Hostname: page-component-848d4c4894-jbqgn Total loading time: 0 Render date: 2024-06-27T21:12:35.992Z Has data issue: false hasContentIssue false
  • English
  • Français

Mineralogical and geochemical characteristics (major, minor, trace elements and REE) of detrital and authigenic clay minerals in a Cenozoic sequence from Ross Sea, Antarctica

Published online by Cambridge University Press:  09 July 2018

M. Setti ,
L. Marinoni  and
A. López-Galindo
M. Setti
Affiliation:
Dipartimento di Scienze della Terra, University of Pavia, Via Ferrata 1, 27100 Pavia, Italy
L. Marinoni
Affiliation:
Dipartimento di Scienze della Terra, University of Pavia, Via Ferrata 1, 27100 Pavia, Italy
A. López-Galindo
Affiliation:
Instituto Andaluz de Ciencias de la Tierra, CSIC, University of Granada, 18071 Granada, Spain
Get access Rights & Permissions [Opens in a new window]

Abstract

The mineralogy and geochemistry of the clay fraction of Victoria Land Basin (Ross Sea, Antarctica) sediments was investigated, to determine the origin of clay minerals and the features of authigenic smectite. The investigated core (CRP-3) is ~800 m long, mostly of Oligocene age. The clay fraction of the upper sequence consists of mica, chlorite and detrital smectite, while that of the central and lower part is largely made up of authigenic smectite. Authigenic smectites are ditrioctahedral, with a composition close to saponite, while detrital smectites such as Al-Fe beidellites are dioctahedral. Authigenic smectites have no illite mixed layers, show a higher degree of crystallization, higher MgO, Fe2O3, V, Cr, Co, Ni and Sc contents and lower SiO2, Al2O3, K2O, TiO2, Ba, Rb and Zr contents with respect to detrital clay minerals, and a clear depletion of LREE with respect to HREE. Authigenic smectite formed from the alteration of volcanic materials and clay minerals.

