Hostname: page-component-848d4c4894-sjtt6 Total loading time: 0 Render date: 2024-06-28T13:07:20.922Z Has data issue: false hasContentIssue false

Analysis of Consistencies of Kaolin-Water Systems Below the Plastic Range

Published online by Cambridge University Press:  01 January 2024

Robert B. Langston
Affiliation:
Ceramics Laboratories, Division of Mineral Technology, University of California, Berkeley, USA Institute of Engineering Research, University of California, Berkeley, California, USA
Joseph A. Pask
Affiliation:
Ceramics Laboratories, Division of Mineral Technology, University of California, Berkeley, USA Division of Mineral Technology, College of Engineering, University of California, Berkeley, California, USA

Abstract

Consistency curves and characteristics of Newtonian, pseudoplastic, Bingham body, thixo-tropic and dilatant types of flow are reviewed. The theoretical effects of particle shape on effective hydrodynamic volume and shear resistance for ideal suspensions are considered.

The rheological properties of hydrogen and sodium mono base-exchanged kaolinite clays were determined, using a rotational viscometer, on slips containing up to 50 g solids per 100 g slurry. Changes in rheological properties were also evaluated as a hydrogen slip containing 20 g solids per 100 g slurry was converted into the sodium form.

The discussion includes the effect of differences in charges and charge distribution on the sodium and hydrogen particles and the resulting effects on particle orientation and flocculation. Correction factors for dissociation and particle interference have allowed the use of Einstein’s equation for the viscosity of a suspension up to concentrations of about 40 percent solids for the hydrogen kaolinite system, and about 50 percent solids for the sodium kaolinite system.

Type
Article
Copyright
Copyright © Clay Minerals Society 1956

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

This study was sponsored as a Grant-in-Aid by the Institute of Geophysics, University of California, Los Angeles, California.

References

Einstein, A., 1906, Eine neue Bestimmung der Moleküldimensionen: Ann. Physik, v. 19, p. 289306.CrossRefGoogle Scholar
Einstein, A., 1911, Berichtigung zu meiner Arbeit; “Eine neue Bestimmung der Moleküldimensionen”: Ann. Physik, v. 34, p. 591592.Google Scholar
Green, H., 1949, Industrial rheology and rheological structures: John Wiley & Sons, Inc., New York, N. Y., 95 p.Google Scholar
Jirgensons, B., and Straumanis, M. E., 1954, A short textbook of colloid chemistry: John Wiley & Sons, Inc., New York, 420 p.Google Scholar
Johnson, A. L., and Norton, F. H., 1941, Fundamental study of clay. II. Mechanism of deflocculation in the clay-water system: J. Amer. Ceram. Soc., v. 24, p. 189203.Google Scholar
Moore, F., and Davies, L. J., 1956, The consistency of ceramic slips: Trans. Br. Ceram. Soc., v. 5, p. 313.Google Scholar
Peterlin, A., 1939, Determination of the size and axial ratio of ellipsoid-forming rigid particles by the innerfriction of diluted suspensions: Kolloid-z., v. 86, p. 230241.CrossRefGoogle Scholar
Peterlin, A., and Stewart, A. H., 1939, Determination of the size and shape, as well as the electrical, optical and magnetic anisotropy of submicroscopic particles with the aid of artificial double refraction and inner viscosity: Z. Physik, v. 112, p. 129147.CrossRefGoogle Scholar
Schofield, R. K., and Sampson, H. R., 1953, The deflocculation of kaolinite suspensions and the accompanying change-over from positive to negative chloride adsorption: Clay Minerals Bull., v. 2, p. 4551.CrossRefGoogle Scholar
Scott Blair, G. W., 1949, A survey of general and applied rheology: Second Edition, Pitman and Sons, London, 191 p.Google Scholar
Simha, R., 1940, The influence of Brownian movement on the viscosity of solutions; J. Phys. Chem., v. 44, p. 2534.CrossRefGoogle Scholar