Chemical Week 1961 88 23 79Google Scholar
Gieseking, J E. Exchange adsorption by clays of large organic cations. Nat. Acad. Sci.-Nat. Res. Council 1955 75–81Google Scholar
Glaeser, R. Organo-clay complexes and the role of exchangeable cations. I. Exchange capacity and exchangeable cations. Mem. Services Chim. Etat. (Paris) 1954 39 1 19–58Google Scholar
Gluesenkamp, E W. Organic materials 1957Google Scholar
Greene-Kelly, R. The sorption of saturated organic compounds by montmorillonite. Trans. Faraday Soc. 1956 52 1281–1286 10.1039/tf9565201281CrossRefGoogle Scholar
Greenland, D J, Russell, E W. Organo-clay derivatives and the origin of the negative charge on clay partieles. Trans. Faraday Soc 1955 51 1300–1307 10.1039/tf9555101300CrossRefGoogle Scholar
Grim, R E. Clay Mineralogy 1953 New York: McGraw-Hill 10.1097/00010694-195310000-00009CrossRefGoogle Scholar
Grim, R E. Some applications of clay mineralogy. Amer. Min. 1960 45 259–269Google Scholar
Hauser, E A. Silicic Science 1955Google Scholar
Hauser, E A, Dannenberg, E M. Molding composition, molded product, and method of making 1946Google Scholar
Hauser, E A, Kollman, R C. Clay complexes with conjugated unsaturated aliphatic compounds of four to five carbon atoms 1960Google Scholar
Hedrick, R M, Mowry, D T. The improvement of soil structure by synthetic polyelectrolytes. Ghem. and Ind. 1952 652–656Google Scholar
Hendricks, S B. Base exchange of crystalline silicates. Ind. Eng. Ghem. 1945 37 625–630 10.1021/ie50427a010CrossRefGoogle Scholar
Hoffmann, R W, Brindley, G W. Infrared extinction coefficients of ketones adsorbed on calcium montmorillonite in relation to surface coverage. Clay—organic studies. Part IV. J. Phys. Ghem. 1961 65 443–448Google Scholar
Iler, R K. The Colloid Chemistry of Silica and Silicates 1955 Ithaca, New York: Cornell University Press 10.1097/00010694-195507000-00014CrossRefGoogle Scholar
Iler, R K. Composition and process 1955Google Scholar
Jordan, J W. Organophilic bentonites. J. Phys. & Colloid Chem. 1949 53 294–306 10.1021/j150467a009CrossRefGoogle Scholar
Jordan, J W. Lubricants 1950Google Scholar
Jordan, J W. Modified clay complexes and method of preparation 1960Google Scholar
Lambe, T W, Michaels, A S. Altering soil properties with chemicals. Ghem. and Eng. News 1954 32 488–492 10.1021/cen-v032n006.p488CrossRefGoogle Scholar
Levine, H H. High temperature structural adhesives for the future. Ind. Eng. Chem. 1962 54 22–25 10.1021/ie50627a004CrossRefGoogle Scholar
MacEwan, D M C. Complexes of clays with organic compounds. Trans. Faraday Soc. 1948 44 349–367 10.1039/tf9484400349CrossRefGoogle Scholar
MacEwan, D M C. Interlamellar reactions of clays and other substances. Clays and Clay Minerals 1962 9 341–443Google Scholar
McAtee, J L Jr. Inorganic-organic cation exchange on montmorillonite. Amer. Min. 1959 44 1230–1236Google Scholar
Méring, J, Mathieu-Sicaud, A, Perrin-Bonnet, I. Fixation des particules d’or colloidal sur la kaolinite. Compt. Bend. Congr. Geol. Int. Alger 1953 103–107Google Scholar
Metz, D J. Graft copolymers—a new technology?. Nucleonics 1958 16 73–77Google Scholar
Michaels, A S, Kingery, W D. Rheological properties of aqueous clay systems. Ceramic Fabrication Processes 1958 New York: Technology Press of Massachusetts Institute of Technology and John Wiley 23–31Google Scholar
Mooser, E, Pearson, W B. The ionic character of chemical bonds. Nature 1961 190 406–408 10.1038/190406a0CrossRefGoogle Scholar
Nahin, P G. Oil-base drilling fluids 1953Google Scholar
National Cash Register Anonymous. Ind. Eng. Chem. 1957 49 8 23ACrossRefGoogle Scholar
Pauling, L C. The structure of micas and related minerals. Proc. Nat. Acad. Sci. U.S. 1930 16 123–129 10.1073/pnas.16.2.123CrossRefGoogle ScholarPubMed
Pauling, L C. Tailor-made compounds predicted by Pauling. Chem. and Eng. News 1949 27 913 10.1021/cen-v027n039.p2775Google Scholar
Pinck, L A. Adsorption of proteins, enzymes and antibiotics by montmorillonite. Clays and Clay Minerals 1962 9 520–529 10.1346/CCMN.1960.0090138CrossRefGoogle Scholar
Pommer, A M, Carroll, D. Interpretation of Potentiometric titration of H-montmorillonite. Nature 1960 185 595–596 10.1038/185595a0CrossRefGoogle Scholar
Rehner, J, Wiese, H K, Gessler, A M. Cyclodiene chlorosilane modified mineral pigment, polymer composition containing same, and method of making 1960Google Scholar
Rowland, R A, Weiss, E J. Bentonite-methylamine complexes 1963 460Google Scholar
Ruehrwein, R A. Modified clays 1957Google Scholar
Ruehrwein, R A. Chemical product 1957Google Scholar
Slabaugh, W H, Kupka, F. Organic cation exchange properties of calcium montmorillonite. J. Phys. Chem. 1958 62 599–601 10.1021/j150563a019CrossRefGoogle Scholar
Talibudeen, O. Complex formation between montmorillonoid clays and aminoacids and proteins. Trans. Faraday Soc. 1955 51 582–590 10.1039/tf9555100582CrossRefGoogle Scholar
Te Grotenhuis, T A. Pigments and particles with unsaturated surface and method of making same 1957Google Scholar
Te Grotenhuis, T A. High polymers with chemically bonded reinforcing and method of making same 1958Google Scholar
Thiessen, P A. Wechselseitige Adsorption von Kolloiden. Z. Elektrochem. 1942 48 675–681Google Scholar
Uskov, I A. Filled polymers. I. The filling of polymethylmethacrylate) with aminated bentonite added directly to the monomer. Vysokomolekulyarnye Soedineniya 1960 2 200–204Google Scholar
Van Volkenburgh, R. Polyvinyl chloride resin-urea-clay composition and method of making same 1959Google Scholar
van der Watt, H v H, Bodman, G B. Viscosimetric constants of suspensions of clay-polymer complexes. Clays and Clay Minerals 1962 9 568–584 10.1346/CCMN.1960.0090142CrossRefGoogle Scholar
Walker, G F. Reactions of expanding-lattice clay minerals with glycerol and ethylene glycol. Clay Minerals Bulletin (London) 1958 3 302–313 10.1180/claymin.1958.003.20.05CrossRefGoogle Scholar
Wilcox, J R. Modified kaolin clay 1961Google Scholar
Wöhler, F. (From a letter of Wöhler to J. J. Berzelius as quoted by R. F. Marschner (1955). Chem. and Eng. News 1848 33 494Google Scholar
Zukas, F J. Hardenable, fluid compositions containing resinous polymeric epoxides and a bentonite—amine reaction product 1956Google Scholar