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Retrograde diagenesis, a widespread process on a regional scale

Published online by Cambridge University Press:  09 July 2018

F. Nieto ,
M. Pilar Mata ,
B. Bauluz ,
G. Giorgetti ,
P. Árkai  and
D. R. Peacor
F. Nieto*
Affiliation:
Instituto Andaluz de Ciencias de la Tierra and Departamento de Mineralogía y Petrología, University of Granada-CSIC, 18002 Granada, Spain
M. Pilar Mata
Affiliation:
Departamento de Geología, University of Cádiz, Campus Río San Pedro, 11510 Puerto Real, Cádiz, Spain
B. Bauluz
Affiliation:
Departamento de Ciencias de la Tierra, University of Zaragoza, 50009 Zaragoza, Spain
G. Giorgetti
Affiliation:
Dipartimento di Science della Terra, University of Siena, Siena, Italy
P. Árkai
Affiliation:
Laboratory for Geochemical Research, Hungarian Academy of Sciences, H-1112 Budapest, Budaörsi út 45, Hungary
D. R. Peacor
Affiliation:
Department of Geological Sciences, The University of Michigan. Ann Arbor, MI-48109, US
*
*E-mail: nieto@goliat.ugr.es
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Abstract

Pelitic and basic rocks occurring within prograde sequences in Portugal, Spain and Hungary have been studied by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The minerals formed in typical prograde reactions define the general sequences, but smectite, chlorite-smectite (corrensite) and/or berthierine were found to have replaced chlorite, whereas kaolinite and mixed-layer illite-smectite replaced illite-muscovite. Alteration occurred under conditions normally associated with diagenesis, subsequent to regional metamorphism, and we therefore refer to such processes with the term “retrograde diagenesis”. In the cases studied and in other cited examples, reactions occurred on a regional basis via pervasive fluids under open-system conditions inferred to be related to tectonic stress. The observed alterations could generally not be inferred from XRD data, although the presence of pure smectite in sediments other than bentonite is suggestive of retrograde relations, especially where other minerals are consistent with a higher grade of diagenesis. Retrograde diagenesis is readily observed through imaging of textures by TEM, however. Textural features show that retrograde reactions are more common than generally assumed, and that care should be used in interpreting geological events where appropriate textural relations are not seen.

Keywords

retrogradediagenesisXRDTEMSEMillite-smectitechlorite-smectiteregional metamorphism
Type
Research Article
Information
Clay Minerals , Volume 40 , Issue 1 , March 2005 , pp. 93 - 104
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2005

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