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Removal of Mg from spring water using natural clinoptilolite

Published online by Cambridge University Press:  09 July 2018

S. Tomić ,
N. Rajić ,
J. Hrenović  and
D. Povrenović
S. Tomić
Affiliation:
Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000, Belgrade, Serbia
N. Rajić*
Affiliation:
Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000, Belgrade, Serbia
J. Hrenović
Affiliation:
Faculty of Science, University of Zagreb, Roosveltov trg 6, 10000 Zagreb, Croatia
D. Povrenović
Affiliation:
Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000, Belgrade, Serbia
*
*E-mail: nena@tmf.bg.ac.rs
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Abstract

Natural zeolitic tuff from Brus (Serbia) consisting mostly of clinoptilolite (about 90%) has been investigated for the reduction of the Mg concentration in spring water. The sorption capacity of the zeolite is relatively low (about 2.5 mg Mg g-1 for the initial concentration of 100 mg Mg dm-3). The zeolitic tuff removes Mg from water solutions by ion exchange, which has been demonstrated by energy dispersive X-ray analysis (EDS). The extent of ion exchange was influenced by the pH and the initial Mg concentration. Kinetic studies revealed that Lagergen's pseudo-second order model was followed. Intra-particle diffusion of Mg2+ influenced the ion exchange, but it is not the rate-limiting step. Rather than having to dispose of the Mg-loaded (waste) zeolite, a possible application was tested. Addition to a wastewater with a low concentration of Mg showed that it could successfully make up for the lack of Mg micronutrient and, accordingly, enabled the growth of phosphate-accumulating bacteria A. Junii, increasing the amount of phosphate removed from the wastewater.

Keywords

natural zeoliteIgroš Vidojević depositBrusSerbiaclinoptiloliteMg removalbacteriawater softening
Type
Research Article
Information
Clay Minerals , Volume 47 , Issue 1 , March 2012 , pp. 81 - 92
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2012

