Hostname: page-component-848d4c4894-pjpqr Total loading time: 0 Render date: 2024-06-28T05:41:50.967Z Has data issue: false hasContentIssue false

A classification of kaolinites by infrared spectroscopy

Published online by Cambridge University Press:  09 July 2018

T. W. Parker*
Affiliation:
English Clays Lovering Pochin & Co. Ltd, St. Austell, Cornwall

Abstract

A method is described for plotting and comparing measurements made on kaolinite clays. In this the ratio of the two strongest bands in the OH-stretch region of the spectrum (band maxima at 3695–3700 cm−1 and 3620–3625 cm−1) of an oriented preparation at 45° incidence is plotted against the corresponding ratio from the spectrum of a randomly oriented preparation. Both ratios are affected by the shape of the kaolinite particles and methods for minimizing this are given. The position of a kaolinite upon a plot so prepared gives information on the following points: (a) the type of kaolinite, (b) the degree of crystallinity of the kaolinite, (c) the shape of the kaolinite particles.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1969

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Brindley, G.W. & Robinson, K. (1945) Nature, Lond. 156, 661.Google Scholar
Farmer, V.C. & Russell, J.D. (1967) Clays Clay Miner. 15, 121.Google Scholar
Fripiat, J.J. & Toussaint, F. (1963) J. phys. Chem. 67, 30.Google Scholar
Ledoux, R.L. & White, J.L. (1964) Science, N. Y. 143, 244.CrossRefGoogle Scholar
Robertson, R.H.S., Brindley, G.W. & Mackenzie, R.C. (1954) Am. Miner. 39, 118.Google Scholar
Serratosa, J.M., Hidalgo, A. & Vinas, J.M. (1962) Nature, Lond. 195, 486.Google Scholar
Wolff, R.G. (1963) Am. Miner. 48, 390.Google Scholar