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Adsorption of Lippia multiflora essential oil on two surfactant-modified clays: qualitative approach

Published online by Cambridge University Press:  08 September 2020

Soumahoro Gueu Open the ORCID record for Soumahoro Gueu [Opens in a new window] ,
Vama Etienne Tia ,
Danièle Bartier ,
Odile Barres  and
Fatogoma Dolourou Soro
Soumahoro Gueu*
Affiliation:
Institut National Polytechnique Félix Houphouët-Boigny – Laboratoire des Procédés Industriels de Synthèse, de l'Environnement et des Energies Nouvelles (LAPISEN), BP 1093 Yamoussoukro, Ivory Coast
Vama Etienne Tia
Affiliation:
Université Peleforo Gon Coulibaly de Korhogo, UFR Sciences Biologiques, Département de Biochimie, BP 1328 Korhogo, Ivory Coast
Danièle Bartier
Affiliation:
GeoRessources UMR 7359, Université de Lorraine, CNRS, Campus Aiguillettes, 54500 Vandœuvre-lès-Nancy, France
Odile Barres
Affiliation:
GeoRessources UMR 7359, Université de Lorraine, CNRS, Campus Aiguillettes, 54500 Vandœuvre-lès-Nancy, France
Fatogoma Dolourou Soro
Affiliation:
Université Peleforo Gon Coulibaly de Korhogo, UFR Sciences Biologiques, Département de Biochimie, BP 1328 Korhogo, Ivory Coast
*
*E-mail: soumahoro.gueu@inphb.ci
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Abstract

This paper deals with the adsorption of an essential oil (EO) on a kaolinite-rich clay and a smectite-rich clay. The two clays were modified with a quaternary alkyl ammonium surfactant to create a lipophilic environment for better adsorption of the EO. The preparation of the clay/EO hybrids avoided the use of a slurry and organic solvent. The selected EO was that of Lippia multiflora. This EO has insecticidal properties. The surfactant was trioctyl methylammonium (TOMA). The modified clays were characterized by X-ray diffraction (XRD) and infrared (IR) spectroscopy. The smectite-rich clay displayed greater adsorption of the L. multiflora EO compared to the kaolinite-rich clay. The interlayer space of the kaolinite-rich clay was not affected by the adsorption of the TOMA and/or EO molecules, which suggests that the adsorption in this clay took place on the external surface. By contrast, a significant increase in the interlayer space of the smectite-rich clay was observed, suggesting that the adsorption process of TOMA and/or EO took place on both the external and internal surfaces. The IR analysis showed that the surfactant loading in the interlayer space of the smectite-rich clay introduces a gauche conformation in the alkyl chains. A formulation mixing this local smectite-rich clay and the L. multiflora EO has potential for the manufacture of new biopesticides.

Keywords

adsorptionclaysessential oilLippia multifloratrioctyl methylammonium
Type
Article
Information
Clay Minerals , Volume 55 , Issue 3 , September 2020 , pp. 219 - 228
Copyright
Copyright © The Author(s), 2020. Published by Cambridge University Press on behalf of The Mineralogical Society of Great Britain and Ireland

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Footnotes

Associate Editor: Chun-Hui Zhou

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