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Study of the Maillard reaction products formed by glycine and D- glucose on different mineral substrates

Published online by Cambridge University Press:  09 July 2018

M. Bosetto ,
P. Arfaioli  and
O. L. Pantani
M. Bosetto*
Affiliation:
Dipartimento di Scienza del Suoloe Nutrizione della Pianta, Università di Firenze, Piazzale Cascine 28, 50144 Firenze
P. Arfaioli
Affiliation:
Dipartimento di Scienza del Suoloe Nutrizione della Pianta, Università di Firenze, Piazzale Cascine 28, 50144 Firenze
O. L. Pantani
Affiliation:
Istituto per la Genesie l'Ecologia del Suolo (IGES) CNR, Firenze, Piazzale Cascine 28, 50144 Firenze, Italy
*
*E-mail: otto@iges.fi.cnr.it
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Abstract

This work deals with the formation of humic-like compounds, products of the Maillard reaction between glycine and D-glucose, on clay (K+, Ca2+ and Al3+-saturated montmorillonite and kaolinite) and quartz systems in the presence of the same cations. Natural quartz was used as the control while the effect of cation type, mineral substrate and CEC was evaluated. All the systems form humic-like substances that are probably responsible for the decrease in the pH (H2O) after 30 d. The type of cation does not influence the overall production of humic substances, while the amount of cations controls the formation of humic-like material especially in the presence of clays. A mineral surface is necessary to synthesize molecules with this high degree of complexity.

Fulvic-like compounds are produced in great amounts on natural quartz and their formation is hampered by the presence of ‘free’ cations, regardless of their amount. Humic substances do not penetrate the interlayer of montmorillonite.

Keywords

Maillard reactionmontmorillonitekaolinitequartzhumic substancesD-glucoseglycine
Type
Research Article
Information
Clay Minerals , Volume 37 , Issue 1 , March 2002 , pp. 195 - 204
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2002

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