Keywords

AntarcticaRoss Seaclay mineralssmectiteREEgeochemistry
Type
Research Article
Information
Clay Minerals , Volume 39 , Issue 4 , December 2004 , pp. 405 - 421
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Aoki, S. & Kohyama, N. (1991) The vertical change in clay mineral composition and chemical characteristics of smectite in sediment cores from the southern part of the Central Pacific Basin. Marine Geology, 98, 41-49.Google Scholar
Barrett PJ. (1996) Antarctic palaeoenvironment through Cenozoic times; a review. Terra Antartica, 3, 103–119.Google Scholar
Biscaye, P.E. (1965) Mineralogy and sedimentation of recent deep-sea clay in the Atlantic Ocean and adjacent seas and oceans. Geological Society of America Bulletin, 76, 803–832.CrossRefGoogle Scholar
Buatier, M.D., Monnin, C., Friih-Green, G. & Karpoff, A.M. (2001) Fluid sediment interactions related to hydrothermal circulation in the Eastern Flank of the Juan de Fuca Ridge. Chemical Geology, 175, 343–360.Google Scholar
Buatier, M.D., Karpoff, A.M. & Charpentier, D. (2002) Clays and zeolite authigenesis in sediments from the flank of the Juan de Fuca Ridge. Clay Minerals, 37, 143–155.CrossRefGoogle Scholar
Campbell, I.B. & Claridge, G.G.C. (1987) Antarctica: Soils, Weathering Processes and Environments. Elsevier, Amsterdam.Google Scholar
Cape Roberts Science Team (2000) Studies from the Cape Roberts Project, Ross Sea, Antarctica—Initial Report on CRP-3. Terra Antartica, 7, 1–209.Google Scholar
Chamley, H. (1989) Clay Sedimentology. Springer.CrossRefGoogle Scholar
Cook, H.E., Johnson, P.D., Matti, J.C. & Zemmels, I. (1975) Methods of sample preparation and X-ray diffraction data analysis, X-ray mineralogy laboratory, Deep Sea Drilling Project, University of California, Riverside. Deep Sea Drilling Project Initial Reports, 28, 999–1007.Google Scholar
Cooper, A.K. & Davey, D.J., editors (1987) The Antarctic Continental Margin: geology and geophysics of the western Ross Sea. Circum-Pacific Council for Energy & Mineral Resources. Earth Science Series, 5B, Houston, Texas.Google Scholar
Ehrmann, W. (1998) Implications of late Eocene to early Miocene clay mineral assemblages in McMurdo Sound (Ross Sea, Antarctica) on paleoclimate and ice dynamics. Palaeogeography, Palaeoclimatology, Palaeoecology, 139, 213–231.CrossRefGoogle Scholar
Ehrmann, W. (2001) Variations in smectite content and crystallinity in sediments from CRP-3, Victoria Land Basin, Antartica. Terra Antartica, 8, 523–532.Google Scholar
Ehrmann, W., Melles, M., Kuhn, G. & Grobe, H. (1992) Significance of clay mineral assemblages in the Antarctic Ocean. Marine Geology, 107, 249–273.Google Scholar
Fagel, N., Andre, L., Chamley, H., Debrabant, P. & Jolivet, L. (1992) Clay sedimentation in the Japan Sea since the Early Miocene: influence of source rocks and hydrothermal activity. Sedimentary Geology, 80, 27–40.CrossRefGoogle Scholar
Fitzgerald, P.G. (1999) Cretaceous-Cenozoic tectonic evolution of the Antarctic Plate. Terra Antartica Reports, 3, 109–130.Google Scholar
Fitzgerald, P.G. (2001) Apatite fission track associated with the altered igneous intrusive in Beacon sandstone near the base of CRP-3, Victoria Land Basin, Antarctica. Terra Antartica, 8, 585–591.Google Scholar
Grauby, O., Petit, S., Decarreau, A. & Baronnet, A. (1993) The beidellite-saponite series: an experimental approach. European Journal of Mineralogy, 5, 623–635.Google Scholar
Hover, V.C., Walter, L.M., Peacor, D.R. & Martini, A.M. (1999) Mg-smectite authigenesis in a marine evaporative environment, Salina Ometepec, Baja California. Clays and Clay Minerals, 47, 252–268.Google Scholar
Jeans, C.V., Wray, D.S., Merriman RJ. & Fisher MJ. (2000) Volcanogenic clays in Jurassic and Cretaceous strata of England and the North Sea basin. Clay Minerals, 35, 25–55.Google Scholar
Kyle, P.R. (1990) McMurdo Volcanic Group-Western Ross Embayment. Introduction. Pp. 19—25 in: Volcanoes of the Antarctic Plate and Southern Oceans. American Geophysical Union, Antarctic Research Series, 48, Washington, D.C.Google Scholar