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References

Arrigo, I., Catalfamo, P., Cavallari, L. & Pasquale, S.D. (2007) Use of zeolitized pumice waste as a water softening agent. Journal of Hazardous Materials, 147, 513–517.CrossRefGoogle ScholarPubMed
Caputo, D. & Pepe, F. (2007) Experiments and data processing of ion exchange equilibria involving Italian natural zeolites: a review. Microporous and Mesoporous Materials, 105, 222–231.CrossRefGoogle Scholar
Cerjan Stefanović, S., Zabukovec Logar, N., Margeta, K., Novak Tusar, N., Arcon, I., Maver, K., Kovač, J. & Kaučić, V. (2007) Structural investigation of Zn2+ sorption on clinoptilolite tuff from the Vranjska Banja deposit in Serbia. Microporous and Mesoporous Materials, 105, 251–29.CrossRefGoogle Scholar
Cotton, F.A., Wilkinson, G. & Gaus, P.L. (1995) Basic Inorganic Chemistry, p. 580. John Wiley and Sons, New York.Google Scholar
Crystallographica Search-Match, version 2,1,1,0, (2003) Oxford Cryosystems, UK.Google Scholar
Douglas, B.E., McDaniel, D.H. & Alexander, J.J. (1994) Concepts and Models of Inorganic Chemistry, p. 731. John Wiley and Sons, New York.Google Scholar
Durham, D.R., Marshall, L.C., Miller, J.G. & Chmurny, A.B. (1994) Characterization of inorganic biocarriers that moderate system upsets during fixed-film biotreatment process. Applied and Environmental Microbiology, 60, 3329–3335.CrossRefGoogle Scholar
FAO/WHO expert consultation (1998) Vitamin and mineral requirements in human nutrition: report of a joint FAO/WHO expert consultation, Bangkok, Thailand, 1998, 21–30 September.Google Scholar
Filippidis, A. (2010) Environmental, industrial and agricultural applications of Hellenic Natural Zeolite. Hellenic Journal of Geosciences, 45, 91–100.Google Scholar
Filippidis, A., Moustaka-Gouni, M., Kantiranis, N., Katsiapi, M., Papastergios, G., Karamitsou, V., Vogiatzis, D. & Filippidis, S. (2010) Chroococcus (cyanobacteria) removal by Hellenic natural zeolite. 8th International Conference on the Occurence, Properties, and Utilization of Natural Zeolites, Sofia, Bulgaria, 91–92.Google Scholar
Ho, Y.S. (2004) Citation review of Lagergren kinetic rate equation on adsorption reactions. Scientometrics, 59, 171–177.Google Scholar
Ho, Y.S. (2006) Review of second-order models for adsorption systems. Journal of Hazardous Materials, 136, 681–689.CrossRefGoogle ScholarPubMed
Ho, Y.S. & McKay, G. (1998) Sorption of dye from aqueous solution by peat. Chemical Engineering Journal, 70, 115–124.CrossRefGoogle Scholar
Hrenović, J., Tibljas, D., Orhan, Y. & Buyukgungor, H. (2005) Immobilization of Acinetobacter calcoaceticus on natural carriers. Water SA, 31, 261–266.Google Scholar
Hrenović, J., Ivanković, T. & Tibljas, D. (2009) The effect of mineral carrier composition on phosphate-accumulating bacteria immobilization. Journal of Hazardous Materials, 166, 1377–1382.CrossRefGoogle ScholarPubMed
Hrenović, J., Ivanković, T. & Rožić, M. (2010) Requirement of Acinetobacter junii for magnesium, calcium and potassium ions. Journal of Bioscience and Bioengineering, 110, 180–186.CrossRefGoogle ScholarPubMed
Huheey, J.E., Keiter, E.A. & Keiter, R.L. (1993) Inorganic Chemistry: Principles of Structure & Reactivity, pp. 114–117. Harper Collins College Publisher, New York.Google Scholar
Marakov, V.V. (2007) Electromagnetic method for softening natural water. Russian Journal of Applied Chemistry, 80, 1604–1605.CrossRefGoogle Scholar
Mao, R.L.V., Vu, N.T., Xiao, S. & Ramsaran, A. (1994) Modified zeolites for the removal of calcium and magnesium from Hard Water. Journal of Materials Chemistry, 4, 1143–1147.Google Scholar
Official Gazette SRJ (1998) Regulation on hygiene of drinking water, no.42/98.Google Scholar
Official Gazette SRJ (1999) Regulation on hygiene of drinking water, no.44/99.Google Scholar
Poots, V.J.P., McKay, G. & Healy, J.J. (1976) The removal acid dye from effluent using natural Adsorbents-I peat. Water Research, 10, 1061–1066.Google Scholar
Rajic, N., Stojakovic, Dj., Jevtic, S., Zabukovec Logar, N., Kovac, J. & Kaucic, V. (2009) Removal of aqueous manganese using the natural zeolitic tuff from the Vranjska Banja deposit in Serbia. Journal of Hazardous Materials, 172, 1450–1457.CrossRefGoogle ScholarPubMed
Rajic, N., Stojakovic, Dj., Jovanovic, M., Zabukovec Logar, N., Mazaj, M. & Kaucic, V. (2010) Removal of nickel(II) ions from aqueous solutions using the natural clinoptilolite and preparation of nano-NiO on the exhausted clinoptilolite. Applied Surface Science, 257, 1524–1532.CrossRefGoogle Scholar
Stojakovic, Dj., Milenkovic, J., Daneu, N. & Rajic, N. (2011a) Study of the removal of copper ions from aqueous solution using clinoptilolite from Serbia. Clays and Clay Minerals, 59, 277–285.CrossRefGoogle Scholar
Stojakovic, Dj., Hrenovic, J., Mazaj, M. & Rajic, N. (2011b) On the zinc sorption by the Serbian natural clinoptilolite and the disinfecting ability and phosphate affinity of the exhausted sorbent. Journal of Hazardous Materials, 185, 408–415.CrossRefGoogle ScholarPubMed
TOPAS V2.1 (2000) Users Manual, Bruker AXS, Karlsruhe, Germany.Google Scholar
Vochten, R.F.C., Van Haverbeke L., & Goovaerts, F. (1990) External surface adsorption of uranylhydroxo complexes on zeolite particles in relation to the double-layer potential. Journal of the Chemical Society, Faraday Transactions, 86, 4095–4099.CrossRefGoogle Scholar
Wang, S. & Peng, Y. (2010) Natural zeolites as effective adsorbents in water and wastewater treatment. Chemical Engineering Journal, 156, 11–24.CrossRefGoogle Scholar
Jr.Weber, W.J. & Morris, J.C. (1963) Kinetics of adsorption on carbon from solution. Journal. Sanitary Engineering Division. Proceedings. American Society of Civil Engineers, 89, 31–60.Google Scholar