López-Galindo, A., Marinoni, L., Ben Aboud, A. & Setti, M. (1998) Morfologia, fabrica y quimismo en esmectitas de los sondeos CIROS-1, 270 y 274 (Mar de Ross, Antartida). Boletin de la Sociedad Española de Mineralogia, 21, 1–15.Google Scholar
Moore, D.M. & Reynolds, R.C. Jr. (1997) X-ray Diffraction and the Identification and Analysis of Clay Minerals, 2nd edition. Oxford University Press, Oxford, UK.Google Scholar
Neumann, M. & Ehrmann, W. (2001) Mineralogy of sediments from CRP-3, Victoria Land Basin, Antarctica, as revealed by X-ray diffraction. Terra Antartica, 8, 523–532.Google Scholar
Piper, D.Z. (1974) Rare earth elements in sedimentary cycle: a summary. Chemical Geology, 4, 285–304.Google Scholar
Pompilio, M., Armienti, P. & Tamponi, M. (2001) Petrography, mineral composition and geochemistry of volcanic and subvolcanic rocks of CRP-3, Victoria Land Basin, Antarctica. Terra Antartica, 8, 469–480.Google Scholar
Robert, C. & Maillot, H. (1990) Paleoenvironment in the Weddell Sea area and Antarctic climates, as deduced from clay mineral association and geochemical data, ODP Leg 113. Pp. 51-70 in. Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX, 113.Google Scholar
Setti, M., Marinoni, L., López-Galindo, A. & Ben Aboud, A. (1997) Clay minerals study (XRD, SEM, TEM) of the core CIROS-1 (Ross Sea, Antarctica). Terra Antartica, 4, 119–125.Google Scholar
Setti, M., Marinoni, L., López-Galindo, A. & Ben Aboud, A. (1998) TEM observations and trace element analysis on the clay minerals of the CRP-1 Core (Ross Sea, Antarctica). Terra Antartica, 5, 621–626.Google Scholar
Setti, M., Marinoni, L., López-Galindo, A. & Delgado-Huertas, A. (2000) Compositional and morphological features of the smectites of the sediments of the CRP-2A core (Ross Sea, Antarctica). Terra Antartica, 7, 581–587.Google Scholar
Setti, M., Marinoni, L. & López-Galindo, A. (2001) Crystal-chemistry of smectites in sediments of CRP-3 drillcore (Victoria Land Basin, Antarctica): preliminary results. Terra Antartica, 8, 543–550.Google Scholar
Smellie, J.L. (2001) History of Oligocene erosion, uplift and unroofing of the Transantarctic Mountains deduced from sandstone detrital modes in CRP-3 drillcore, Victoria Land Basin, Antarctica. Terra Antartica, 8, 481–489.Google Scholar
Sprovieri, M., Bellanca, A. & Neri, R. (2001) Bulk geochemistry of the sand fraction from CRP-3 (Victoria Land Basin, Antarctica); evidence for provenance and Milankovitch climatic fluctuations. Terra Antartica, 8, 551–562.Google Scholar
Stump, E. (1995) The Ross Orogen of the Transantarctic Mountains. Cambridge University Press, Cambridge, UK.Google Scholar
Thiry, M. (2000) Palaeoclimatic interpretation of clay minerals in marine deposits: an outlook from the continental origin. Earth-Science Reviews, 49, 201–221.Google Scholar
Tingey, R.J. (1991) Commentary on schematic geological map of Antarctic Scale 1:10,000,000. Bureau of Mineral Resources of Australia Bulletin, 238.Google Scholar
Uysal, I.T. & Golding, S.Z. (2003) Rare earth element fractionation in authigenic illite-smectite from Late Permian clastic rocks, Bowen Basin, Australia: implications for physico-chemical environments of fluids during illitization. Chemical Geology, 193, 167–179.Google Scholar
Velde, B. (1995) Origin and Mineralogy of Clays. Springer Verlag, Berlin.Google Scholar
Weaver, C.E. (1989) Clays, Muds and Shales. Developments in Sedimentology, 44. Elsevier, Amsterdam.Google Scholar
Wedepohl, K.H. (1978) Handbook of Geochemistry. Springer, New York.Google Scholar
Wilson, T.J. & Paulsen, T.S. (2001) Fault and fracture patterns in CRP-3 core, Victoria Land Basin, Antarctica. Terra Antartica, 8, 177–196.Google Scholar
Wise, S.W., Smellie, J., Aghib, F., Jarrad, R. & Krissek, L. (2001) Authigenic smectite clay coats in CRP-3 Drillcore, Victoria Land Basin, Antarctica, as possible indicators of fluid flow: a progress report. Terra Antartica, 8, 281–298.Google Scholar
Zwingmann, H., ClauerN. & Gaupp, R. (1999) Structurerelated geochemical (REE) and isotopic (K-Ar, Rb- Sr, δ18O) characteristics of clay minerals from Rotliegend sandstone reservoirs (Permian, Northern Germany). Geochimica et Cosmochimica Ada, 63, 2805–2823.Google Scholar